GB1476380A - Radiation polymerisable paint - Google Patents

Radiation polymerisable paint

Info

Publication number
GB1476380A
GB1476380A GB2997374A GB2997374A GB1476380A GB 1476380 A GB1476380 A GB 1476380A GB 2997374 A GB2997374 A GB 2997374A GB 2997374 A GB2997374 A GB 2997374A GB 1476380 A GB1476380 A GB 1476380A
Authority
GB
United Kingdom
Prior art keywords
zinc
acrylate
methyl methacrylate
methacrylate
diacrylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2997374A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ford Motor Co Ltd
Ford Motor Co
Original Assignee
Ford Motor Co Ltd
Ford Motor Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ford Motor Co Ltd, Ford Motor Co filed Critical Ford Motor Co Ltd
Publication of GB1476380A publication Critical patent/GB1476380A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/068—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using ionising radiations (gamma, X, electrons)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

1476380 Radiation polymerizable paint FORD MOTOR CO Ltd 5 July 1974 [5 July 1973] 29973/74 Headings C3G and C3P A paint polymerizable by ionizing radiation comprises a paint binder comprising a filmforming solution of an α,#-olefinically unsaturated organic resin containing 0À5-5 units of unsaturation per 1000 of the numerical value of the molecular weight and a compound polymerizable with said resin upon exposure to ionizing radiation, and 0À5-5 wt. per cent based on the total weight of the paint of a zinc salt of an α,#-monounsaturated carboxylic acid. The term "paint" is defined as including finely divided pigment and/or particulate filler, e.g. titania or silica in a film-forming, resin comprising, binder or the binder without pigment and/or particulate filler. The ionizing radiation is preferably electron-beam radiation, and the paints may be polymerized in situ on the substrate, particularly aluminium and steel. The specific examples describe the polymerization of (a) an unsaturated resin formed from methylmethacrylate, ethyl acrylate, glycidyl methacrylate and methacrylic acid and (b) a monomer mixture of methyl methacrylate, isobutyl methacrylate, acrylic acid and either zinc diacrylate or zinc dimethacrylate (1, 2, 3, 4); (a) resin formed from styrene, ethyl acrylate, glycidyl methacrylate and methacrylic acid and (b) monomer mixture of methyl methacrylate, isobutyl methacrylate, acrylic acid and zinc diacrylate (5); (a) resin formed from methylmethacrylate, butyl acrylate, glycidyl methacrylate and methacrylic acid and (b) monomer mixture of methyl methacrylate, isobutyl methacrylate, acrylic acid and zinc diacrylate (6); (a) resin formed from methyl methacrylate, ethyl acrylate, glycidyl methacrylate, and methacrylic acid and (b) monomer mixture of methyl methacrylate, 2-ethyl hexylacrylate, isobutyl acrylate, acrylic acid and either zinc diacrylate, zinc dimethacrylate, zinc dicrotonate or zinc dicinnamate (7, 8, 9, 10); (a) a resin formed from methyl methacrylate, ethyl acrylate, glycidyl methacrylate and (b) monomer mixture of methyl methacrylate, 2-ethylhexyl acrylate, isobutyl acrylate and either zinc diacrylate, zinc dimethacrylate and zinc dicrotonate (11, 12, 13). Examples 14 and 15 refer to polymerization of an unsaturated polyester based on maleic anhydride, tetrahydrophthalic anhydride and neopentyl glycol and styrene in the presence of zinc dimethacrylate and zinc dicrotonate; Examples 16 to 18 the polymerization of a silicone-modified polyester formed from: hydroxyfunctional cyclic polysiloxane, neopentyl glycol, maleic anhydride and tetrahydrophthalic anhydride, styrene and methyl methacrylate in the presence of zinc diacrylate, zinc dimethacrylate and zinc dicinnamate. Example 19 describes the polymerization of a rubber urethane acrylate resin, an unsaturated epoxide, methyl methacrylate and zinc dimethacrylate whilst Examples 20, 21 and 22 describe the polymerization of an α,#-olefinically unsaturated urethane formed from: adipic acid, maleic anhydride, neopentyl glycol, hexamethylene diisocyanate and 2-hydroxyethyl acrylate, 2-ethyl hexyl acrylate, neopentyl glycol diacrylate and either zinc diacrylate, zinc dimethacrylate or zinc dicinnamate.
GB2997374A 1973-07-05 1974-07-05 Radiation polymerisable paint Expired GB1476380A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US37685473A 1973-07-05 1973-07-05

Publications (1)

Publication Number Publication Date
GB1476380A true GB1476380A (en) 1977-06-10

Family

ID=23486780

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2997374A Expired GB1476380A (en) 1973-07-05 1974-07-05 Radiation polymerisable paint

Country Status (5)

Country Link
JP (1) JPS5039334A (en)
DE (1) DE2432356A1 (en)
FR (1) FR2235990B1 (en)
GB (1) GB1476380A (en)
NL (1) NL7409074A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0982327A1 (en) * 1998-08-21 2000-03-01 Sartomer Company Inc. Unsaturated polyester resin compositions comprising metallic monomers

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5035529B2 (en) * 1972-09-19 1975-11-17

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0982327A1 (en) * 1998-08-21 2000-03-01 Sartomer Company Inc. Unsaturated polyester resin compositions comprising metallic monomers
US6472069B1 (en) * 1998-08-21 2002-10-29 Sartomer Technology Company, Inc. Unsaturated polyester resin compositions comprising metallic monomers

Also Published As

Publication number Publication date
FR2235990A1 (en) 1975-01-31
DE2432356A1 (en) 1975-01-30
NL7409074A (en) 1975-01-07
FR2235990B1 (en) 1979-02-16
JPS5039334A (en) 1975-04-11

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee