GB1559952A - Lubricating oil compositions - Google Patents
Lubricating oil compositions Download PDFInfo
- Publication number
- GB1559952A GB1559952A GB44555/77A GB4455577A GB1559952A GB 1559952 A GB1559952 A GB 1559952A GB 44555/77 A GB44555/77 A GB 44555/77A GB 4455577 A GB4455577 A GB 4455577A GB 1559952 A GB1559952 A GB 1559952A
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- carbon atoms
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M149/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
- C10M145/12—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
- C10M145/14—Acrylate; Methacrylate
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/108—Residual fractions, e.g. bright stocks
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/06—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/402—Castor oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/028—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
- C10N2070/02—Concentrating of additives
Abstract
The mixture contains a hydrocracked lubricating oil as the base oil and also a) an oil-soluble polyalkyl (meth)acrylate having viscosity index-improving properties and a mean molecular weight (weight average) from 10<3> to 10<6>, in which more than 75 per cent by weight of the alkyl chains have 12 to 15 carbon atoms, in a concentration from 0.001 to 20 per cent by weight and b) an oil-soluble polyalkyl (meth)acrylate having pour point-lowering properties and a mean molecular weight (weight average) from 10<3> to 10<6>, in which at most 75 per cent by weight of the alkyl chains have 12 to 15 carbon atoms and 10 to 90 per cent by weight of the alkyl chains have at least 16 carbon atoms, in a concentration from 0.001 to 5 per cent by weight. Due to the presence of these two additives, a lowering of the pour point is achieved which is greater than that achievable with only the additive b).
Description
(54) LUBRICATING OIL COMPOSITIONS
(71) We, SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ
B.V., a company organised under the laws of the Netherlands, of 30 Carel van
Bylandtlaan, The Hague, The Netherlands, do hereby declare the invention, for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement:- The invention relates to lubricating oil compositions comprising a hydrocracked lubricating oil as a base oil and a mixture of certain oil-soluble polyalkyl(meth)acrylates as pour point depressants.
Hydrocracked lubricating oils such as the oils described in Netherlands patent application 7613854 can be obtained with a very high viscosity index (V.I.) and are therefore particularly suitable as base oils for multigrade engine oil formulations, especially multigrade gasoline and diesel engine oils.
However, for hydrocracked base oils of the extra high V.I. type (XHVI oils having a VI of at least 140 (ASTM D-2270)) it appeared not possible to reduce the pour point which normally is e.g. about -15 C to -330C (ASTM D-97) or lower as required by the current demands for e.g. cold climates, even when using pour point depressants especially designed for use in HVI oils, including hydrocracked
HVI oils, such as the polyalkylmethacrylates described in British patent 1,347,713.
These polyalkylmethacrylates have an average number molecular weight between 2 x 103 and 106, an average number of carbon atoms in the alkyl chains containing 9-18 carbon atoms of 12.4 to 13.7 and at least 6 alkyl chains with a different number of carbon atoms among the alkyl chains containing 9-18 carbon atoms. It has now been found that this problem can be solved by using a special combination of two classes of polyalkyl(meth)acrylates.
Thus the invention relates to a lubricating oil composition comprising a hydrocracked lubricating oil as a base oil and a) 0.00120%w of an oil-soluble polyalkyl(meth)acrylate with VI improving
properties, more than 75%w of the alkyl chains having 12-15 C-atoms, the
weight average molecular weight being 103--10, and b) 0.001-5%w of an oil-soluble polyalkyl(meth)acrylate with pour point
depressing properties, at most 75%w of the alkyl chains having 12-15 C-atoms
and 1090%w of the alkyl chains having at least 16 carbon atoms, the weight
average molecular weight being 103103.
US patent 2,655,479 already discloses that a synergistic pour point depressing effect can be obtained if a mixture of two classes of polyalkylmethacrylates is used.
This mixture principally contains polyalkylmethacrylates with alkyl chains containing 8-18 C-atoms, the average alkyl chain length being about 12.7 and about 13.5, respectively, for the two classes of polymers. This patent is directed to solvent extracted (conventional) oils and nothing is said about the present problem of depressing the pour point of a hydrocracked lubricating oil (unconventional oil).
