GB1408560A - Process for the production of hydrogenrich gas - Google Patents
Process for the production of hydrogenrich gasInfo
- Publication number
- GB1408560A GB1408560A GB5498771A GB5498771A GB1408560A GB 1408560 A GB1408560 A GB 1408560A GB 5498771 A GB5498771 A GB 5498771A GB 5498771 A GB5498771 A GB 5498771A GB 1408560 A GB1408560 A GB 1408560A
- Authority
- GB
- United Kingdom
- Prior art keywords
- gas
- conversion
- soot
- water
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 2
- 239000007789 gas Substances 0.000 abstract 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 18
- 238000006243 chemical reaction Methods 0.000 abstract 16
- 239000004071 soot Substances 0.000 abstract 14
- 238000002485 combustion reaction Methods 0.000 abstract 11
- 239000003054 catalyst Substances 0.000 abstract 7
- 239000002918 waste heat Substances 0.000 abstract 7
- 239000002002 slurry Substances 0.000 abstract 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract 4
- 239000001257 hydrogen Substances 0.000 abstract 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 3
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 3
- 238000001816 cooling Methods 0.000 abstract 3
- 239000000295 fuel oil Substances 0.000 abstract 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 239000001569 carbon dioxide Substances 0.000 abstract 2
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 2
- 239000000446 fuel Substances 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract 2
- 239000011733 molybdenum Substances 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 239000003921 oil Substances 0.000 abstract 2
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 abstract 2
- 238000002849 thermal shift Methods 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- 239000013543 active substance Substances 0.000 abstract 1
- 230000003190 augmentative effect Effects 0.000 abstract 1
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000013618 particulate matter Substances 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 239000011949 solid catalyst Substances 0.000 abstract 1
- 150000004763 sulfides Chemical class 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 238000011144 upstream manufacturing Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
- Industrial Gases (AREA)
Abstract
1408560 Hydrogen rich gas SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ NV 24 Nov 1972 [26 Nov 1971] 54987/71 Heading C5E A hydrogen-rich gas stream is produced by partial combustion of a fuel in a substantially hollow combustion chamber, whereby a crude gas predominantly containing hydrogen and carbon monoxide and also containing entrained soot and other particulate matter is obtained, the crude gas is cooled in a waste heat boiler to not below 200 C. and at substantially the same temperature is passed into a zone for the catalytic shift conversion of carbon monoxide and steam to carbon dioxide and hydrogen, in which zone the gases pass through one or more reactors comprising a housing having therein at least one elongated open gas channel with a gas inlet at one end and a gas outlet at the other end and having one or more walls providing thereon or therein or therebehind a cataylst freely accessible to the gas passing through the gas channel(s), and the emanating gases are purified. The soot may be kept in the gas during the conversion and the gas is purified subsequent to the conversion by the removal of water vapour, soot and sour gases, such as carbon dioxide, hydrogen sulphide and carbonyl sulphide. The conversion may be carried out in two or more reactors with intermediate cooling of the gases in between the reactors. A temperature difference between the inlet and outlet of the or each conversion reactor of less than 200 C. may be maintained, with an inlet temperature of the conversion zone, reactor or reactors of 210 to 450 C., and the gases leaving each reactor at below 500 C. The partial combustion is carried out at atmospheric or superatmospheric pressure, the conversion being carried out at substantially the same pressure. The pressure in the conversion reactors may differ from and be less than the pressure in the partial combustion chamber and/or the pressure in the waste heat boiler. Water and/or water vapour is injected into the gas prior to the conversion in the first reactor, and between the reactors when there is a number of separate reactors. Water and/or water vapour is introduced into the combustion chamber, such that the amount of water vapour in the gas that is ultimately available for the conversion is enlarged, more water and/or water vapour being introduced than required for a thermal shift conversion of the carbon monoxide at above 900 C. in and/or upstream of the waste heat boiler, e.g. into the downstream part of the chamber so that the crude gas enters the waste heat boiler at not less than 900 C. A connection or carburettor is provided between the combustion chamber and the waste heat boiler of such cross-section as to increase the residence time of the gases at high temperature whereby the yield of the thermal shift is augmented. Water and/or steam may be injected into the gas in the connection or carburettor. For each 100 Kg fuel that has been partially combusted, 60 to 140 Kg water or 100 to 200 Kg steam, or an equivalent combination of water and steam is introduced into the lower part of the combustion chamber. The soot is partially removed from the crude gas in between the waste heat boiler and the conversion zone by washing it at an elevated temperature with hot oil whereby a slurry of soot in oil is obtained, e.g. fuel oil is used and the slurry is used as at least part of the feed for the partial combustion, or by passing the gas from the waste heat boiler through one or more cyclones and the removed soot recycled for partial combustion, a small amount of liquid, e.g. fuel oil, water or the aqueous soot slurry obtained by a waterwash of the gas subsequent to the conversion, is injected in the underflow or in the conical portion near the apex of the cyclone or cyclones to take up the soot and obtain a concentrated suspension of soot in liquid. Each reactor in the conversion zone may comprise a plurality of substantially parallel open elongated gas channels, catalyst being present between each pair of two adjacent gas channels in catalyst chambers which are separated from the gas channels by gas-permeable channel walls. The reactor internals may comprise a plurality of gauze sheets which are spaced apart and supported by spacing means, alternately leaving the space between two adjacent sheets at opposite ends open to form a gas channel and secluding the space between each one of the sheets and its next adjacent sheet to form a catalyst chamber to be filled with particulate catalyst material; or a plurality of substantially parallel rows of ceramic tiles comprising the catalyst and spaced apart to form substantially open elongated gas channels therebetween, the tiles forming the catalyst-comprising channel walls; or one or more blocks or elements provided with open elongated gas channels, the blocks being made of inert base material and solid catalyst. The catalyst is sulphur-resistant and comprises one or more refractory oxides, e.g. alumina, magnesia, chrome oxide, iron oxide or a mixture thereof, as the carrier and one or more metals from Groups VI to VIII of the Periodic System, e.g. cobalt, molybdenum and/or nickel, as the active agent, which metals are either used as such or as their sulphides. The catalyst may comprise about 3À5% by wt. nickel and about 8% by wt. molybdenum based on alumina. The partial pressure of the hydrogen sulphide in the gas leaving the water heat boiler may be 0À1 to 0À7 atmospheres. The soot remaining in the gas subsequent to the conversion is removed by water wash and a dilute aqueous soot slurry is obtained which may be passed on to a pelletizer when the soot is agglomerated by means of hydrocarbons and the agglomerates are separated and taken up in a fuel oil which is recycled to the combustion zone, or the dilute slurry or part thereof may be introduced directly into the combustion zone or combined with the relatively concentrated aqueous soot slurry obtained from the cyclone(s). The gases may then be further cooled and freed from undesirable components. All or at least a major amount of water is recycled in the process. The water wash to remove soot after the conversion constitutes the first of two cooling stages, the remaining water vapour being removed from the gas as clean water in the second cooling stage.
Priority Applications (14)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5498771A GB1408560A (en) | 1971-11-26 | 1971-11-26 | Process for the production of hydrogenrich gas |
CA154,739A CA989173A (en) | 1971-11-26 | 1972-10-24 | Process for the production of a hydrogen-rich gas |
BE791610D BE791610A (en) | 1971-11-26 | 1972-11-20 | PROCESS FOR THE PREPARATION OF HYDROGEN-FILLED GAS |
IT31864/72A IT972249B (en) | 1971-11-26 | 1972-11-20 | PROCESS FOR THE PRODUCTION OF GAS RICH IN HYDROGEN |
CS7200007927A CS184318B2 (en) | 1971-11-26 | 1972-11-22 | Reactor for catalytic conversion of carbonmonoxide by steam to carbondioxide and hydrogene |
FR7241817A FR2161045B1 (en) | 1971-11-26 | 1972-11-24 | |
ZA728354A ZA728354B (en) | 1971-11-26 | 1972-11-24 | Process for the production of a hydrogen-rich gas |
DE2257733A DE2257733A1 (en) | 1971-11-26 | 1972-11-24 | PROCESS FOR PRODUCING A HYDROGEN-RICH GAS |
SU1852109A SU598553A3 (en) | 1971-11-26 | 1972-11-24 | Method of obtaining hydrogen-containing gas |
SE7215398A SE394192B (en) | 1971-11-26 | 1972-11-24 | PROCEDURE FOR CONVERSION AND PURIFICATION OF A RAGAS FOR THE PURPOSE OF GETTING A VETERIC GAS STRUM, WHICH RAGAS MAINLY CONTAINS WHEAT AND CARBON MONOXIDE AND SOOT PARTICULARS |
AU49274/72A AU476625B2 (en) | 1971-11-26 | 1972-11-24 | Process forthe production ofa hydrogen-rich gas |
JP47117917A JPS4863986A (en) | 1971-11-26 | 1972-11-24 | |
DD167078A DD101694A5 (en) | 1971-11-26 | 1972-11-24 | |
NL7215933A NL7215933A (en) | 1971-11-26 | 1972-11-24 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5498771A GB1408560A (en) | 1971-11-26 | 1971-11-26 | Process for the production of hydrogenrich gas |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1408560A true GB1408560A (en) | 1975-10-01 |
Family
ID=10472637
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5498771A Expired GB1408560A (en) | 1971-11-26 | 1971-11-26 | Process for the production of hydrogenrich gas |
Country Status (14)
Country | Link |
---|---|
JP (1) | JPS4863986A (en) |
AU (1) | AU476625B2 (en) |
BE (1) | BE791610A (en) |
CA (1) | CA989173A (en) |
CS (1) | CS184318B2 (en) |
DD (1) | DD101694A5 (en) |
DE (1) | DE2257733A1 (en) |
FR (1) | FR2161045B1 (en) |
GB (1) | GB1408560A (en) |
IT (1) | IT972249B (en) |
NL (1) | NL7215933A (en) |
SE (1) | SE394192B (en) |
SU (1) | SU598553A3 (en) |
ZA (1) | ZA728354B (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5030440A (en) * | 1988-07-22 | 1991-07-09 | Imperial Chemical Industries Plc | Hydrogen production |
US6083425A (en) | 1996-08-26 | 2000-07-04 | Arthur D. Little, Inc. | Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide |
US6245303B1 (en) | 1998-01-14 | 2001-06-12 | Arthur D. Little, Inc. | Reactor for producing hydrogen from hydrocarbon fuels |
US6641625B1 (en) | 1999-05-03 | 2003-11-04 | Nuvera Fuel Cells, Inc. | Integrated hydrocarbon reforming system and controls |
CN100361889C (en) * | 2006-03-16 | 2008-01-16 | 五环科技股份有限公司 | Secondary transformation technological method of high concentration carbon monooxide |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DK148915C (en) * | 1980-03-21 | 1986-06-02 | Haldor Topsoe As | METHOD FOR PREPARING HYDROGEN OR AMMONIA SYNTHESIC GAS |
DE3223702C2 (en) * | 1982-06-25 | 1984-06-28 | M.A.N. Maschinenfabrik Augsburg-Nürnberg AG, 4200 Oberhausen | Process for generating synthesis gas and reactor for carrying out the process |
DE4318444C2 (en) * | 1993-06-03 | 1997-01-23 | Bfi Entsorgungstech | Process for high-temperature conversion |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB517530A (en) * | 1938-07-23 | 1940-02-01 | Gas Light & Coke Co | Process for the manufacture of water gas enriched with hydrogen |
US2960388A (en) * | 1956-12-17 | 1960-11-15 | Hydrocarbon Research Inc | Shift reaction with fluidized catalyst |
FR1274183A (en) * | 1959-11-25 | 1961-10-20 | Basf Ag | Process for the catalytic conversion of carbon monoxide, using water vapor, into hydrogen and carbon dioxide |
DE1247279B (en) * | 1963-01-19 | 1967-08-17 | Basf Ag | Process for the catalytic conversion of gases containing carbon oxide which contain resin-forming substances |
-
1971
- 1971-11-26 GB GB5498771A patent/GB1408560A/en not_active Expired
-
1972
- 1972-10-24 CA CA154,739A patent/CA989173A/en not_active Expired
- 1972-11-20 BE BE791610D patent/BE791610A/en unknown
- 1972-11-20 IT IT31864/72A patent/IT972249B/en active
- 1972-11-22 CS CS7200007927A patent/CS184318B2/en unknown
- 1972-11-24 DE DE2257733A patent/DE2257733A1/en active Pending
- 1972-11-24 DD DD167078A patent/DD101694A5/xx unknown
- 1972-11-24 SE SE7215398A patent/SE394192B/en unknown
- 1972-11-24 SU SU1852109A patent/SU598553A3/en active
- 1972-11-24 FR FR7241817A patent/FR2161045B1/fr not_active Expired
- 1972-11-24 NL NL7215933A patent/NL7215933A/xx not_active Application Discontinuation
- 1972-11-24 JP JP47117917A patent/JPS4863986A/ja active Pending
- 1972-11-24 AU AU49274/72A patent/AU476625B2/en not_active Expired
- 1972-11-24 ZA ZA728354A patent/ZA728354B/en unknown
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5030440A (en) * | 1988-07-22 | 1991-07-09 | Imperial Chemical Industries Plc | Hydrogen production |
US6083425A (en) | 1996-08-26 | 2000-07-04 | Arthur D. Little, Inc. | Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide |
US6123913A (en) | 1996-08-26 | 2000-09-26 | Arthur D. Little, Inc. | Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide |
US6126908A (en) * | 1996-08-26 | 2000-10-03 | Arthur D. Little, Inc. | Method and apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide |
US6207122B1 (en) | 1996-08-26 | 2001-03-27 | Arthur D. Little, Inc. | Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide |
US6254839B1 (en) | 1996-08-26 | 2001-07-03 | Arthur D. Little, Inc. | Apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide |
US6468480B1 (en) | 1996-08-26 | 2002-10-22 | Lawrence G. Clawson | Apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide |
US6245303B1 (en) | 1998-01-14 | 2001-06-12 | Arthur D. Little, Inc. | Reactor for producing hydrogen from hydrocarbon fuels |
US6783742B2 (en) | 1998-01-14 | 2004-08-31 | Nuvera Fuel Cells | Reactor for producing hydrogen from hydrocarbon fuels |
US6641625B1 (en) | 1999-05-03 | 2003-11-04 | Nuvera Fuel Cells, Inc. | Integrated hydrocarbon reforming system and controls |
CN100361889C (en) * | 2006-03-16 | 2008-01-16 | 五环科技股份有限公司 | Secondary transformation technological method of high concentration carbon monooxide |
Also Published As
Publication number | Publication date |
---|---|
ZA728354B (en) | 1973-07-25 |
NL7215933A (en) | 1973-05-29 |
BE791610A (en) | 1973-05-21 |
FR2161045A1 (en) | 1973-07-06 |
CA989173A (en) | 1976-05-18 |
JPS4863986A (en) | 1973-09-05 |
SU598553A3 (en) | 1978-03-15 |
AU476625B2 (en) | 1976-09-30 |
IT972249B (en) | 1974-05-20 |
FR2161045B1 (en) | 1975-11-07 |
DE2257733A1 (en) | 1973-05-30 |
DD101694A5 (en) | 1973-11-12 |
SE394192B (en) | 1977-06-13 |
CS184318B2 (en) | 1978-08-31 |
AU4927472A (en) | 1974-05-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |