GB1383447A - Rechargeable solid state electrochemical cell having a lithium anode and a method of manufacturing the same - Google Patents

Rechargeable solid state electrochemical cell having a lithium anode and a method of manufacturing the same

Info

Publication number
GB1383447A
GB1383447A GB963972A GB963972A GB1383447A GB 1383447 A GB1383447 A GB 1383447A GB 963972 A GB963972 A GB 963972A GB 963972 A GB963972 A GB 963972A GB 1383447 A GB1383447 A GB 1383447A
Authority
GB
United Kingdom
Prior art keywords
solvent
lithium
separator
binder
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB963972A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Alcatel Lucent SAS
Original Assignee
Compagnie Generale dElectricite SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Compagnie Generale dElectricite SA filed Critical Compagnie Generale dElectricite SA
Publication of GB1383447A publication Critical patent/GB1383447A/en
Expired legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562—Solid materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)
  • Cell Separators (AREA)

Abstract

1383447 Solid state cell with lithium anode COMPAGNIE GENERALE D'ELECTRICITE 1 March 1972 [4 March 1971] 9639/72 Heading H1B A rechargeable cell comprises a number of thin solid layers, these layers comprising, in order, (i) a cathodic collector, e.g. of silver; (ii) a catholyte capable of supplying anions which can form a salt with lithium, e.g. silver iodide; (iii) a separator consisting of a lithium salt, e.g. lithium iodide, and a material having a solid structure, the separator being an ionic conductor, an electron insulator, and being impermeable to the catholyte, and (iv) a lithium anode. The separator is made by a method which ensures that the lithium salt is present at least partially in solvate form whereby the ionic conductivity of the separator is increased. The method of the making the separator comprises putting the lithium salt in solution in a solvent and in forming a thin solid layer with that solution and the solid structure material. The solvent may comprise at least one of the following:-water, methanol, ethanol, acetone, acetamide, N-methylacetamide, N-methylformamide, N-methyl-2-pyrrolidone, isopropylamine, propylene carbonate, formic aldehyde. In a specific example of performing the method, a soluble organic binder is added to the solution of the lithium salt in the solvent. When the solvent is water, the binder is selected from the group polyvinylic alcohol and carboxymethylcellulose. When the solvent is methanol or ethanol the binder is selected from vinyl polyacetate, polyvinyl butyral, polyvinyl pyrrolidone, polyvinylic ethers, resols or formal-phenol prepolymeric resins and monomeric methacrylates. When the solvent is acetone the binder is selected from polymethacrylates, polystyrene, acrylonitrile, styrene, vinyl acetate and methacrylates. This solution is applied to a thin solid porous inert layer, constituting the solid structure material, so as to impregnate it. Heat is applied to evaporate the solvent. In other methods described, the binder constitutes the solid structure material.
GB963972A 1971-03-04 1972-03-01 Rechargeable solid state electrochemical cell having a lithium anode and a method of manufacturing the same Expired GB1383447A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR717107529A FR2128102B2 (en) 1971-03-04 1971-03-04

Publications (1)

Publication Number Publication Date
GB1383447A true GB1383447A (en) 1974-02-12

Family

ID=9072922

Family Applications (1)

Application Number Title Priority Date Filing Date
GB963972A Expired GB1383447A (en) 1971-03-04 1972-03-01 Rechargeable solid state electrochemical cell having a lithium anode and a method of manufacturing the same

Country Status (10)

Country Link
BE (1) BE779750A (en)
CA (1) CA979481A (en)
CH (1) CH542521A (en)
DE (1) DE2209086C3 (en)
DK (1) DK130097B (en)
FR (1) FR2128102B2 (en)
GB (1) GB1383447A (en)
IT (1) IT949834B (en)
NL (1) NL7202817A (en)
SE (1) SE378710B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1019598B (en) * 1973-05-18 1977-11-30 Comp Generale Electricite ELECTROCHEMICAL ELEMENTS WITH THIN LAYERS
FR2442513A1 (en) * 1978-11-22 1980-06-20 Anvar Electrochemical generator for electric current prodn. - using solid soln. of ionic cpd. in polymer pref. polyoxyalkylene as electrolyte
FR2442512A1 (en) * 1978-11-22 1980-06-20 Anvar NEW ELASTOMERIC MATERIALS WITH ION CONDUCTION
US4378385A (en) * 1980-03-28 1983-03-29 United Kingdom Atomic Energy Authority Method of making oxygen ion conducting solid electrolyte device
DE3511703A1 (en) * 1985-03-29 1986-10-02 Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V., 3400 Göttingen LITHIUMION LADDER
DE3920129A1 (en) * 1988-06-21 1989-12-28 Ricoh Kk ELECTROCHEMICAL DEVICE

Also Published As

Publication number Publication date
FR2128102B2 (en) 1974-02-15
CH542521A (en) 1973-09-30
FR2128102A2 (en) 1972-10-20
CA979481A (en) 1975-12-09
DE2209086C3 (en) 1981-02-26
NL7202817A (en) 1972-09-06
DE2209086B2 (en) 1980-06-12
DK130097B (en) 1974-12-16
DE2209086A1 (en) 1972-09-14
SE378710B (en) 1975-09-08
IT949834B (en) 1973-06-11
BE779750A (en) 1972-08-24
DK130097C (en) 1975-06-02

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee