GB1387909A - Treatment of brines by chlorination - Google Patents
Treatment of brines by chlorinationInfo
- Publication number
- GB1387909A GB1387909A GB1620472A GB1620472A GB1387909A GB 1387909 A GB1387909 A GB 1387909A GB 1620472 A GB1620472 A GB 1620472A GB 1620472 A GB1620472 A GB 1620472A GB 1387909 A GB1387909 A GB 1387909A
- Authority
- GB
- United Kingdom
- Prior art keywords
- brine
- carboxylic
- chlorine
- pka value
- materials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005660 chlorination reaction Methods 0.000 title 1
- 239000012267 brine Substances 0.000 abstract 12
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 abstract 12
- 239000000463 material Substances 0.000 abstract 4
- 150000003839 salts Chemical class 0.000 abstract 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 2
- 150000001735 carboxylic acids Chemical class 0.000 abstract 2
- 239000000460 chlorine Substances 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 239000005708 Sodium hypochlorite Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910001617 alkaline earth metal chloride Inorganic materials 0.000 abstract 1
- -1 alkylene glycols Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 abstract 1
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical class OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 abstract 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid group Chemical group C(CCCCC)(=O)O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 230000001678 irradiating effect Effects 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 239000011368 organic material Substances 0.000 abstract 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/123—Ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D3/00—Halides of sodium, potassium or alkali metals in general
- C01D3/14—Purification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
1387909 Treating brines DOW CHEMICAL CO 7 April 1972 16204/72 Heading ClC The concentration of one or more carboxylic materials (as defined), in brine containing at least 1% by wt. of alkali metal and/or alkaline earth metal chlorides, is reduced by contacting the brine with chlorine and irradiating the brine with light having a wavelength of less than 3600Š. The carboxylic materials are watersoluble carboxylic acids, salts thereof and organic materials (e.g. alkylene glycols, alcohols, aldehydes, ketones, amines), which when treated in brine with chlorine form watersoluble carboxylic acids. The pH of the brine is maintained within the range from 2À5 units less than to 1À0 unit more than the pKa value of the brine, which pKa value is defined as the pKa value of the carboxylic acid or salt present in or formed in the brine when the brine contains only one carboxylic material or the weighted average of the pKa values of the individual acid(s) and/or salt(s) when the brine contains more than one carboxylic material. The brine may comprise formic, acetic, propionic, burytic, valeric, hexanoic and chloroacetic acids or salts thereof. The brine may be treated with chloride gas or chlorine produced in situ electrolytically or by use of sodium hypochlorite. The brine may be heated during the process. The light source may be sunlight or a mercury arc. Chlorinated hydrocarbons produced in the process may be collected.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1620472A GB1387909A (en) | 1972-04-07 | 1972-04-07 | Treatment of brines by chlorination |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1620472A GB1387909A (en) | 1972-04-07 | 1972-04-07 | Treatment of brines by chlorination |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1387909A true GB1387909A (en) | 1975-03-19 |
Family
ID=10073049
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1620472A Expired GB1387909A (en) | 1972-04-07 | 1972-04-07 | Treatment of brines by chlorination |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1387909A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4372860A (en) | 1979-05-30 | 1983-02-08 | H. & P. Kaas System Teknik Aps | Method and an apparatus for cleaning water in a swimming pool |
| US4415460A (en) * | 1979-07-30 | 1983-11-15 | The Lummus Company | Oxidation of organics in aqueous salt solutions |
| FR2598403A1 (en) * | 1986-05-07 | 1987-11-13 | Dampier Salt Ltd | INDUSTRIAL SALT PRODUCTION |
| CN107156608A (en) * | 2017-05-27 | 2017-09-15 | 郑州大学 | A kind of method of peculiar smell in removal purified salt |
-
1972
- 1972-04-07 GB GB1620472A patent/GB1387909A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4372860A (en) | 1979-05-30 | 1983-02-08 | H. & P. Kaas System Teknik Aps | Method and an apparatus for cleaning water in a swimming pool |
| US4415460A (en) * | 1979-07-30 | 1983-11-15 | The Lummus Company | Oxidation of organics in aqueous salt solutions |
| FR2598403A1 (en) * | 1986-05-07 | 1987-11-13 | Dampier Salt Ltd | INDUSTRIAL SALT PRODUCTION |
| CN107156608A (en) * | 2017-05-27 | 2017-09-15 | 郑州大学 | A kind of method of peculiar smell in removal purified salt |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |