GB1437143A - Catalysts for treating gases containing sulphur compounds - Google Patents
Catalysts for treating gases containing sulphur compoundsInfo
- Publication number
- GB1437143A GB1437143A GB1515274A GB1515274A GB1437143A GB 1437143 A GB1437143 A GB 1437143A GB 1515274 A GB1515274 A GB 1515274A GB 1515274 A GB1515274 A GB 1515274A GB 1437143 A GB1437143 A GB 1437143A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sulphur
- catalysts
- gases containing
- april
- impurities
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 239000007789 gas Substances 0.000 title abstract 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 abstract 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Substances 0.000 abstract 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 239000012535 impurity Substances 0.000 abstract 2
- 101710178035 Chorismate synthase 2 Proteins 0.000 abstract 1
- 101710152694 Cysteine synthase 2 Proteins 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- 229910010413 TiO 2 Inorganic materials 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 150000001721 carbon Chemical class 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000008188 pellet Substances 0.000 abstract 1
- 239000004291 sulphur dioxide Substances 0.000 abstract 1
- 235000010269 sulphur dioxide Nutrition 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
- 239000002912 waste gas Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/0456—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process the hydrogen sulfide-containing gas being a Claus process tail gas
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
1437143 Treating exhaust gases; alumina RHONE-PROGIL SA 5 April 1974 [9 April 1973] 15152/74 Heading C1A [Also in Division B1] Waste gases containing hydrogen sulphide, sulphur dioxide and carbon derivatives of sulphur as impurities are treated for conversion of the impurities to sulphur, water and carbon dioxide in the presence of a catalyst comprising active alumina and 1 to 60% wt. of a titanium compound. calculated as titania, the catalyst having a specific surface area of at least 80 m.<SP>2</SP>/g. and optionally containing a compound of Mo, Co, Ni, Fe or U. In the examples temperatures of 260-335 C. and contact times of 1 to 8 seconds are used in the treatment of a gas mixture containing H 2 S, SO 2 , CS 2 , H 2 O and N 2 . The catalytic base is made by impregnating Al 2 O 3 pellets with TiCl 4 and calcining or agglomerating Al 2 O 3 with TiO 2 gel or sol.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7312658A FR2224203B1 (en) | 1973-04-09 | 1973-04-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1437143A true GB1437143A (en) | 1976-05-26 |
Family
ID=9117610
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1515274A Expired GB1437143A (en) | 1973-04-09 | 1974-04-05 | Catalysts for treating gases containing sulphur compounds |
Country Status (15)
| Country | Link |
|---|---|
| JP (1) | JPS5137912B2 (en) |
| AT (1) | AT346817B (en) |
| BE (1) | BE813436A (en) |
| CA (1) | CA1060183A (en) |
| ES (1) | ES425072A1 (en) |
| FI (1) | FI58727C (en) |
| FR (1) | FR2224203B1 (en) |
| GB (1) | GB1437143A (en) |
| IL (1) | IL44519A (en) |
| IT (1) | IT1004181B (en) |
| NL (1) | NL182703C (en) |
| NO (1) | NO139157C (en) |
| RO (1) | RO69554A (en) |
| SE (2) | SE403714B (en) |
| SU (1) | SU784739A3 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4552746A (en) * | 1981-11-02 | 1985-11-12 | Roland Kettner | Process for the reduction of the sulfur content in a gaseous stream |
| WO2004007358A1 (en) * | 2002-07-15 | 2004-01-22 | Research Triangle Institute | Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5395893A (en) * | 1977-02-03 | 1978-08-22 | Mizusawa Industrial Chem | Titanium oxide catalyst carrier and manufacture thereof |
| FR2427844A1 (en) * | 1978-06-05 | 1980-01-04 | Raffinage Cie Francaise | PROCESS FOR DEPOSITING ZIRCONIUM AND / OR TITANIUM ON A CATALYST SUPPORT |
| FR2481145A1 (en) * | 1980-04-23 | 1981-10-30 | Rhone Poulenc Ind | PROCESS FOR PRODUCING CATALYSTS OR TITANIUM OXIDE-BASED CATALYST SURFACE SUPPORTS AND THEIR CATALYSIS CLAUS APPLICATIONS |
| FR2540092B1 (en) * | 1983-01-31 | 1986-02-21 | Elf Aquitaine | CATALYTIC PROCESS FOR THE PRODUCTION OF SULFUR FROM A H2S-CONTAINING GAS |
| JPS6158805A (en) * | 1984-08-30 | 1986-03-26 | 三井三池化工機株式会社 | Method of removing nh3 in gas containing s02 |
-
1973
- 1973-04-09 FR FR7312658A patent/FR2224203B1/fr not_active Expired
-
1974
- 1974-03-28 IL IL44519A patent/IL44519A/en unknown
- 1974-04-05 RO RO7478324A patent/RO69554A/en unknown
- 1974-04-05 GB GB1515274A patent/GB1437143A/en not_active Expired
- 1974-04-05 FI FI1050/74A patent/FI58727C/en active
- 1974-04-06 ES ES425072A patent/ES425072A1/en not_active Expired
- 1974-04-08 SE SE7404741A patent/SE403714B/en not_active IP Right Cessation
- 1974-04-08 CA CA197,066A patent/CA1060183A/en not_active Expired
- 1974-04-08 NO NO741293A patent/NO139157C/en unknown
- 1974-04-08 NL NLAANVRAGE7404746,A patent/NL182703C/en not_active IP Right Cessation
- 1974-04-08 JP JP49039745A patent/JPS5137912B2/ja not_active Expired
- 1974-04-08 BE BE142960A patent/BE813436A/en not_active IP Right Cessation
- 1974-04-08 SU SU742014858A patent/SU784739A3/en active
- 1974-04-09 IT IT50265/74A patent/IT1004181B/en active
- 1974-04-09 AT AT294774A patent/AT346817B/en not_active IP Right Cessation
-
1977
- 1977-03-28 SE SE7703550A patent/SE417500B/en not_active IP Right Cessation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4552746A (en) * | 1981-11-02 | 1985-11-12 | Roland Kettner | Process for the reduction of the sulfur content in a gaseous stream |
| US4857297A (en) * | 1981-11-02 | 1989-08-15 | Mobil Oil Corporation | Process for the reduction of the sulfur content in a gaseous stream |
| WO2004007358A1 (en) * | 2002-07-15 | 2004-01-22 | Research Triangle Institute | Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases |
Also Published As
| Publication number | Publication date |
|---|---|
| SU784739A3 (en) | 1980-11-30 |
| NL182703C (en) | 1988-05-02 |
| AT346817B (en) | 1978-11-27 |
| ATA294774A (en) | 1978-04-15 |
| FI58727C (en) | 1981-04-10 |
| NL7404746A (en) | 1974-10-11 |
| NO741293L (en) | 1974-10-10 |
| SE7703550L (en) | 1977-03-28 |
| FR2224203B1 (en) | 1976-11-12 |
| IL44519A (en) | 1976-10-31 |
| JPS5026789A (en) | 1975-03-19 |
| NL182703B (en) | 1987-12-01 |
| RO69554A (en) | 1980-08-15 |
| NO139157B (en) | 1978-10-09 |
| IT1004181B (en) | 1976-07-10 |
| SE417500B (en) | 1981-03-23 |
| SE403714B (en) | 1978-09-04 |
| DE2417092A1 (en) | 1974-10-24 |
| FI58727B (en) | 1980-12-31 |
| CA1060183A (en) | 1979-08-14 |
| ES425072A1 (en) | 1976-11-16 |
| JPS5137912B2 (en) | 1976-10-19 |
| BE813436A (en) | 1974-10-08 |
| FR2224203A1 (en) | 1974-10-31 |
| NO139157C (en) | 1979-01-17 |
| DE2417092B2 (en) | 1976-11-18 |
| IL44519A0 (en) | 1974-06-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PE20 | Patent expired after termination of 20 years |
Effective date: 19940404 |