GB1376587A - Process for the liquid phase chlorination of c8-c16 hydrocarbons - Google Patents
Process for the liquid phase chlorination of c8-c16 hydrocarbonsInfo
- Publication number
- GB1376587A GB1376587A GB2568973A GB2568973A GB1376587A GB 1376587 A GB1376587 A GB 1376587A GB 2568973 A GB2568973 A GB 2568973A GB 2568973 A GB2568973 A GB 2568973A GB 1376587 A GB1376587 A GB 1376587A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ccl
- additive
- paraffin
- hydrocarbons
- liquid phase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1376587 C 8-16 chlorohydrocarbons NEVILLE CHEMICAL CO 30 May 1973 [29 June 1972] 25689/73 Heading C2C C 8-16 chlorinated hydrocarbons are produced by chlorinating a paraffin hydrocarbon mixture having an average 8-16 C atoms per molecule in the presence of 2 to 20% by weight, based on the weight of said paraffin hydrocarbon mixture, of CCl 4 , CHCl 3 , ClCH 2 CH 2 Cl, CH 3 CCl 3 , ClCH 2 CHCl 2 or CCl 3 CCl 3 , said paraffin being present in the liquid state in contact during at least a portion of the reaction with paraffin hydrocarbon vapour and gaseous chlorine and said additive being at least partially volatilized and present in the gaseous mixture in contact with the liquid hydrocarbon. The reaction is preferably conducted at 80‹ to 120‹C. with a 5 to 10% concentration of additive. The preferred additive is CCl 4 .
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US26744472A | 1972-06-29 | 1972-06-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1376587A true GB1376587A (en) | 1974-12-04 |
Family
ID=23018798
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2568973A Expired GB1376587A (en) | 1972-06-29 | 1973-05-30 | Process for the liquid phase chlorination of c8-c16 hydrocarbons |
Country Status (4)
Country | Link |
---|---|
DE (1) | DE2332170A1 (en) |
FR (1) | FR2190783B1 (en) |
GB (1) | GB1376587A (en) |
IT (1) | IT989438B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2569182B1 (en) * | 1984-08-20 | 1986-12-05 | Solvay | PROCESS FOR PERFORMING REACTIONS OF SUBSTITUTIVE CHLORINATION OF ORGANIC COMPOUNDS BY MEANS OF MOLECULAR CHLORINE IN THE PRESENCE OF A CHLORINE PRODUCT AS RADICAL INITIATOR AND RADICAL INITIATORS USED IN SUCH A PROCESS |
-
1973
- 1973-05-30 GB GB2568973A patent/GB1376587A/en not_active Expired
- 1973-06-25 DE DE19732332170 patent/DE2332170A1/en active Pending
- 1973-06-25 IT IT2579673A patent/IT989438B/en active
- 1973-06-29 FR FR7324080A patent/FR2190783B1/fr not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR2190783A1 (en) | 1974-02-01 |
FR2190783B1 (en) | 1978-06-30 |
IT989438B (en) | 1975-05-20 |
DE2332170A1 (en) | 1974-01-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed |