GB1402832A - Asymmetric hydroformylation - Google Patents

Asymmetric hydroformylation

Info

Publication number
GB1402832A
GB1402832A GB5597973A GB5597973A GB1402832A GB 1402832 A GB1402832 A GB 1402832A GB 5597973 A GB5597973 A GB 5597973A GB 5597973 A GB5597973 A GB 5597973A GB 1402832 A GB1402832 A GB 1402832A
Authority
GB
United Kingdom
Prior art keywords
asymmetric hydroformylation
hydroformylation
asymmetric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5597973A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH1779172A external-priority patent/CH572456A5/en
Priority claimed from CH316273A external-priority patent/CH574383A5/en
Application filed by Individual filed Critical Individual
Publication of GB1402832A publication Critical patent/GB1402832A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0267—Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C07C45/505—Asymmetric hydroformylation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/36—Oxygen or sulfur atoms
    • C07D207/40—2,5-Pyrrolidine-diones
    • C07D207/404—2,5-Pyrrolidine-diones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. succinimide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/20—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0286—Complexes comprising ligands or other components characterized by their function
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
GB5597973A 1972-12-04 1973-12-03 Asymmetric hydroformylation Expired GB1402832A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH1779172A CH572456A5 (en) 1972-12-04 1972-12-04 Asymmetric hydroformylation of olefins - in presence of rhodium catalyst and optically active cpd, giving aldehydes in high optical yield
CH316273A CH574383A5 (en) 1973-03-02 1973-03-02 Asymmetric hydroformylation of olefins - in presence of rhodium catalyst and optically active cpd, giving aldehydes in high optical yield

Publications (1)

Publication Number Publication Date
GB1402832A true GB1402832A (en) 1975-08-13

Family

ID=25692345

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5597973A Expired GB1402832A (en) 1972-12-04 1973-12-03 Asymmetric hydroformylation

Country Status (4)

Country Link
JP (1) JPS4986310A (en)
DE (1) DE2359101A1 (en)
FR (2) FR2219141B1 (en)
GB (1) GB1402832A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2385671A1 (en) * 1977-03-31 1978-10-27 Celanese Corp HYDROFORMYLATION PROCESS USING A CATALYTIC COMPLEX BASED ON RHODIUM AND DIPHOSPHINO LIGANDS
US4169861A (en) * 1977-08-19 1979-10-02 Celanese Corporation Hydroformylation process
US4221744A (en) * 1978-12-01 1980-09-09 Celanese Corporation Hydroformylation process employing rhodium-based catalysts comprising ligands having electronegative substituents
US5360938A (en) * 1991-08-21 1994-11-01 Union Carbide Chemicals & Plastics Technology Corporation Asymmetric syntheses
CN104781228A (en) * 2012-11-09 2015-07-15 三井化学株式会社 Method for producing aldehyde compound
US9487475B2 (en) 2012-11-09 2016-11-08 Mitsui Chemicals, Inc. Preparation method of aldehyde compound with limited amount of acrylonitrile

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2649900A1 (en) * 1975-11-05 1977-05-12 Firestone Tire & Rubber Co PROCESS FOR THE PRODUCTION OF GAMMA HYDROXYTETRAHYDROFURAN OR TETRAHYDROFURAN
US4193943A (en) * 1976-01-19 1980-03-18 Celanese Corporation Hydroformylation catalysts
EP0033554B1 (en) * 1980-02-04 1983-11-09 Shell Internationale Researchmaatschappij B.V. A process for the hydroformylation of conjugated dienes
JPS5832841A (en) * 1981-08-22 1983-02-25 Nippon Petrochem Co Ltd Ethylnorbornyl-2-aldehyde and its preparation
IT1140319B (en) * 1981-12-04 1986-09-24 Consiglio Nazionale Ricerche CATALYST CONTAINING CHIRAL STEROID PHOSPHINS ASYMMETRICAL CATALYTIC PRECESSES THAT USE THEM

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2385671A1 (en) * 1977-03-31 1978-10-27 Celanese Corp HYDROFORMYLATION PROCESS USING A CATALYTIC COMPLEX BASED ON RHODIUM AND DIPHOSPHINO LIGANDS
US4139565A (en) * 1977-03-31 1979-02-13 Celanese Corporation Hydroformylation using improved catalysts comprising rhodium and diphosphino ligands
US4169861A (en) * 1977-08-19 1979-10-02 Celanese Corporation Hydroformylation process
US4221744A (en) * 1978-12-01 1980-09-09 Celanese Corporation Hydroformylation process employing rhodium-based catalysts comprising ligands having electronegative substituents
US5360938A (en) * 1991-08-21 1994-11-01 Union Carbide Chemicals & Plastics Technology Corporation Asymmetric syntheses
US5491266A (en) * 1991-08-21 1996-02-13 Union Carbide Chemicals & Plastics Technology Corporation Asymmetric syntheses
CN104781228A (en) * 2012-11-09 2015-07-15 三井化学株式会社 Method for producing aldehyde compound
EP2918575A4 (en) * 2012-11-09 2016-07-13 Mitsui Chemicals Inc Method for producing aldehyde compound
US9475760B2 (en) 2012-11-09 2016-10-25 Mitsui Chemicals, Inc. Preparation method of aldehyde compound using a metal compound and a phosphorus compound
US9487475B2 (en) 2012-11-09 2016-11-08 Mitsui Chemicals, Inc. Preparation method of aldehyde compound with limited amount of acrylonitrile

Also Published As

Publication number Publication date
DE2359101A1 (en) 1974-06-06
JPS4986310A (en) 1974-08-19
FR2219141A1 (en) 1974-09-20
FR2219141B1 (en) 1977-06-10
FR2230612B1 (en) 1977-10-14
FR2230612A1 (en) 1974-12-20

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Legal Events

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PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee