GB2110693A - An acid-resistant flooring composition - Google Patents
An acid-resistant flooring composition Download PDFInfo
- Publication number
- GB2110693A GB2110693A GB08234498A GB8234498A GB2110693A GB 2110693 A GB2110693 A GB 2110693A GB 08234498 A GB08234498 A GB 08234498A GB 8234498 A GB8234498 A GB 8234498A GB 2110693 A GB2110693 A GB 2110693A
- Authority
- GB
- United Kingdom
- Prior art keywords
- composition
- filler
- chippings
- acid
- resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/12—Flooring or floor layers made of masses in situ, e.g. seamless magnesite floors, terrazzo gypsum floors
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/14—Polyepoxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Floor Finish (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The Specification describes an acid-resistant flooring composition intended principally for industrial use particularly in environments where spillage of acidic substances is a common hazard. The composition comprises an epoxy resin and a filler wherein the filler comprises chippings of an acid-resistant rock or mineral. The filler may also contain sand or silica flour and the chippings may be granite or quartz. The average particle diameter of the chippings is preferably in the 3 mm to 20 mm.
Description
SPECIFICATION
An acid-resistant flooring composition
This invention relates to an acid-resistant flooring composition. The composition is intended principally for industrial use, particularly in environments where spillage of acidic substances is a common hazard.
Acid-resistant flooring compositions based on epoxy resins are well known. They usually contain a filler or extender, which may be silica sand or silica flour or a mixture of the two. One reason for incorporating a filler is to reduce the cost of the composition per unit floor area covered, which cost would be prohibitive in the case of a flooring composition based on epoxy resins without a filler. Another reason is that the silica filler imparts desirable properties to a floor made from a composition containing it, such as hardness and durability.
Nevertheless known acid-resistant epoxy resin flooring compositions have certain disadvantages in use, which include their high cost, and a tendency to craze, split and fragment as a result of temperature variation. Such compositions are normally laid on concrete bases, and have a coefficient of thermal expansion markedly different from that of concrete, which accounts for the above recited behaviour. The compositions are also somewhat deficient in toughness and resistance to wear.
Among the objects of the present invention is the elimination or alleviation of some or all of the above recited disadvantages.
In known compositions the sand filler, as stated, acts as an extender of the expensive epoxy resin.
It is desirable to reduce the cost of epoxy resin flooring compositions as much as possible, by incorporating the maximum proportion of inexpensive filler consistent with adequate properties and performance of the resulting floor. It does not appear to have been realised in the past, just how far one can go in realising this ideal. We have now found, surprisingly, that a ratio as great as 7:1 (filler to unset epoxy resin) can be used with satisfactory results. but only when the additional filler consists largely of sizeable chippings instead of sand.
The present invention accordinyly provides an acid-resistant flooring composition of the type comprising an epoxy resin and a filler, characterised in that the filler comprises chippings of an acidresistant rock or mineral.
Preferably the filler comprises sand and/or silica flour in addition to the chippings. Preferably the chippings are of quartz or granite. It will be clear that minerals such as limestone, marble and chalk are unsuitable for lack of acid-resistance. Preferably the average particle diameter of the chippings is in the range 3 mm to 20 mm.
The proportion of filler in the composition can be expressed in terms of the ratio of the bulk volume of the filler to that of the epoxy resin mixture before it sets. Preferably this ratio is from 5:1 to 7:1, more preferably about 5.5:1.0.
In an embodiment wherein the filler comprises sand as well as chippings the ratio of the bulk volume of the sand to that of the chippings is desirably from 1.2:1.0 to 2.7:1.0, more preferably about 1.75:1.0.
Known compositions containing sand are conventionally laid to a thickness of about 10 mm or 3/8". Compositions of tha invention, however, are conveniently laid to a somewhat greater depth such as 20 to 30 mm. The precise depth required or desirable depends mainly on the mean particle size of the chippings used. The greater depths recommended in the performance of the invention result in floors which are no more expensive than those of the prior art having much smaller depths, and are often less expensive.
It will be seen that the invention exploits the unsuspectedly great covering power of the commercial grades of epoxy resins Heretofore used for making flooring compositions, a covering power which had been by no means exhausted by the incorporation of the low proportions of sand or silica flour heretofore customary. Such grades include for example those marketed for the purpose by Ciba
Geigy of Switzerland under the Trade Mark ARALDITE and its variations.
The invention will be appreciated in greater detail from the following example of a particular and preferred embodiment thereof. Measurements are in parts by volume: in the case of sand and chippings bulk volume is intended, i.e. including the space between the particles.
EXAMPLE
An epoxy resin composition was prepared by intimately mixing 5 parts Araldite base with 3 parts
Araldite hardener. This mixture remains workable for several hours.
To 0.05 m3 of the above mixture was added 0.175 m3 of sharp washed silica sand and 0.1 m3 of sharp quartz chippings of mean particle diameter 12 mm, and the whole thoroughly mixed in a powered blender supplied by the suppliers of the resin.
A pre-existing concrete floor was cleaned of oil and grease, washed with water and allowed to dry, prior to the making up of the above composition.
The composition was deposited on the concrete from the blender, roughly distributed and then trowelled and floated to a mean thickness of 25 mm. Nine further similar batches were made and laid.
The composition was practically self-levelling, and covered in all an area of 128 square meters, where it was allowed to harden.
In 36 hours the hardened composition provided a smooth, even, tough, acid-proof, strongly adhering floor, capable of withstanding a continuous traffic of heavy vehicles with narrow-rimmed steel wheels. Samples of the floor, when tested, proved to have a co-efficient of thermal expansion very near to that of the underlying concrete. Thus a major cause of cracking and crazing had been eliminated: conventional flooring compositions, when set, mostly have a coefficient of thermal expansion greater than that of concrete. A cost comparison showed that the material, with a thickness of 25 mm, was cheaper per unit area than a conventional composition laid to a conventional thickness of 10 mm.
Cupons of the laid composition were cut out for testing. Similarly sized cupons were removed from a typical composition floor of the prior art and used as controls.
Test and control cupons were immersed in various acidic liquors and examined periodically. The
results are set out in the following Tables 1 and 2.
TABLE 1
TESTING FLOORING COMPOUNDS
TEST: Cupons immersed in various liquors for 16 days at 70~C.
% WEIGHT CHANGE APPEARANCE MECHANICAL PROPERTIES Control Test Control Test Control Test Test liquor Cupons Cupons Cupons Cupons Cupons Cupons Sodium citrate +0.7 +0.2 As original Slightly No visible attack N.V.A.
30% W/W discoloured Sodium citrate +1.2 +0.3 As original Slightly N.V.A. N.V.A.
60% W/W discoloured Gluconic acid +3.1 +0.2 Slightly Discoloured N.V.A. N.V.A.
30% W/W discoloured Gluconic acid +2.3 +0.2 Discoloured Discoloured N.V.A. N.V.A.
100% W/W Sulphuric acid +9.0 +0.2 Badly Badly Softened easily broken N.V.A.
2% W/W discoloured discoloured Sulphuric acid +13.1 0 Badly Badly Softened, surface cracked, N.V.A.
10% W/W discoloured discoloured easily broken Citric old liquor +3.4 +0.3 Badly Badly Sl. softening N.V.A.
discoloured discoloured Citric whole broth +2.4 +0.3 Discoloured Slightly N.V.A. N.V.A.
discoloured Sodium hydroxide +0.9 0 Slightly Slightly N.V.A. N.V.A.
46% W/W discoloured discoloured TABLE 2
TEST: Cupons immersed in citric ol liquor 10 days at 90"C.
Test Cupons Control Cupons % weight change + 0.5 + 14.6 Appearance Badly discoloured Badly discoloured Mechanical Soft on removing V. soft and surface Properties from iiquor. cracked on removing, When cooled as when cooled brittle, original. easily broken.
Claims (10)
1. An acid-resistant flooring composition of the type comprising an epoxy resin and a filler characterised in that the filler comprises chippings of an acid-resistant rock or mineral.
2. A composition as claimed in claim 1 wherein the filler additionally comprises sand.
3. A composition as claimed in claim 1 or claim 2 wherein the filler additionally comprises silica flour.
4. A composition as claimed in any of claims 1-3 wherein the chippings are of quartz or granite.
5. A composition as claimed in any of claims 1--4 wherein the average particle diameter of the chippings is in the range 3 mm to 20 mm.
6. A composition as claimed in any of claims 1--6 wherein the ratio of the bulk volume of the filler to that of the epoxy resin mixture before setting is from 5:1 to 7:1.
7. A composition as claimed in claim 6 wherein the ratio of 5.5:1.0.
8. A composition as claimed in claim 2 or claims 3-7 when dependent on claim 2 wherein the ratio of the bulk volume of the sand to that of the chippings is from 1.2:1.0 to 2.7:1.0.
9. A composition as claimed in claim 8 wherein the ratio is 5.5:1.0.
10. A composition as claimed in any of claims 1-9 substantially as hereinbefore described and with reference to the Example.
1 A method of laying a composition as claimed in any of claims 1-10 substantially as hereinbefore described and with reference to the Example.
1 2. An acid-resistant floor which comprises a composition as claimed in any of claims 1-10 substantially as hereinbefore described and with reference to the Example.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IE2864/81A IE52256B1 (en) | 1981-12-04 | 1981-12-04 | An acid-resistant flooring composition |
Publications (1)
Publication Number | Publication Date |
---|---|
GB2110693A true GB2110693A (en) | 1983-06-22 |
Family
ID=11036823
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB08234498A Withdrawn GB2110693A (en) | 1981-12-04 | 1982-12-03 | An acid-resistant flooring composition |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB2110693A (en) |
IE (1) | IE52256B1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0906895A1 (en) * | 1997-06-12 | 1999-04-07 | Gebr. Knauf Westdeutsche Gipswerke | Flooring having a polyepoxide binder and a method of producing the same |
WO2009000941A1 (en) * | 2007-06-26 | 2008-12-31 | Areniscas De Los Pinares Burgos Soria, S.L. | Polymeric sand |
CN104100071A (en) * | 2014-07-09 | 2014-10-15 | 北京亦龙鑫建筑装饰工程有限公司 | Floor paint application method |
CN109424156A (en) * | 2017-08-29 | 2019-03-05 | 王宁 | A kind of oil resistant anti-pollution floor structure level |
-
1981
- 1981-12-04 IE IE2864/81A patent/IE52256B1/en unknown
-
1982
- 1982-12-03 GB GB08234498A patent/GB2110693A/en not_active Withdrawn
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0906895A1 (en) * | 1997-06-12 | 1999-04-07 | Gebr. Knauf Westdeutsche Gipswerke | Flooring having a polyepoxide binder and a method of producing the same |
WO2009000941A1 (en) * | 2007-06-26 | 2008-12-31 | Areniscas De Los Pinares Burgos Soria, S.L. | Polymeric sand |
ES2310486A1 (en) * | 2007-06-26 | 2009-01-01 | Areniscas De Los Pinares Burgos-Soria, S.L. | Polymeric sand |
CN104100071A (en) * | 2014-07-09 | 2014-10-15 | 北京亦龙鑫建筑装饰工程有限公司 | Floor paint application method |
CN109424156A (en) * | 2017-08-29 | 2019-03-05 | 王宁 | A kind of oil resistant anti-pollution floor structure level |
Also Published As
Publication number | Publication date |
---|---|
IE812864L (en) | 1983-06-04 |
IE52256B1 (en) | 1987-08-19 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |