GB444544A - A process for the manufacture of organic peroxides - Google Patents
A process for the manufacture of organic peroxidesInfo
- Publication number
- GB444544A GB444544A GB25287/35A GB2528735A GB444544A GB 444544 A GB444544 A GB 444544A GB 25287/35 A GB25287/35 A GB 25287/35A GB 2528735 A GB2528735 A GB 2528735A GB 444544 A GB444544 A GB 444544A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ketone
- peroxide
- prepared
- gas oil
- per cent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/20—Peroxy compounds the —O—O— group being bound to a carbon atom further substituted by singly—bound oxygen atoms
- C07C409/22—Peroxy compounds the —O—O— group being bound to a carbon atom further substituted by singly—bound oxygen atoms having two —O—O— groups bound to the carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
- C07C407/003—Separation; Purification; Stabilisation; Use of additives
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B47/00—Methods of operating engines involving adding non-fuel substances or anti-knock agents to combustion air, fuel, or fuel-air mixtures of engines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Acetone peroxide and homologues thereof such as the peroxides of methyl ethyl ketone, di-ethyl ketone and di-isopropyl-ketone are prepared by a process which comprises reacting the ketone and hydrogen peroxide at low temperature in the presence of strong acids, characterized in that the hydrogen peroxide used in the reaction is not isolated as such, but is prepared by hydrolysis of persulphuric acid or a persulphate and the reaction with the ketone conducted in situ. The hydrolytic treatment is carried out in any manner known per se, such as by bringing the solution containing the acidified persulphate to an elevated temperature for a short time. Stabilizers such as urea may be present during the hydrolysis. If the peroxide is intended to be isolated in the free state it is extracted from the reaction mixture with a pure readily distillable solvent such as benzene or gasoline, but if it is intended to be used for improving the ignition quality of fuels for Diesel engines, gas oil is used as the extraction agent. In the latter case a 7 per cent solution of the peroxide in gas oil is prepared which is a readily dosable product. In an example a 13 per cent solution of H2S2O8 obtained by electrolysis of a 50 per cent solution of sulphuric acid is hydrolysed for 1 minute at 100 DEG C. After cooling to -20 DEG C. the theoretical amount of acetone calculated on the amount of active oxygen present is added slowly. The reaction mixture is stirred for 15 minutes and the peroxide extracted with gasoline.ALSO:The ignition quality of fuels for Diesel engines is improved by the addition of acetone peroxide or a homologue thereof, e.g. the peroxides of methyl-ethyl-ketone, diethyl ketone, and diisopropyl ketone. The peroxide is prepared by the direct action of the ketone on a hydrolyzed solution of persulphuric acid or a persulphate, and extraction by gas oil. A 7 per cent solution of the peroxide in gas oil is prepared as a readily dosable product.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL444544X | 1934-09-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB444544A true GB444544A (en) | 1936-03-23 |
Family
ID=19786270
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB25287/35A Expired GB444544A (en) | 1934-09-14 | 1935-09-11 | A process for the manufacture of organic peroxides |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB444544A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2992923A (en) * | 1959-06-23 | 1961-07-18 | Short Milling Co J | Methods for oxidatively ireating flour |
US2992922A (en) * | 1959-06-23 | 1961-07-18 | Short Milling Co J | Methods for preparing baked goods |
US3047406A (en) * | 1959-06-23 | 1962-07-31 | Short Milling Co J | Methods for preparing oxidatively active compositions |
US3077412A (en) * | 1960-12-14 | 1963-02-12 | Short Milling Co J | Preparation and methods of employing oxidatively active materials |
US3243304A (en) * | 1961-07-10 | 1966-03-29 | Wallace & Tiernan Inc | Method for treating farinaceous materials |
-
1935
- 1935-09-11 GB GB25287/35A patent/GB444544A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2992923A (en) * | 1959-06-23 | 1961-07-18 | Short Milling Co J | Methods for oxidatively ireating flour |
US2992922A (en) * | 1959-06-23 | 1961-07-18 | Short Milling Co J | Methods for preparing baked goods |
US3047406A (en) * | 1959-06-23 | 1962-07-31 | Short Milling Co J | Methods for preparing oxidatively active compositions |
US3077412A (en) * | 1960-12-14 | 1963-02-12 | Short Milling Co J | Preparation and methods of employing oxidatively active materials |
US3243304A (en) * | 1961-07-10 | 1966-03-29 | Wallace & Tiernan Inc | Method for treating farinaceous materials |
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