GB2437280A - Concrete incorporating organic liquids or solids treated with super critical carbon dioxide - Google Patents
Concrete incorporating organic liquids or solids treated with super critical carbon dioxide Download PDFInfo
- Publication number
- GB2437280A GB2437280A GB0607902A GB0607902A GB2437280A GB 2437280 A GB2437280 A GB 2437280A GB 0607902 A GB0607902 A GB 0607902A GB 0607902 A GB0607902 A GB 0607902A GB 2437280 A GB2437280 A GB 2437280A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carbon dioxide
- super critical
- concrete
- organic liquids
- critical carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 64
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 32
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 32
- 239000007787 solid Substances 0.000 title claims abstract description 12
- 239000007788 liquid Substances 0.000 title claims abstract description 9
- 239000004567 concrete Substances 0.000 title abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 239000004568 cement Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 8
- 239000008187 granular material Substances 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000012615 aggregate Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/18—Waste materials; Refuse organic
- C04B18/20—Waste materials; Refuse organic from macromolecular compounds
- C04B18/22—Rubber, e.g. ground waste tires
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/06—Oxides, Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/02—Selection of the hardening environment
- C04B40/0231—Carbon dioxide hardening
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Toxicology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Civil Engineering (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Organic liquids or solids whose carbon dioxide content has been enhances through their exposure to high pressure carbon dioxide are introduced into cement aggregate mixtures. The carbon dioxide may be in the super critical state. The organic solid may be vulcanised rubber chips which may be treated with super critical carbon dioxide for between 1 and 120 minutes. The vulcanised rubber chips are then added to a cement aggregate and water mix, the mix is then allowed to harden. The resultant concretes are mechanically stronger than those produced without the super critical carbon dioxide laden granules.
Description
<p>1 2437280 improved Concrete.</p>
<p>This invention relates to a method for producing improved concrete.</p>
<p>Background.</p>
<p>In its simplest form concrete is a tnixture of pastes aggregate and water. The paste is a mixture of water and cement which coats the surface of the fine or course aggregate particles. Through the chemical process of hydration the paste hardens and forms a rock like mass known as concrete. The pastes used in the formation of cernen.t may contain varying proportions of the hydroxides of calcium, magnesium, sodium, alluminium and other metal hydrates. When exposed to atmospheric carbon dioxide they slowly convert to carbonates and water further improving the mechanical properties of concrete. In ceramics and water this process can take many years to complete.</p>
<p>Water saturation in the pores, desirable for some aspects of concrete production can further slow the carbonation process. To enhance the rate of carbonation cured or partially cured concrete can be treated using supercritiCal carbon dioxide. Due to the high diffusivitY of supercritical carbon dioxide rapid penetration into the concrete matrix occurs ensuring enhanced availability of carbon dioxide throughout the formative concrete matrix. The availability of carbon dioxide throughout the matrix allows more rapid carbonation to occur with the end result that stronger, harder concretes are produced more quickly than in ordinary conditions. At present the supercritiCal carbon dioxide is introduced into the cured or partially cured cement matrices either by the action of a jet of superCritiCal carbon dioxide on the surface of the cement or by placing the cement in an autoclave into which is pumped superCritiCal carbon dioxide.</p>
<p>Essential technical features.</p>
<p>This method enhances and improves the delivery of superCritical carbon dioxide into a concrete by jptroduCiflg the superCritical carbon dioxide into the initial cement, aggregate, water mixing stage.</p>
<p>SuperCritical Carbon dioxide is carbon dioxide above its critical point i.e. a temperature of 374 K at a pressure of 74 Bar. It is not possible to introduce such a high pressure fluid directly into a concrete production system which is normally carried out at atmospheric pressure.</p>
<p>SurpriSifl8lY it is possible to mix supercritical carbon dioxide and high pressure carbon dioxide into a conventional concrete production system through the use of an intermediate carrier substance which can either be a liquid or a solid. This is complished by exploiting the ability of supercritical carbon dioxide to either dissolve in or become miscible with a range of organic liquids. In the case of solid carriers, the supetCTitil carbon dioxide can penetrate a wide range of solid organic materials or polymers and become retained within the structure and matrices of these organic solids. If the supercritical carbon dioxide is introduced into such organic liquids or solids in an autoclave above the critical point of carbon dioxide, and if the autoclave is rapidly decompressed a surprisingly large amount of the carbon dioxide is retained within the organic liquid or solid. The organic liquid or solid may then be incorporated into the mix of a concrete as it is being blended. The carbon dioxide retained in the organic liquid or solid is released into the mix as the concrete mix starts to cure. The presence of carbon dioxide within the concrete mix at this early stage ensures rapid carbonation, enhanced curing, improved mechanical properties and negates the need for post cure treatment with supercritiCal carbon dioxide.</p>
<p>Example.</p>
<p>Vulcanised rubber chips of sizes between 0.1mm and 50mm are placed within an autoclave and sealed. An excess of SupercritiCal carbon dioxide is pumped into the autoclave and left to equilibrate for between 1 minute and 120 minutes. After equilibration the autoclave is vented and unsealed. The vulcanized rubber chips are withdrawn from the autoclave and then added into a cement aggregate and water mix.</p>
<p>The resulting mix is then poured into position either in an open mould or within a shuttered gas porous enclosure to allow the curing I hardening of the concrete. The resultant concretes are mechanicallY stronger than those produced Without the supercritical carbon dioxide laden granules.</p>
Claims (1)
- <p>Claims 1. The introduction of organic liquids or solids whose carbondioxide content has been enhanced through their exposure to high pressure carbon dioxide into cement aggregate mixtures.</p>
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0607902A GB2437280A (en) | 2006-04-21 | 2006-04-21 | Concrete incorporating organic liquids or solids treated with super critical carbon dioxide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0607902A GB2437280A (en) | 2006-04-21 | 2006-04-21 | Concrete incorporating organic liquids or solids treated with super critical carbon dioxide |
Publications (2)
Publication Number | Publication Date |
---|---|
GB0607902D0 GB0607902D0 (en) | 2006-05-31 |
GB2437280A true GB2437280A (en) | 2007-10-24 |
Family
ID=36581004
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB0607902A Withdrawn GB2437280A (en) | 2006-04-21 | 2006-04-21 | Concrete incorporating organic liquids or solids treated with super critical carbon dioxide |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB2437280A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011033311A3 (en) * | 2009-09-18 | 2011-05-05 | Peter Hammond | Improved materials |
WO2012134928A1 (en) * | 2011-04-01 | 2012-10-04 | Chun Well Industry Co., Ltd. | Method for producing improved rubberized concrete using waste rubber tires |
US8536239B1 (en) | 2011-05-02 | 2013-09-17 | Chun Well Industry Co. Ltd. | Method for producing improved rubberized concrete using waste rubber tires |
WO2015136290A1 (en) * | 2014-03-12 | 2015-09-17 | Enviromate Limited | Construction material and method of manufacturing the same |
US20230118904A1 (en) * | 2021-10-19 | 2023-04-20 | Halliburton Energy Services, Inc. | Enhanced Carbon Sequestration via Foam Cementing |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113733352B (en) * | 2021-04-08 | 2022-08-16 | 中国矿业大学 | Method and device for preparing foam concrete by using supercritical carbon dioxide |
CN114538850B (en) * | 2022-03-09 | 2022-11-29 | 南京工业大学 | Solid waste base lightweight aggregate based on biochar internal carbonization and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997044293A1 (en) * | 1996-05-20 | 1997-11-27 | Materials Technology, Limited | Hardened hydraulic cement, ceramic or coarse concrete aggregate treated with high pressure fluids |
JPH11314979A (en) * | 1998-05-07 | 1999-11-16 | Sekisui Chem Co Ltd | Production of cement hardened body |
JP2000128663A (en) * | 1998-10-27 | 2000-05-09 | Nichiha Corp | Production of wooden cement board |
JP2000335947A (en) * | 1999-03-25 | 2000-12-05 | Sekisui Chem Co Ltd | Artificial lightweight aggregate, its production and cement hardened product |
WO2002090293A2 (en) * | 2001-05-09 | 2002-11-14 | Balmoral Technologies (Proprietary) Limited | Method of making a finished product from a feedstock, a portland cement, and a thermosetting resin |
-
2006
- 2006-04-21 GB GB0607902A patent/GB2437280A/en not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997044293A1 (en) * | 1996-05-20 | 1997-11-27 | Materials Technology, Limited | Hardened hydraulic cement, ceramic or coarse concrete aggregate treated with high pressure fluids |
JPH11314979A (en) * | 1998-05-07 | 1999-11-16 | Sekisui Chem Co Ltd | Production of cement hardened body |
JP2000128663A (en) * | 1998-10-27 | 2000-05-09 | Nichiha Corp | Production of wooden cement board |
JP2000335947A (en) * | 1999-03-25 | 2000-12-05 | Sekisui Chem Co Ltd | Artificial lightweight aggregate, its production and cement hardened product |
WO2002090293A2 (en) * | 2001-05-09 | 2002-11-14 | Balmoral Technologies (Proprietary) Limited | Method of making a finished product from a feedstock, a portland cement, and a thermosetting resin |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011033311A3 (en) * | 2009-09-18 | 2011-05-05 | Peter Hammond | Improved materials |
CN102574743A (en) * | 2009-09-18 | 2012-07-11 | Ccm研究有限公司 | Improved materials |
CN102574743B (en) * | 2009-09-18 | 2014-10-01 | Ccm研究有限公司 | Improved materials |
US9446985B2 (en) | 2009-09-18 | 2016-09-20 | Ccm Research Limited | Method of treating cellulose material with CO2 or source thereof |
WO2012134928A1 (en) * | 2011-04-01 | 2012-10-04 | Chun Well Industry Co., Ltd. | Method for producing improved rubberized concrete using waste rubber tires |
US8338506B2 (en) | 2011-04-01 | 2012-12-25 | Chun Well Industry Co., Ltd. | Method for producing improved rubberized concrete using waste rubber tires |
CN103443047A (en) * | 2011-04-01 | 2013-12-11 | 铨吉企业有限公司 | Method for producing improved rubberized concrete using waste rubber tires |
CN103443047B (en) * | 2011-04-01 | 2015-11-25 | 铨新化工科技股份有限公司 | Waste rubber tire is utilized to manufacture the concrete method of modified form rubbery |
US8536239B1 (en) | 2011-05-02 | 2013-09-17 | Chun Well Industry Co. Ltd. | Method for producing improved rubberized concrete using waste rubber tires |
WO2015136290A1 (en) * | 2014-03-12 | 2015-09-17 | Enviromate Limited | Construction material and method of manufacturing the same |
US20230118904A1 (en) * | 2021-10-19 | 2023-04-20 | Halliburton Energy Services, Inc. | Enhanced Carbon Sequestration via Foam Cementing |
US11859122B2 (en) * | 2021-10-19 | 2024-01-02 | Halliburton Energy Services, Inc. | Enhanced carbon sequestration via foam cementing |
Also Published As
Publication number | Publication date |
---|---|
GB0607902D0 (en) | 2006-05-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |