GB2470062A - Production and Distribution of Natural Gas - Google Patents

Production and Distribution of Natural Gas Download PDF

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Publication number
GB2470062A
GB2470062A GB0907905A GB0907905A GB2470062A GB 2470062 A GB2470062 A GB 2470062A GB 0907905 A GB0907905 A GB 0907905A GB 0907905 A GB0907905 A GB 0907905A GB 2470062 A GB2470062 A GB 2470062A
Authority
GB
United Kingdom
Prior art keywords
natural gas
refrigerant
gas
heat exchanger
liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB0907905A
Other versions
GB0907905D0 (en
Inventor
Adrian Graham Alford
Julian Oliver Reed
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Corac Group PLC
Original Assignee
Corac Group PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Corac Group PLC filed Critical Corac Group PLC
Priority to GB0907905A priority Critical patent/GB2470062A/en
Publication of GB0907905D0 publication Critical patent/GB0907905D0/en
Priority to PCT/IB2010/051982 priority patent/WO2010128467A2/en
Priority to PCT/IB2010/051981 priority patent/WO2010128466A2/en
Publication of GB2470062A publication Critical patent/GB2470062A/en
Withdrawn legal-status Critical Current

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
    • F25J1/005—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by expansion of a gaseous refrigerant stream with extraction of work
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0012—Primary atmospheric gases, e.g. air
    • F25J1/0015—Nitrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022—Hydrocarbons, e.g. natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/004—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0045—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by vaporising a liquid return stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/006—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
    • F25J1/007—Primary atmospheric gases, mixtures thereof
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/006—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
    • F25J1/007—Primary atmospheric gases, mixtures thereof
    • F25J1/0072—Nitrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0203—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle
    • F25J1/0208—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle in combination with an internal quasi-closed refrigeration loop, e.g. with deep flash recycle loop
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0221—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using the cold stored in an external cryogenic component in an open refrigeration loop
    • F25J1/0223—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using the cold stored in an external cryogenic component in an open refrigeration loop in combination with the subsequent re-vaporisation of the originally liquefied gas at a second location to produce the external cryogenic component
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0221—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using the cold stored in an external cryogenic component in an open refrigeration loop
    • F25J1/0224—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using the cold stored in an external cryogenic component in an open refrigeration loop in combination with an internal quasi-closed refrigeration loop
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
    • F25J1/0229—Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock
    • F25J1/023—Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock for the combustion as fuels, i.e. integration with the fuel gas system
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
    • F25J1/0262—Details of the cold heat exchange system
    • F25J1/0264—Arrangement of heat exchanger cores in parallel with different functions, e.g. different cooling streams
    • F25J1/0265—Arrangement of heat exchanger cores in parallel with different functions, e.g. different cooling streams comprising cores associated exclusively with the cooling of a refrigerant stream, e.g. for auto-refrigeration or economizer
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
    • F25J1/0281—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc. characterised by the type of prime driver, e.g. hot gas expander
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
    • F25J1/0281—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc. characterised by the type of prime driver, e.g. hot gas expander
    • F25J1/0283—Gas turbine as the prime mechanical driver
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
    • F25J1/0285—Combination of different types of drivers mechanically coupled to the same refrigerant compressor, possibly split on multiple compressor casings
    • F25J1/0288—Combination of different types of drivers mechanically coupled to the same refrigerant compressor, possibly split on multiple compressor casings using work extraction by mechanical coupling of compression and expansion of the refrigerant, so-called companders
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    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/08—Separating gaseous impurities from gases or gaseous mixtures or from liquefied gases or liquefied gaseous mixtures
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    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/40—Processes or apparatus using other separation and/or other processing means using hybrid system, i.e. combining cryogenic and non-cryogenic separation techniques
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F25J2210/04—Mixing or blending of fluids with the feed stream
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    • F25J2210/00—Processes characterised by the type or other details of the feed stream
    • F25J2210/40—Air or oxygen enriched air, i.e. generally less than 30mol% of O2
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    • F25J2210/00—Processes characterised by the type or other details of the feed stream
    • F25J2210/42—Nitrogen
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    • F25J2210/00—Processes characterised by the type or other details of the feed stream
    • F25J2210/62—Liquefied natural gas [LNG]; Natural gas liquids [NGL]; Liquefied petroleum gas [LPG]
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    • F25J2220/00—Processes or apparatus involving steps for the removal of impurities
    • F25J2220/44—Separating high boiling, i.e. less volatile components from nitrogen, e.g. CO, Ar, O2, hydrocarbons
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    • F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
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    • F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/22—Compressor driver arrangement, e.g. power supply by motor, gas or steam turbine
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    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/30—Compression of the feed stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/14—External refrigeration with work-producing gas expansion loop
    • F25J2270/16—External refrigeration with work-producing gas expansion loop with mutliple gas expansion loops of the same refrigerant
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/62—Details of storing a fluid in a tank

Abstract

Natural gas is liquefied at a production site by compression 10, cooling in an after-cooler 12, after first mixing with it a refrigerant. The condensed refrigerant is separated from the compressed gas in a separator 14, flashed through an expansion valve 16 and used to cool the natural gas further. To liquefy the now compressed natural gas, it is passed through heat exchangers 18, 22, where it is cooled by the refrigerant, such as liquid nitrogen, or a cooled refrigerant gas of a reverse Brayton cycle refrigeration circuit. At a market site (Fig 2), the liquid natural gas can be used to produce liquid nitrogen which is returned to the production site using the same insulated containers as used for transporting the liquid natural gas from the production site to the market site. The liquid nitrogen is produced at the market site by using natural gas to fuel an engine (60 Fig 2) that powers a compressor (68, 70, Fig 2)acting to compress the exhaust gases of the engine before they are cooled by the liquid natural gas. Water and carbon dioxide condense at different stages of the cooling process and are removed.

Description

PRODUCTION AND DISTRIBUTION OF NATURAL GAS
Field of the invention
The present invention relates to the production and distribution of natural gas derived from low pressure sources.
Background To The Invention
Natural gas (methane) has traditionally been produced from large, hiqh pressure gas wells with individual discrete sources providing flow rates of some 2 to 100kg/s. With these high mass flow rates, the construction of fixed installations and extensive pipeline networks has been economic. More recently, lower flow, lower pressure and more diffuse sources such as coal and biomass derived methane have been utilized. For these cases, the high capital costs of pipeline construction and gas gathering networks have had a negative impact on both the investment decision and the operating profitability of these schemes.
In some cases, methane has been combusted in internal combustion engine/generator sets with energy sold on as electricity. This approach still requires the investment in generator sets and electrical transmission lines, and the relative inefficiency of the energy conversion and delivery process in comparison with large scale electricity generation further reduces the potential for profitability.
In addition, the visual and noise impact of generating sets and transmission cables may limit the use of this approach in certain areas.
A second potential approach to avoid the significant investment in pipeline construction would be for methane to be converted to Liquefied Natural Gas (LNG) at or close to the source of the gas by mechanical refrigeration and transported to markets by insulated tanker. The capital investment in the refrigeration equipment for this method is still significant, and operating costs are relatively high due to the low efficiency of small scale cryogenic refrigeration equipment which can use up to 25% of the gas mass flow to achieve the liquefaction of the remainder, 75% in this case. Though the methane will be increased in value by its conversion to LNG, a market for LNG within a reasonable distance of the methane source would be necessary, and if this was not in existence the regasification of the LNG would entail the total loss of the energy expended in the original conversion of the gas to LNG.
A third approach would be to use a system such as that suggested by Williams et al (US 3,400,547), with methane liquefied at or close to its source by heat exchange against boiling liquid air or nitrogen, transported to a "market site" as LNG in an insulated tanker and regasified against pressurized air or nitrogen which is liquefied for transport to and subsequent use at the methane liquefaction site.
This method was originally suggested for use with large flow rate, high pressure natural gas sources to be transported over long distances by sea, and has significant difficulties associated with its implementation for small, low pressure sources of methane. The most significant difficulty in utilization of this method is the discrepancy between the mass flows of the LNG and liquid nitrogen streams. A mass flow of liquid nitrogen some double that of the LNG stream is required to liquefy natural gas, and though the liquid nitrogen is around double the density of the LNG, this can create significant transport difficulties with a tractor and trailer unit specified for the mass of liquid nitrogen to be carried having an LNG capacity of only around half of this figure. Thus an insulated semi-trailer and tractor unit optimised for transport of LNG will be unable to transport sufficient liquid nitrogen from the market site to the production site in order to liquefy that methane stream. In addition, the difference in the boiling points of methane and nitrogen makes it necessary to compress the nitrogen to a significant pressure before the boiling point is increased sufficiently for the nitrogen to be liquefied by the LNG stream. A further problem to be addressed is the provision of a nitrogen stream for conversion to liquid nitrogen. Air separation units and other methods for the generation of nitrogen from air have a non-negligible capital and operating cost and have a secondary stream of oxygen or liquid oxygen, a market for which must be found if the air separation unit is to be subsidised to any degree.
It is therefore apparent that to increase the financial viability of both the second and third approach, a low capital cost and efficient means of refrigeration of the methane stream must be provided.
In both cases, the use of some 20 to 25% of the gas in the liquefaction process will significantly reduce the low-carbon nature of the fuel and can result in far higher releases of Carbon Dioxide to the atmosphere than utilization of more traditional routes to market.
Summary of the invention
According to a first aspect of the present invention, there is provided a method of liquefying natural gas, which comprises adding to the natural gas a refrigerant having a higher boiling point than natural gas, compressing the gaseous mixture, cooling the compressed mixture to liquefy the refrigerant, separating the liquid refrigerant from the cooled natural gas, passing the liquid refrigerant through an expansion valve to vaporise the refrigerant, using the refrigerant fluid to cool the natural gas further in a heat exchanger, returning the refrigerant gas to the compressor intake for recycling and subsequently applying further cooling to liquefy the natural gas passing through the heat exchanger.
The first aspect of the invention takes advantage of the fact that the natural gas sources need to be compressed before transport, treatment or liquefaction processes are applied. Use is made of this compression process to introduce a pre-cooling step before liquefaction, by adding a refrigerant gas to the natural gas prior to compression and condensing it after compression and cooling of the compressed gas mix. By separating the condensed refrigerant and passing it through an expansion valve to flash it to around compressor inlet pressure, a sub-ambient temperature refrigerant fluid is produced to cool the compressed natural gas to a sub-ambient temperature before the refrigerant is returned as gas to the inlet side of the compressor. Further cooling to liquefy the natural gas can be performed by a Brayton cycle refrigeration system or by sacrificial liquid nitrogen cooling.
According to a second aspect of the invention, there is provided an apparatus for liquefying natural gas, which comprises a compressor for compressing an intake gas consisting of a mixture of the natural gas and an added refrigerant having a higher boiling point than natural gas, an after-cooler for cooling the compressed mixture to cause the refrigerant to condense, a separator for separating condensed refrigerant from the natural gas, an expansion valve connected to receive the liquid refrigerant from the separator and operative to cool the refrigerant by partial vaporisation, a heat exchanger for using the refrigerant fluid to cool the natural gas further, a line for returning refrigerant gas from the heat exchanger to the compressor intake for recycling and a refrigeration stage for cooling the natural gas passing through the heat exchanger so as to liquefy the natural gas.
It has already been proposed in US 3400547 to recover energy expended at the production site in liquefying the natural gas, by using that energy at the market site to generate liquid nitrogen. Liquid nitrogen can then be returned in the same delivery containers to the production site where it can once again be used to liquefy natural gas.
However, an efficient method and apparatus is required to produce liquid nitrogen using the liquid natural gas if the complete process is to be economically viable.
According to a third aspect of the invention, there is provided an apparatus for producing liquid nitrogen from the gasification of liquid natural gas, comprising an engine producing mechanical output power from combustion of natural gas, a compressor driven by the engine and serving to compress a gas stream consisting predominantly of nitrogen and substantially oxygen free derived from exhaust gases of the engine to raise the boiling point of the nitrogen and at least one heat exchanger serving to reject heat from the compressed nitrogen stream to a stream of liquid natural gas to cause the nitrogen stream to condense and to gasify the natural gas.
According to a further aspect of the invention, there is provided a method of distributing natural gas derived from a low pressure source, which comprises the steps of, at a production site, liquefying natural gas by use of an apparatus of the second aspect of the invention, loading the liquid natural gas into insulated containers, and transporting the insulated containers to a market site, and, at the market site, gasifying the natural gas received in the insulated containers and producing liquid nitrogen by the use of an apparatus of the third aspect of the invention, loading the liquid nitrogen into the insulated containers, and transporting the liquid nitrogen filled containers back to the production site.
Brief description of the drawings
The invention will now be described further, by way of example, with reference to the accompanying drawings, in which Figure 1 is a schematic diagram of a production site installation to liquefy natural gas, and Figure 2 is a schematic diagram of a market site installation to gasify LNG and produce liquid nitrogen.
Detailed description of the preferred embodiment
In Figure 1, a mixture of natural gas NG derived from a low pressure source such as coal bed methane, and a refrigerant, such as propane or butane circulating in a refrigerant circuit described below, is compressed in a compressor 10 and cooled in an after-cooler 12. The compressed refrigerant condenses in the after-cooler 12 and the liquid refrigerant is removed from the compressed gas by a separator 14. The liquid refrigerant is then "flashed" in an expansion valve 16 (which is essentially a throttle) which has the effect of cooling the refrigerant by partial evaporation. The vaporised refrigerant and the compressed natural gas are then passed through a heat exchanger to gasify the refrigerant and cool the natural gas. The gasified refrigerant is then returned to the intake of the compressor 10 for remixing with fresh natural gas.
Some refrigerant may remain in the compressed natural gas stream and it will condense within the heat exchanger 18. Once again, the liquid refrigerant is removed from the gas stream by a second separator 24 and that liquid refrigerant can either be recycled through the previously described expansion valve 16 (as shown by the broken line arrow) or it can be passed through a second expansion valve and heat exchanger 22 to reduce the temperature of the natural gas still further before it too is returned to the intake of the compressor 10.
At this point, the natural gas will have been compressed and cooled but it will still remain as a gas until cooled further; for example, the natural gas may be at a pressure of 15 bar and a temperature of -60°C. At this pressure, the temperature of the natural gas would need to be reduced to -115°C before it will condense to form LNG.
The necessary further cooling is carried out in the illustrated embodiment in two stages, passing first through a heat exchanger 50 then through a heat exchanger 40. In each of these two heat exchangers, the natural gas can lose heat to a reverse Brayton cycle refrigeration circuit, as will be described below, or to a stream of liquid nitrogen obtained from an insulated container, as will also be described below. Unless there is a local requirement for the gasified nitrogen, it can be sacrificed by being discharged into the ambient atmosphere.
Figure 1 shows two reverse Brayton cycle refrigeration units that are bootstrapped so that only one motor is required to operate both of them. These units are well known in the art and are often referred to as companders.
The companders use air, nitrogen, or any suitable gas, as the refrigerant and this remains in a gaseous state at all stages of the refrigeration cycle.
The compander supplying cold gas to the heat exchanger comprises a compressor 30 driven by a motor 32. The compressed gas passes through an after-cooler 36 before flowing through a recuperator 38, which is itself a counter-current heat exchanger where the compressed gas loses heat to the gas entering the compressor 30. The gas is then used to drive a turbine that is mechanically coupled to the motor 32 to assist in driving the compressor 30. The expansion of the gas in the turbine results in a drop in pressure and temperature so that when it is passed through the heat exchanger 40 it lowers the temperature of the natural gas to the point where it liquefies.
The second compander comprises a compressor 42 driven by a turbine 44 and the circulating gas once again passes through an after-cooler 46 and a recuperator 48. The difference from the first compander is that it does not have a separate motor and is instead powered by the compressed gas generated by the compressor 30 to which it is connected in a bootstrap configuration.
After leaving the heat exchanger 40, the natural gas will have been fully liquefied but, to lower its temperature and pressure to values suitable for transportation of the LNG, the liquefied natural gas is flashed in an expansion valve 52 creating some NG vapour and lowering the temperature of the liquid natural gas. A separator 54 separates the liquid natural gas for storage in insulated transportation containers, while the vaporised natural gas is returned via the two heat exchangers 40 and 50 to the intake of the compressor 10.
To assist in understanding the drawing, heavier lines have been drawn to represent the flow of the natural gas, lighter lines to represent the flow of different refrigerant and a dotted line to represent the flow of nitrogen.
Figure 2 shows an installation at a market site, where the LNG arrives in containers to be gasified and, if necessary, pressurised for distribution through a pipeline.
It will be clear from the description given above of the production site installation that considerable energy needs to be expended to liquefy natural gas. When the liquid is gasified at the market site, all the energy consumed in the liquefaction process is ordinarily wasted. The distribution system of the present invention reduces such energy wastage by allowing the "coolth" of the liquefied natural gas to be recycled and returned to the production site in the form of liquid nitrogen, to enable the natural gas to be liquefied at the production site using less energy. The installation in Figure 2 therefore has LNG as its input and at the same time as gasifying the LNG it generates liquid nitrogen to be returned to a production site to be used in the previously described heat exchangers 40 and 50.
As the liquefied gas to be returned to the production site is stored in the same container as the LNG, it is important that it should be substantially devoid of oxygen.
Air is of course a suitable source of nitrogen but before it can be used it has to be stripped of its oxygen content.
The market site installation shown in Figure 2 comprises as a source of nitrogen an engine 60 which runs on natural gas, for example obtained from the pipeline to be supplied. The engine may suitably be a reciprocating piston engine but it could equally be a rotary or gas turbine engine.
When the engine burns methane in air, its combustion products will include water and carbon dioxide in addition to the required nitrogen. These must also be removed before the exhaust gases are liquefied because they would otherwise freeze and block the various heat exchangers.
The exhaust gases of the engine 60 are cooled in an after-cooler 62 to cause the steam to condense. A separator 64 removes the liquid water and allows the remainder of the exhaust gas stream to enter the intake of a two-stage compressor 68, 70 driven by the output shaft 66 of the engine 60. An intercooler 72 is arranged in the normal way between the two stages 68, 70 of the compressor. A second -10 -after-cooler 74 results in more of the water condensing and this is removed by a second separator 76.
The remaining exhaust gas stream which still contains carbon dioxide is passed through a two-stage counter-current heat exchanger where the other fluid is the liquid natural gas to be gasified. The carbon dioxide condenses in the first stage 78 of the heat exchanger and is removed in liquid form by a separator 80. It should be noted that because the exhaust gases have been pressurised by the compressor 68, 70 they are above the pressure at which carbon dioxide will sublimate. The exhaust gas stream entering the second stage 82 of the heat exchanger will therefore consist predominantly of nitrogen and because its boiling point will have been raised by its high pressure it will condense on losing its heat to the liquid natural gas stream.
The temperature of the liquefied nitrogen is lowered by partial vaporisation in an expansion valve 84. The further cooled liquid nitrogen is then stored in the insulated containers that were used for the liquid natural gas for return to a production site while the nitrogen vapour is returned to an earlier compressor stage for recycling after having first passed through the two-stage counter-current heat exchanger 78, 82. Depending on the pressure of the liquid nitrogen, the recycled nitrogen can either be returned to the second stage 70 of the compressor as shown in solid lines or to the first stage 68 as shown by a dotted line.
Instead of relying exclusively on thermal contact to transfer heat from the nitrogen stream to the liquid natural gas stream in the heat exchangers 78, 82, it would be possible to provide a mechanically powered refrigeration circuit to act effectively as a heat pump, in order to pump -11 -heat from the nitrogen stream into the liquid natural gas stream.
The volume of liquid nitrogen produced can be substantially the same as the volume of LNG that is gasified because of the difference in the specific heats of the two gases. However, the weight of the liquid nitrogen will be substantially greater than the LNG and it may not therefore be acceptable to fill the containers to their maximum capacity for their return to the production site. It is therefore possible that a production site will not receive all the liquid nitrogen that is needed to liquefy the natural gas.
This inequality can be allowed for by combining liquid nitrogen cooling with reverse Brayton cycle cooling as described above but this would necessitate expensive heat exchangers with multiple passages.
An alternative approach in a network comprising several production sites is to design some sites to use only liquid nitrogen sacrificial cooling as the last cooling stage in the liquefaction of the natural gas while other sites rely solely on reverse Brayton cycle cooling for the last cooling stage. In this way, cost of individual production sites can be minimised by avoiding the need for dual purpose heat exchangers in all production sites, and the need for companders in the sites that rely on liquid nitrogen cooling.

Claims (15)

  1. -12 -CLAIMS1. A method of liquefying natural gas, which comprises adding to the natural gas a refrigerant having a higher boiling point than natural gas, compressing the gaseous mixture, cooling the compressed mixture to liquefy the refrigerant, separating the liquid refrigerant from the cooled natural gas, passing the liquid refrigerant through an expansion valve to vaporise the refrigerant, using the refrigerant fluid to cool the natural gas further in a heat exchanger, returning the refrigerant gas to the compressor intake for recycling and subsequently applying further cooling to liquefy the natural gas passing through the heat exchanger.
  2. 2. An apparatus for liquefying natural gas, which comprises a compressor for compressing an intake gas consisting of a mixture of the natural gas and an added refrigerant having a higher boiling point than natural gas, an after-cooler for cooling the compressed mixture to cause the refrigerant to condense, a separator for separating condensed refrigerant from the natural gas, an expansion valve connected to receive the liquid refrigerant from the separator and operative to cool the refrigerant by partial vaporisation, a heat exchanger for using the refrigerant fluid to cool the natural gas further, a line for returning refrigerant gas from the heat exchanger to the compressor intake for recycling and a further refrigeration stage for cooling the natural gas passing through the heat exchanger SO as to liquefy the natural gas.
  3. 3. Apparatus according to claim 2, wherein the refrigerant is a mixture of two or more refrigerant gases having different boiling points.
  4. 4. Apparatus as claimed in claim 2 or 3, in which the refrigerant is a hydrocarbon or mixture of hydrocarbons.
    -13 -
  5. 5. An apparatus as claimed in any of claims 2 to 4, further comprising a second separator for separating any refrigerant remaining in the natural gas stream after leaving the after-cooler and condensing in the heat exchanger.
  6. 6. An apparatus as claimed in claim 5, wherein the refrigerant from the second separator is combined for recycling with the refrigerant from the first separator.
  7. 7. An apparatus as claimed in claim 5, wherein the refrigerant recovered by the second separator is flashed through a second expansion valve and used in a second heat exchanger arranged downstream of the first heat exchanger to lower the temperature of the natural gas still further.
  8. 8. An apparatus as claimed in any of claims 2 to 7, wherein the further refrigeration stage is a reverse Brayton cycle refrigeration system, formed of a motor powered compressor and an expander connected to one another in a closed circuit which comprises an after-cooler for reducing the temperature of the gas leaving the compressor to near ambient and a recuperator for exchanging heat between the gas entering the compressor and the gas stream between the inter-cooler and the turbine.
  9. 9. Apparatus as claimed in claim 8, wherein the further refrigeration stage comprises two compressor and expander sets of which one is powered by an electric motor and the other is powered by compressed gas derived from the compressor of the first set.
  10. 10. Apparatus as claimed in any of claims 2 to 9, wherein the further refrigeration stage includes a heat exchanger transferring heat from the natural gas to a stream -14 -of a sacrificial refrigerant that is exhausted to atmosphere.
  11. 11. Apparatus as claimed in claim 10, wherein the sacrificial refrigerant is liquid nitrogen.
  12. 12. Apparatus for producing liquid nitrogen from the gasification of liquid natural gas, comprising an engine producing mechanical output power from combustion of natural gas, a compressor driven by the engine and serving to compress a gas stream consisting predominantly of nitrogen and substantially oxygen free derived from exhaust gases of the engine to raise the boiling point of the nitrogen and at least one heat exchanger serving to reject heat from the compressed nitrogen stream to a stream of liquid natural gas to cause the nitrogen stream to condense and to gasify the natural gas.
  13. 13. Apparatus as claimed in claim 12, wherein an means are provided for cooling the engine exhaust gases prior to their entering the heat exchanger, so as to remove the water content of the exhaust gases by condensation.
  14. 14. An apparatus as claimed in claim 12 or 13, wherein the heat exchanger is a two-stage heat exchanger dimensioned such that the temperature of the exhaust gas stream between the two stages allows the CO2 content of the exhaust gases to be removed by condensation.
  15. 15. A method of distributing natural gas derived from a low pressure source, which comprises the steps of at a production site liquefying natural gas by use of an apparatus as claimed in any one of claims 10 and 11, loading the liquid natural gas into insulated containers at atmospheric or above atmospheric pressure, and -15 -transporting the insulated containers to a market site, and at the market site: gasifying the natural gas received in the insulated containers and producing liquid nitrogen by the use of an apparatus as claimed in any one of claims 11 to 13, loading the liquid nitrogen into the insulated containers at atmospheric or above atmospheric pressure, and transporting the liquid nitrogen filled containers back to the production site.
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