GB2325234A - Highly functionalized polyethylene glycol grafted polystyrene supports - Google Patents

Highly functionalized polyethylene glycol grafted polystyrene supports

Info

Publication number
GB2325234A
GB2325234A GB9815744A GB9815744A GB2325234A GB 2325234 A GB2325234 A GB 2325234A GB 9815744 A GB9815744 A GB 9815744A GB 9815744 A GB9815744 A GB 9815744A GB 2325234 A GB2325234 A GB 2325234A
Authority
GB
United Kingdom
Prior art keywords
poly
ethylene oxide
polymers
polyethylene glycol
graft copolymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB9815744A
Other versions
GB2325234B (en
GB9815744D0 (en
Inventor
Jeffrey William Labadie
Jr John Anthony Porco
Owen Will Gooding
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Argonaut Technologies Inc
Original Assignee
Argonaut Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Argonaut Technologies Inc filed Critical Argonaut Technologies Inc
Publication of GB9815744D0 publication Critical patent/GB9815744D0/en
Publication of GB2325234A publication Critical patent/GB2325234A/en
Application granted granted Critical
Publication of GB2325234B publication Critical patent/GB2325234B/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C08G81/024—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
    • C08G81/025—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/26—Removing halogen atoms or halogen-containing groups from the molecule
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/00277—Apparatus
    • B01J2219/00497—Features relating to the solid phase supports
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Polyethers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

This invention provides novel polymers and graft copolymers of poly(ethylene oxide) and methods for their preparation and purification. The invention provides graft copolymers of a backbone polymer comprising poly(methylstyrene) and side chain polymers of poly(ethylene oxide). The graft copolymers have up to three poly(ethylene oxide) chains per methylstyrene unit in the backbone. The poly(ethylene oxide) chains are attached to the backbone polymer via a 1,3-dioxyprop-2-yl linking group. The polymers of this invention are made by reaction of a 1,3-dicarbonyl nucleophile with a backbone polymer having a leaving group and subsequent modification. The purification methods comprise treating the polymers with a polar protic solvent.
GB9815744A 1996-01-23 1997-01-22 Graft copolymers formed via a 1,3-dioxyprop-2-yl linkage and their uses Expired - Fee Related GB2325234B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US59948696A 1996-01-23 1996-01-23
PCT/US1997/000988 WO1997027226A2 (en) 1996-01-23 1997-01-22 Highly functionalized polyethylene glycol grafted polystyrene supports

Publications (3)

Publication Number Publication Date
GB9815744D0 GB9815744D0 (en) 1998-09-16
GB2325234A true GB2325234A (en) 1998-11-18
GB2325234B GB2325234B (en) 2000-03-01

Family

ID=24399812

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9815744A Expired - Fee Related GB2325234B (en) 1996-01-23 1997-01-22 Graft copolymers formed via a 1,3-dioxyprop-2-yl linkage and their uses

Country Status (5)

Country Link
JP (1) JP2000504368A (en)
AU (1) AU1834697A (en)
DE (1) DE19781535T1 (en)
GB (1) GB2325234B (en)
WO (1) WO1997027226A2 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2223114A1 (en) * 1997-11-28 1999-05-28 Brent R. Stranix Functional polymers with carbon-linked functional groups
GB9814876D0 (en) * 1998-07-10 1998-09-09 Zeneca Ltd Polymer
WO2000053578A1 (en) * 1999-03-11 2000-09-14 Kuraray Co., Ltd. Vitamin d derivatives and process for the preparation thereof
SE9902133D0 (en) 1999-06-06 1999-06-06 Amersham Pharm Biotech Ab A method for surface modification, a novel support matrix and the use of the matrix
US6410643B1 (en) 2000-03-09 2002-06-25 Surmodics, Inc. Solid phase synthesis method and reagent
DE60116799T2 (en) 2000-11-20 2006-09-28 Matrix Innovation Inc. PREPARATION AMPHIPHILER SOLID CARRIER FOR PEPTIDE SYNTHESIS AND BIOORGANIC AND ORGANIC CHEMISTRY
GB0209539D0 (en) * 2002-04-26 2002-06-05 Avecia Ltd Monomer Polymer and process
EP1440995B1 (en) * 2003-01-23 2019-08-07 Rapp Polymere GmbH Hydroxyl-group containing polymers
US7842767B2 (en) 2003-08-04 2010-11-30 Matrix Innovation Inc. Polyether based monomers and highly cross-linked amphiphile resins
EP2159228A1 (en) 2008-08-28 2010-03-03 Polymer Laboratories Limited Amphiphilic solid support
JP5866182B2 (en) * 2011-11-17 2016-02-17 住友ゴム工業株式会社 Copolymer, rubber composition and pneumatic tire
KR20240055715A (en) * 2021-06-14 2024-04-29 윌리엄 마쉬 라이스 유니버시티 Triazole containing polymers and methods of use thereof
CN115160578B (en) * 2022-06-24 2023-09-29 纯钧新材料(深圳)有限公司 Solid-solid phase change material for data center, preparation method and cooling liquid thereof
CN115785564B (en) * 2022-12-05 2023-08-15 广东帅普科技有限公司 High-strength modified PP material

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB771926A (en) * 1954-06-12 1957-04-10 Distillers Co Yeast Ltd Graft copolymers
US2806844A (en) * 1955-10-24 1957-09-17 Colgate Palmolive Co Alkylene oxide addition product of copolymer of a styrene compound and an aliphatic alcohol
EP0187391A2 (en) * 1985-01-04 1986-07-16 Ernst Prof. Dr. Bayer Graft polymers from cross-linked polymers and polyoxyethylene, their preparation and use
US5042990A (en) * 1988-11-28 1991-08-27 Eniricerche S.P.A.-And- Snamprogetti S.P.A. Stabilizer and fluidifier additives for dispersions of coal in water
WO1992004384A1 (en) * 1990-08-31 1992-03-19 Regents Of The University Of Minnesota Polyethylene glycol derivatives for solid-phase applications
EP0580991A2 (en) * 1992-06-29 1994-02-02 Bridgestone Corporation Rubbers, rubber compounds, and rubber curing bladders having self release or low adhesion to curing or cured hydrocarbon rubbers

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB771926A (en) * 1954-06-12 1957-04-10 Distillers Co Yeast Ltd Graft copolymers
US2806844A (en) * 1955-10-24 1957-09-17 Colgate Palmolive Co Alkylene oxide addition product of copolymer of a styrene compound and an aliphatic alcohol
EP0187391A2 (en) * 1985-01-04 1986-07-16 Ernst Prof. Dr. Bayer Graft polymers from cross-linked polymers and polyoxyethylene, their preparation and use
US5042990A (en) * 1988-11-28 1991-08-27 Eniricerche S.P.A.-And- Snamprogetti S.P.A. Stabilizer and fluidifier additives for dispersions of coal in water
WO1992004384A1 (en) * 1990-08-31 1992-03-19 Regents Of The University Of Minnesota Polyethylene glycol derivatives for solid-phase applications
EP0580991A2 (en) * 1992-06-29 1994-02-02 Bridgestone Corporation Rubbers, rubber compounds, and rubber curing bladders having self release or low adhesion to curing or cured hydrocarbon rubbers

Also Published As

Publication number Publication date
GB2325234B (en) 2000-03-01
WO1997027226A2 (en) 1997-07-31
AU1834697A (en) 1997-08-20
DE19781535T1 (en) 1999-01-28
GB9815744D0 (en) 1998-09-16
WO1997027226A3 (en) 1997-10-16
JP2000504368A (en) 2000-04-11

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee

Effective date: 20050122