GB1504059A - Method of desulphurizing gases containing hydrogen sulphide - Google Patents
Method of desulphurizing gases containing hydrogen sulphideInfo
- Publication number
- GB1504059A GB1504059A GB29245/75A GB2924575A GB1504059A GB 1504059 A GB1504059 A GB 1504059A GB 29245/75 A GB29245/75 A GB 29245/75A GB 2924575 A GB2924575 A GB 2924575A GB 1504059 A GB1504059 A GB 1504059A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrogen sulphide
- gas
- sulphur
- gases containing
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/046—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process without intermediate formation of sulfur dioxide
- C01B17/0465—Catalyst compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Treating Waste Gases (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
1504059 Hydrogen sulphide removal SOC NATIONALE DES PETROLES D'AQUITAINE 11 July 1975 [11 July 1974] 29245/75 Heading C1A [Also in Division B1] Hydrogen sulphide is recovered as sulphur. vapour from gases containing hydrogen sulphide in low concentrations, preferably 0À2 to 1% by volume, in a process in which the gas together with oxygen is passed over a catalyst consisting of one or more transition metal oxides and/or salts, preferably sulphides, on a porous support at a temperature of from 80‹ to 200‹ C.; the sulphur-laden catalyst is then swept with an oxygen free regeneration gas at a temperature of from 200‹ to 500‹ C. to remove sulphur vapour which may be condensed. The preferred metal oxides, sulphides or salts are those of W, V, Cr, Fe, Co, Ni, Cu, Mo, Ag and Mn. The regeneration gas may contain a reducing gas, hydrogen, hydrogen sulphide or carbon monoxide and preferably is the hydrogen sulphide containing gas which is to be treated in the process, to which may be added a further 5 to 20% by volume of hydrogen sulphide.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7424176A FR2277877A1 (en) | 1974-07-11 | 1974-07-11 | PROCESS FOR DESULFURING GASES CONTAINING HYDROGEN SULPHIDE |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1504059A true GB1504059A (en) | 1978-03-15 |
Family
ID=9141168
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB29245/75A Expired GB1504059A (en) | 1974-07-11 | 1975-07-11 | Method of desulphurizing gases containing hydrogen sulphide |
Country Status (12)
Country | Link |
---|---|
JP (1) | JPS5131697A (en) |
BE (1) | BE831211A (en) |
CA (1) | CA1044440A (en) |
DD (1) | DD121335A5 (en) |
DE (1) | DE2530674A1 (en) |
DK (1) | DK312575A (en) |
FR (1) | FR2277877A1 (en) |
GB (1) | GB1504059A (en) |
IT (1) | IT1039789B (en) |
LU (1) | LU72942A1 (en) |
NL (1) | NL7508279A (en) |
ZA (1) | ZA754426B (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0242920A1 (en) * | 1986-04-16 | 1987-10-28 | Veg-Gasinstituut N.V. | A catalyst for the selective oxidation of sulfur containing compounds, in particular hydrogen sulfide, to elemental sulfur; a process for the preparation of the catalyst; and a process for the selective oxidation of sulfur containing compounds in particular hydrogen sulfide, to elemental sulfur |
AU583982B2 (en) * | 1986-04-16 | 1989-05-11 | Comprimo B.V. | A process for recovering sulfur from sulfur-containing gases |
AU610296B2 (en) * | 1987-11-28 | 1991-05-16 | Comprimo B.V. | A process for the removal of hydrogen sulfide from gases |
US6017507A (en) * | 1995-11-03 | 2000-01-25 | Elf Aquitaine Productiion | Process for oxidation of H2 S to sulphur |
US6083471A (en) * | 1994-11-17 | 2000-07-04 | Elf Exploration Production | Method and catalyst for catalytically oxidizing a low concentration of H2 S in a gas to give sulphur |
GB2443290B (en) * | 2006-10-02 | 2010-03-17 | M I Drilling Fluids Uk Ltd | Separation agent |
CN103521203A (en) * | 2012-06-12 | 2014-01-22 | 中国石油化工股份有限公司 | Aluminum oxide-based sulfur recovery catalyst and preparation method thereof |
CN111715242A (en) * | 2012-11-08 | 2020-09-29 | 代表Mt创新中心的斯塔米卡邦有限公司 | Catalyst for sulfur recovery process for simultaneous production of hydrogen and process for producing the same |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2614307A1 (en) * | 1976-04-02 | 1977-10-13 | Union Oil Co | Hydrogen sulphide removal from feed gas - by contacting the gas with a catalyst to convert hydrogen sulphide to sulphur |
DE2617649C2 (en) * | 1976-04-22 | 1983-03-03 | Metallgesellschaft Ag, 6000 Frankfurt | Process for removing hydrogen sulfide and sulfur dioxide from exhaust gases |
US4124696A (en) * | 1977-11-07 | 1978-11-07 | Standard Oil Company (Indiana) | Method for sealing leakage across valves in a sulfur recovery plant |
DE2752317A1 (en) * | 1977-11-23 | 1979-05-31 | Union Oil Co | Removal of hydrogen sulphide from gas streams - and recovering molten sulphur by catalytic oxidn., esp. for treating tail gas from Claus process |
JPS5647733U (en) * | 1979-09-19 | 1981-04-28 | ||
DE3131257C2 (en) * | 1981-08-07 | 1986-10-30 | VEG-Gasinstituut N.V., Apeldoorn | Process for removing hydrogen sulfide from gases |
FR2511663A1 (en) * | 1981-08-19 | 1983-02-25 | Elf Aquitaine | CATALYTIC PROCESS FOR THE PRODUCTION OF SULFUR FROM A GAS CONTAINING H2S |
NL9202282A (en) * | 1992-12-29 | 1994-07-18 | Gastec Nv | Method for desulfurizing a gas and absorbent suitable for this method. |
JP2701217B2 (en) * | 1994-09-08 | 1998-01-21 | 有限会社三芯製作所 | Mixing device |
DE102005022164B4 (en) * | 2005-05-13 | 2009-08-06 | Lurgi Gmbh | Apparatus and method for operating the apparatus for the continuous recovery of sulfur from H2S-containing gas |
-
1974
- 1974-07-11 FR FR7424176A patent/FR2277877A1/en active Granted
-
1975
- 1975-07-09 DE DE19752530674 patent/DE2530674A1/en not_active Withdrawn
- 1975-07-09 CA CA231,104A patent/CA1044440A/en not_active Expired
- 1975-07-10 DK DK312575A patent/DK312575A/en unknown
- 1975-07-10 ZA ZA00754426A patent/ZA754426B/en unknown
- 1975-07-10 LU LU72942A patent/LU72942A1/xx unknown
- 1975-07-10 BE BE158161A patent/BE831211A/en not_active IP Right Cessation
- 1975-07-10 NL NL7508279A patent/NL7508279A/en not_active Application Discontinuation
- 1975-07-11 JP JP50085195A patent/JPS5131697A/ja active Pending
- 1975-07-11 DD DD187257A patent/DD121335A5/xx unknown
- 1975-07-11 IT IT25290/75A patent/IT1039789B/en active
- 1975-07-11 GB GB29245/75A patent/GB1504059A/en not_active Expired
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0242920A1 (en) * | 1986-04-16 | 1987-10-28 | Veg-Gasinstituut N.V. | A catalyst for the selective oxidation of sulfur containing compounds, in particular hydrogen sulfide, to elemental sulfur; a process for the preparation of the catalyst; and a process for the selective oxidation of sulfur containing compounds in particular hydrogen sulfide, to elemental sulfur |
AU583982B2 (en) * | 1986-04-16 | 1989-05-11 | Comprimo B.V. | A process for recovering sulfur from sulfur-containing gases |
AU583983B2 (en) * | 1986-04-16 | 1989-05-11 | Comprimo B.V. | A catalyst for the selective oxidation of sulfur containing compounds in particular hydrogen sulfide, to elemental sulfur; a process for the preparation of catalyst; and a process for the selective oxidation of sulfur containing compounds in particular hydrogen sulfide,to elemental sulfur |
AU610296B2 (en) * | 1987-11-28 | 1991-05-16 | Comprimo B.V. | A process for the removal of hydrogen sulfide from gases |
US5152970A (en) * | 1987-11-28 | 1992-10-06 | Veg-Gasinstituut N.V. | Process for the removal of hydrogen sulfide from gases |
US6083471A (en) * | 1994-11-17 | 2000-07-04 | Elf Exploration Production | Method and catalyst for catalytically oxidizing a low concentration of H2 S in a gas to give sulphur |
US6017507A (en) * | 1995-11-03 | 2000-01-25 | Elf Aquitaine Productiion | Process for oxidation of H2 S to sulphur |
GB2443290B (en) * | 2006-10-02 | 2010-03-17 | M I Drilling Fluids Uk Ltd | Separation agent |
US8871675B2 (en) | 2006-10-02 | 2014-10-28 | M I Drilling Fluids Uk Ltd. | Method of forming an agent and its use in desulphurisation |
US9987625B2 (en) | 2006-10-02 | 2018-06-05 | M-I Drilling Fluids Uk Limited | Desulfurization agent |
CN103521203A (en) * | 2012-06-12 | 2014-01-22 | 中国石油化工股份有限公司 | Aluminum oxide-based sulfur recovery catalyst and preparation method thereof |
CN111715242A (en) * | 2012-11-08 | 2020-09-29 | 代表Mt创新中心的斯塔米卡邦有限公司 | Catalyst for sulfur recovery process for simultaneous production of hydrogen and process for producing the same |
CN111715242B (en) * | 2012-11-08 | 2024-03-08 | 代表Mt创新中心的斯塔米卡邦有限公司 | Catalyst for sulfur recovery method for simultaneous production of hydrogen and method for producing the same |
Also Published As
Publication number | Publication date |
---|---|
DK312575A (en) | 1976-01-12 |
CA1044440A (en) | 1978-12-19 |
DE2530674A1 (en) | 1976-01-29 |
FR2277877B1 (en) | 1976-12-24 |
LU72942A1 (en) | 1976-02-04 |
FR2277877A1 (en) | 1976-02-06 |
NL7508279A (en) | 1976-01-13 |
ZA754426B (en) | 1976-06-30 |
DD121335A5 (en) | 1976-07-20 |
IT1039789B (en) | 1979-12-10 |
JPS5131697A (en) | 1976-03-17 |
BE831211A (en) | 1975-11-03 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PE20 | Patent expired after termination of 20 years |
Effective date: 19950710 |