The lubricating base oil can be a hydrocracked base oil as described in
Netherlands patent application 7613854 including the XHVI oils, the present invention is particularly concerned with. It preferably has a VI of at least 120, more preferably at least 140.
These base oils may be blended with other oils, such as solvent extracted lubricating oils, animal or vegetable oils, synthetic oils, such as polyolefins, ester oils or polyo syalkylene oils, or with residual fractions, such as bright stock, or with hydrotreated fractions, such as hydrotreated extracts of distillates or residues.
Additives (a) can act as a VI-improver and if no other VI improver is present a proportion of 1-10%w is preferred. If another Vi improver is used normally 0.05-l%w of additive (a) is sufficient to obtain the synergistic pour point depressant effect with additive (b).
The alkyl chains containing 12-15 carbon atoms are preferably derived from a mixture of branched and unbranched synthetic alcohols, obtained by hydroformylation, in particular by reacting a mixture of olefins containing 11-14 carbon atoms, with carbon monoxide and hydrogen in the presence of a complex catalyst consisting of cobalt, carbon monoxide and a phosphorous compound.
Normally the latter alcohols contain 5-25Vw branched alkyl chains. In additives (a) at most 25%w of the alkyl(meth)acrylates may be derived from other alcohols, in particular primary alcohols, such as synthetic (unbranched and branched, e.g.
5--25%w branched) Cs~t,-alcohols, synthetic or preferably natural (unbranched)
C16-18-alcohols, lower alcohols having 1-8 carbon atoms or alcohols having more than 18 carbon atoms.
Additives (a) containing in addition to one or more of the above-mentioned monomers a small amount, e.g. at most 100w, of polar monomers such as substituted or unsubstituted vinyl pyridines, substituted or unsubstituted vinyl pyrrolidones or hydroxyl group-containing monomers.
Additives (a) can have weight average molecular weights (Mw) of 2 x 103 to 104, in particular of 5 x 104 to 5 x 105. They preferably have a low molecular weight distribution range to provide a good shear stability, which means that Q = Mw/lWn (Mn = number average molecular weight) should be low, e.g. 1.5-5, such as 2-4.
If desirable they may be pre-sheared.
As mentioned above suitable additives (a) have VI improving properties.
Although they can also act as pour point depressants it will be shown that additives (a) alone do not substantially improve the pour point of XHVI oils.
Preferred additives (b) are described in British patents 1,163,807 and in particular 1,347,713. This means that the C,2~,5-alkyl chains are preferably of the type described above for additives (a), whereas the other alkyl chains are preferably derived from synthetic C9-11-alcohols and/or synthetic or preferably natural C16-18-alcohols and optionally C,~8-alcohols or alcohols having more than 18 carbon atoms. The presence of C, > 18-alcohols in proportions of at least 10%w is particularly desirable. A small amount e.g. at most 10%w, of polar monomers, such as described for additives (a), can also be present.
Preferred proportions of additive (b) are 0.01-2%w.
Additives (b) can have weight average molecular weights (Mw) of 2 x 103 to 104, in particular 2 x 104 to 5 x 105. They preferably have a low Q value of e.g.
1.5-5, such as 2-4.
Additives (a) and (b) can be added, as such or in the form of a concentrate of (a) and/or (b) in a carrier oil to the base oils. The concentrate may e.g. contain 20-75%w (a) and/or (b) in e.g. a mineral lubricating oil as carrier oil.
Other additives can also be used, such as antioxidants, detergents, other VI improvers, anti-corrosion agents, extreme pressure agents, anti-foaming agents, etc.
The invention is illustrated by the following examples.
The additives according to the invention were tested in various hydrocracked base oils.
Base oil 1: a hydrocracked lubricating oil having a pour point of-15 C and a VI of 149.
Base oil 2: base oil 1 + commercial gasoline engine oil additive package.
Base oil 3: 88%w base oil 1 + 12%w hydrotreated bright stock (VI of 95) (VI of mixture being 144).
Base oil 4: base oil 3 + package of base oil 2.
Base oil 5: 89%w base oil 1 + 11%w of above hydrotreated bright stock + commercial diesel engine oil additive package including a VI improver (a hydrogenated styrene/isoprene block copolymer).
Additives a1: Poly C12-15-alkylmethacrylate derived from branched and unbranched (weight ratio 15:85)synthetic C12-15-alcohols(20%w C12, 30%w C13, 30%w C14 and 20%w C15). Mn = 1.35 x 105; Mw = 5.35 x 105; Q = 4.0.
Additive a2: random copolymer of 92.3%w C12-15-alkylmethacrylate (see additive a1) and 7.1%w 2-vinylpyridine. Mw = 63,000; Mn = 223,000; Q = 2.8.
Additive a3:copolymer of 98.0%wC12-15-alkylmethacrylate (see additive a1), 0.9%w
C9-11-alkylmethacrylate (see additive b1) and 1.1%W C16-18-alkylmethacrylate (see additive b1).w = 310,000;n = 93,700; Q = 3.3.
Additive b1: poly C9-18-alkylmethacrylate derived from 43.5%w branched and unbranched (weight ratio 15:85) synthetic C9-11-alcohols (20%w C9, 50%w C10 and 30%w C11), 10.0%w (C12-15-alcohols (see additive a1) and 44.5%w natural C16-18alcohols (30%w C16 and 58%w C18). Mw = 420,000; Mn = 55,000; Q = 7.7.
Additive b2: same composition as additive b,, but:n = 21,200; Mw =46,500; Q = 2.2.
EXAMPLE 1 (base oil 1) TABLE 1 (pour points 'C)
%wb1
%w a1 0 0.1 0.2 0.3
0 -15 -21 -21/-24
0.1 -15 -24 -24
0.2 -15 -24/-27 -30 -30
0.3 -15 -27 -30
0.4 -15 -30 -33
EXAMPLE II (base oil 2)
TABLE 2 (pour points C)
%w b2
%w1 0 0.1 0.2
0 -15 -21 -24
4.0 -15 -36 -36 EXAMPLE III
TABLE 3 (pour points C)
%w b1 %w b2 Base oil %w a1 0 0.03 0.05 0.1 0.2 0.4 0 0.03 0.05 0.1 0.2 0.4 0.6 3 0 -12 - - - - -27 - - - - - -30 3 7.4 -27 -33 -33 -36 -36 -33 -27 -33 -33 -33 -33 -33 4 7.4 -18 -33 -33 -33 -33 -33 -18 -33 -33 -33 -33 -33 5 0 -12 - - -24 -24 -27 -12 -24 -27 -27 5 0.4 - - - - -30 -30 - -27 - -30 -30 -30 -30 5 0.6 -12 -18 -30 -33 -33 -33 -12 -27 -30 -33 -33 -33 5 0.8 -15 -27 -33 - -33 -33 -15 -33 -33 - -33 -33 EXAMPLE IV (base oil 2)
TABLE 4 (pour points C)
%w b2 additive %w 0 0.1 0.2 a2 0 -15 -21 -24 4.0 -15 -36 a3 0 -15 -21 -24 4.0 -21 -36 -36
Claims (1)
- WHAT WE CLAIM IS:1. A lubricating oil composition comprising a hydrocracked lubricating oil as a base oil and a) 0.001-20%w of an oil-soluble polyalkyl(meth)acrylate with VI improving properties, more than 75%w of the alkyl chains having 12-15 C-atoms, the weight average molecular weight being 10 -105, and b) 0.001-5%w of an oil-soluble polyalkyl(meth)acrylate with pour point depressing properties, at most 75%w of the alkyl chains having 12-15 C-atoms and 1090%w of the alkyl chains having at least 16 carbon atoms, the weight average molecular weight being 104-104.2. Composition as claimed in claim 1, in which the viscosity index of the hydrocracked base oil is at least 120.3. Composition as claimed in any one of the preceding claims, in which additive (a) is a polyalkylmethacrylate having branched and unbranched chains; with 12-15 carbon atoms.4. Composition as claimed in any one of the preceding claims, in which additive (a) and/or (b) are derived from monomers at most 10% w of which are polar monomers.5. Composition as claimed in any one of the preceding claims, in which additive (b) is a polyalkylmethacrylate with at least six different alkyl groups having 9-18 carbon atoms.6. Composition as claimed in any one of the preceding claims, in which additive (b) is a polyalkylmethacrylate in which the alkyl groups are derived from alcohols with branched and unbranched chains and 9-15 carbon atoms and straight chain alcohols with 16 and 18 carbon atoms.7. Composition as claimed in any one of the preceding claims, in which the alkyl groups containing 9-15 carbon atoms have 525%w branched chains.8. Composition as claimed in any one of the preceding claims, in which the ratio of the weight average to the number average molecular weight (Q-factor) of the additives (a) and (b) is between 1.5 and 5.10. Composition as claimed in claim 1 substantially as hereinbefore described with special reference to the Examples.11. A concentrate of the additives (a) and (b) as defined in anyone of the preceding claims in a carrier oil.
Priority Applications (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB44555/77A GB1559952A (en) | 1977-10-26 | 1977-10-26 | Lubricating oil compositions |
CA000311808A CA1117517A (en) | 1977-10-26 | 1978-09-21 | Lubricating oil compositions |
BE1009100A BE871277A (en) | 1977-10-26 | 1978-10-16 | LUBRICATING OIL COMPOSITIONS |
JP13012978A JPS5470305A (en) | 1977-10-26 | 1978-10-24 | Lubricating composition |
DE19782846253 DE2846253A1 (en) | 1977-10-26 | 1978-10-24 | LUBRICATING OIL MIXTURES |
DK471778A DK150547C (en) | 1977-10-26 | 1978-10-24 | LUBRICATION OIL PREPARATION AND LUBRICATING OIL CONCENTRATE |
FR7830189A FR2407259A1 (en) | 1977-10-26 | 1978-10-24 | COMPOSITIONS OF LUBRICATING OILS CONTAINING CERTAIN POLYALCOYLACRYLATES OR METHACRYLATES |
AT0761778A AT366091B (en) | 1977-10-26 | 1978-10-24 | LUBRICANTS |
NL7810586A NL190644C (en) | 1977-10-26 | 1978-10-24 | Lube oil compositions. |
SE7811066A SE431225B (en) | 1977-10-26 | 1978-10-24 | LUBRICANE OIL COMPOSITION INCLUDING A HYDROCRAFT BASED OIL ADDED WITH A POLYALKYL (MET) ACRYLATE MIXTURE, AND THE MIXTURE CONCENTRATE |
CH1098778A CH638559A5 (en) | 1977-10-26 | 1978-10-24 | Lubricating oil mixtures |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB44555/77A GB1559952A (en) | 1977-10-26 | 1977-10-26 | Lubricating oil compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1559952A true GB1559952A (en) | 1980-01-30 |
Family
ID=10433843
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB44555/77A Expired GB1559952A (en) | 1977-10-26 | 1977-10-26 | Lubricating oil compositions |
Country Status (11)
Country | Link |
---|---|
JP (1) | JPS5470305A (en) |
AT (1) | AT366091B (en) |
BE (1) | BE871277A (en) |
CA (1) | CA1117517A (en) |
CH (1) | CH638559A5 (en) |
DE (1) | DE2846253A1 (en) |
DK (1) | DK150547C (en) |
FR (1) | FR2407259A1 (en) |
GB (1) | GB1559952A (en) |
NL (1) | NL190644C (en) |
SE (1) | SE431225B (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3339103A1 (en) * | 1983-10-28 | 1985-05-09 | Röhm GmbH, 6100 Darmstadt | ADDITIVES FOR LUBRICANTS |
US4620048A (en) * | 1980-03-26 | 1986-10-28 | Exxon Research & Engineering Co. | Hydrocarbon solutions of macromolecular polymers having an improved resistance to mechanical degradation |
US4822508A (en) * | 1985-12-13 | 1989-04-18 | Rohm Gmbh | Shear stable multirange oils having an improved viscosity index |
US4844829A (en) * | 1987-08-19 | 1989-07-04 | Pennzoil Products Company | Methacrylate pour point depressants and compositions |
US4956111A (en) * | 1987-08-19 | 1990-09-11 | Pennzoil Products Company | Methacrylate pour point depressants and compositions |
US5043087A (en) * | 1986-04-25 | 1991-08-27 | Rohn Gmbh | Addives for paraffinic lubricants |
WO1999010454A2 (en) * | 1997-08-22 | 1999-03-04 | Röhm RohMax Holding GmbH | Mixtures of high- and low-molecular weight poymeric additives for the improvement of the low-temperature fluidity of lubricating oils |
US6255261B1 (en) | 1999-09-22 | 2001-07-03 | Ethyl Corporation | (Meth) acrylate copolymer pour point depressants |
US8143202B2 (en) | 2006-11-07 | 2012-03-27 | Ciba Corp. | Methacrylate copolymer pour point depressants |
WO2013062924A3 (en) * | 2011-10-27 | 2013-07-11 | The Lubrizol Corporation | Lubricating composition containing an esterified polymer |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3607444A1 (en) * | 1986-03-07 | 1987-09-10 | Roehm Gmbh | ADDITIVES FOR MINERAL OILS WITH IMPROVEMENT EFFECT |
US5149452A (en) * | 1990-12-19 | 1992-09-22 | Exxon Research And Engineering Company | Wax isomerate having a reduced pour point |
US5891831A (en) * | 1996-02-20 | 1999-04-06 | Sanyo Chemical Industries, Ltd. | Viscosity index improver, engine lubricant composition, and concentrate |
JP4583137B2 (en) * | 2004-10-22 | 2010-11-17 | Jx日鉱日石エネルギー株式会社 | Lubricating oil composition for transmission |
JP5256205B2 (en) * | 2006-11-07 | 2013-08-07 | チバ ホールディング インコーポレーテッド | Methacrylate copolymer pour point depressant |
WO2008152984A1 (en) * | 2007-06-08 | 2008-12-18 | Toho Chemical Industry Co., Ltd. | Pour point depressant for lubricant |
JP6043245B2 (en) * | 2013-07-05 | 2016-12-14 | Jxエネルギー株式会社 | Poly (meth) acrylate viscosity index improver, and lubricating oil additive and lubricating oil composition containing the viscosity index improver |
JP6077956B2 (en) * | 2013-07-05 | 2017-02-08 | Jxエネルギー株式会社 | Poly (meth) acrylate viscosity index improver, and lubricating oil additive and lubricating oil composition containing the viscosity index improver |
EP2878656B1 (en) | 2012-07-24 | 2018-01-10 | JX Nippon Oil & Energy Corporation | Poly(meth)acrylate-based viscosity index improver, lubricant additive and lubricant composition containing viscosity index improver |
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Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2655479A (en) * | 1949-01-03 | 1953-10-13 | Standard Oil Dev Co | Polyester pour depressants |
GB1347713A (en) * | 1971-05-05 | 1974-02-27 | Shell Int Research | Alkyl methacrylate polymer compositions suitable as luboil additives |
DE2250406A1 (en) * | 1971-05-05 | 1974-04-18 | Sun Oil Co Pennsylvania | Lubricants based on hydrocracked lubricating oils - stabilised by solvent extraction or hydrofining |
-
1977
- 1977-10-26 GB GB44555/77A patent/GB1559952A/en not_active Expired
-
1978
- 1978-09-21 CA CA000311808A patent/CA1117517A/en not_active Expired
- 1978-10-16 BE BE1009100A patent/BE871277A/en not_active IP Right Cessation
- 1978-10-24 SE SE7811066A patent/SE431225B/en not_active IP Right Cessation
- 1978-10-24 AT AT0761778A patent/AT366091B/en not_active IP Right Cessation
- 1978-10-24 DK DK471778A patent/DK150547C/en not_active IP Right Cessation
- 1978-10-24 NL NL7810586A patent/NL190644C/en not_active IP Right Cessation
- 1978-10-24 FR FR7830189A patent/FR2407259A1/en active Granted
- 1978-10-24 JP JP13012978A patent/JPS5470305A/en active Granted
- 1978-10-24 DE DE19782846253 patent/DE2846253A1/en active Granted
- 1978-10-24 CH CH1098778A patent/CH638559A5/en not_active IP Right Cessation
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4620048A (en) * | 1980-03-26 | 1986-10-28 | Exxon Research & Engineering Co. | Hydrocarbon solutions of macromolecular polymers having an improved resistance to mechanical degradation |
US4968444A (en) * | 1983-10-28 | 1990-11-06 | Rohm Gmbh | Lubricating oil additives |
DE3339103A1 (en) * | 1983-10-28 | 1985-05-09 | Röhm GmbH, 6100 Darmstadt | ADDITIVES FOR LUBRICANTS |
US4822508A (en) * | 1985-12-13 | 1989-04-18 | Rohm Gmbh | Shear stable multirange oils having an improved viscosity index |
US5043087A (en) * | 1986-04-25 | 1991-08-27 | Rohn Gmbh | Addives for paraffinic lubricants |
US4844829A (en) * | 1987-08-19 | 1989-07-04 | Pennzoil Products Company | Methacrylate pour point depressants and compositions |
US4956111A (en) * | 1987-08-19 | 1990-09-11 | Pennzoil Products Company | Methacrylate pour point depressants and compositions |
WO1999010454A2 (en) * | 1997-08-22 | 1999-03-04 | Röhm RohMax Holding GmbH | Mixtures of high- and low-molecular weight poymeric additives for the improvement of the low-temperature fluidity of lubricating oils |
WO1999010454A3 (en) * | 1997-08-22 | 1999-05-27 | Roehm Rohmax Holding Gmbh | Mixtures of high- and low-molecular weight poymeric additives for the improvement of the low-temperature fluidity of lubricating oils |
US6458749B2 (en) | 1997-08-22 | 2002-10-01 | Rohmax Additives Gmbh | Method for improving low-temperature fluidity of lubricating oils using high-and-low-molecular weight polymer |
CN1104487C (en) * | 1997-08-22 | 2003-04-02 | 罗麦斯添加剂有限公司 | Method for improvement of low-temp. fluidity of lubricating oil using high- and low-molecular weight polymeric additives |
US6255261B1 (en) | 1999-09-22 | 2001-07-03 | Ethyl Corporation | (Meth) acrylate copolymer pour point depressants |
US8143202B2 (en) | 2006-11-07 | 2012-03-27 | Ciba Corp. | Methacrylate copolymer pour point depressants |
WO2013062924A3 (en) * | 2011-10-27 | 2013-07-11 | The Lubrizol Corporation | Lubricating composition containing an esterified polymer |
Also Published As
Publication number | Publication date |
---|---|
NL7810586A (en) | 1979-05-01 |
NL190644B (en) | 1994-01-03 |
FR2407259B1 (en) | 1982-04-30 |
DK150547B (en) | 1987-03-23 |
CH638559A5 (en) | 1983-09-30 |
ATA761778A (en) | 1981-07-15 |
JPS6224480B2 (en) | 1987-05-28 |
AT366091B (en) | 1982-03-10 |
DE2846253C2 (en) | 1992-12-03 |
SE7811066L (en) | 1979-04-27 |
CA1117517A (en) | 1982-02-02 |
JPS5470305A (en) | 1979-06-06 |
BE871277A (en) | 1979-04-17 |
DE2846253A1 (en) | 1979-05-03 |
NL190644C (en) | 1994-06-01 |
FR2407259A1 (en) | 1979-05-25 |
DK150547C (en) | 1987-09-28 |
SE431225B (en) | 1984-01-23 |
DK471778A (en) | 1979-04-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PE20 | Patent expired after termination of 20 years |
Effective date: 19971025 |