GB1310760A - Supersensitized silver halide photographic emulsions - Google Patents
Supersensitized silver halide photographic emulsionsInfo
- Publication number
- GB1310760A GB1310760A GB2499470A GB2499470A GB1310760A GB 1310760 A GB1310760 A GB 1310760A GB 2499470 A GB2499470 A GB 2499470A GB 2499470 A GB2499470 A GB 2499470A GB 1310760 A GB1310760 A GB 1310760A
- Authority
- GB
- United Kingdom
- Prior art keywords
- optionally substituted
- naphthothiazole
- benzothiazole
- allyl
- ethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 silver halide Chemical class 0.000 title abstract 5
- 239000000839 emulsion Substances 0.000 title abstract 2
- 229910052709 silver Inorganic materials 0.000 title abstract 2
- 239000004332 silver Substances 0.000 title abstract 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 abstract 6
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 3
- KXNQKOAQSGJCQU-UHFFFAOYSA-N benzo[e][1,3]benzothiazole Chemical compound C1=CC=C2C(N=CS3)=C3C=CC2=C1 KXNQKOAQSGJCQU-UHFFFAOYSA-N 0.000 abstract 3
- 239000000975 dye Substances 0.000 abstract 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 3
- 125000000547 substituted alkyl group Chemical group 0.000 abstract 3
- AIGNCQCMONAWOL-UHFFFAOYSA-N 1,3-benzoselenazole Chemical compound C1=CC=C2[se]C=NC2=C1 AIGNCQCMONAWOL-UHFFFAOYSA-N 0.000 abstract 2
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical compound C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 abstract 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N anhydrous quinoline Natural products N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- ODIRBFFBCSTPTO-UHFFFAOYSA-N 1,3-selenazole Chemical compound C1=C[se]C=N1 ODIRBFFBCSTPTO-UHFFFAOYSA-N 0.000 abstract 1
- IPVORJLWOBDFGD-UHFFFAOYSA-N 1,3-selenazolidine Chemical compound C1C[Se]CN1 IPVORJLWOBDFGD-UHFFFAOYSA-N 0.000 abstract 1
- OGYGFUAIIOPWQD-UHFFFAOYSA-N 1,3-thiazolidine Chemical compound C1CSCN1 OGYGFUAIIOPWQD-UHFFFAOYSA-N 0.000 abstract 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 abstract 1
- ALUQMCBDQKDRAK-UHFFFAOYSA-N 2,3,3a,4-tetrahydro-1,3-benzothiazole Chemical compound C1C=CC=C2SCNC21 ALUQMCBDQKDRAK-UHFFFAOYSA-N 0.000 abstract 1
- BGTVICKPWACXLR-UHFFFAOYSA-N 4,5-diphenyl-1,3-thiazole Chemical compound S1C=NC(C=2C=CC=CC=2)=C1C1=CC=CC=C1 BGTVICKPWACXLR-UHFFFAOYSA-N 0.000 abstract 1
- QMHIMXFNBOYPND-UHFFFAOYSA-N 4-methylthiazole Chemical group CC1=CSC=N1 QMHIMXFNBOYPND-UHFFFAOYSA-N 0.000 abstract 1
- RWNMLYACWNIEIG-UHFFFAOYSA-N 5,6-dimethyl-1,3-benzoxazole Chemical compound C1=C(C)C(C)=CC2=C1OC=N2 RWNMLYACWNIEIG-UHFFFAOYSA-N 0.000 abstract 1
- YTSFYTDPSSFCLU-UHFFFAOYSA-N 5-chloro-1,3-benzothiazole Chemical compound ClC1=CC=C2SC=NC2=C1 YTSFYTDPSSFCLU-UHFFFAOYSA-N 0.000 abstract 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 abstract 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 abstract 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 abstract 1
- 235000010724 Wisteria floribunda Nutrition 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001450 anions Chemical group 0.000 abstract 1
- AMTXUWGBSGZXCJ-UHFFFAOYSA-N benzo[e][1,3]benzoselenazole Chemical compound C1=CC=C2C(N=C[se]3)=C3C=CC2=C1 AMTXUWGBSGZXCJ-UHFFFAOYSA-N 0.000 abstract 1
- WMUIZUWOEIQJEH-UHFFFAOYSA-N benzo[e][1,3]benzoxazole Chemical compound C1=CC=C2C(N=CO3)=C3C=CC2=C1 WMUIZUWOEIQJEH-UHFFFAOYSA-N 0.000 abstract 1
- 125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 abstract 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 230000001235 sensitizing effect Effects 0.000 abstract 1
- 125000005415 substituted alkoxy group Chemical group 0.000 abstract 1
- CBDKQYKMCICBOF-UHFFFAOYSA-N thiazoline Chemical compound C1CN=CS1 CBDKQYKMCICBOF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/28—Sensitivity-increasing substances together with supersensitising substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/0008—Methine or polymethine dyes, e.g. cyanine dyes substituted on the polymethine chain
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/0008—Methine or polymethine dyes, e.g. cyanine dyes substituted on the polymethine chain
- C09B23/0025—Methine or polymethine dyes, e.g. cyanine dyes substituted on the polymethine chain the substituent being bound through an oxygen atom
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/0075—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain being part of an heterocyclic ring
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/04—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with macromolecular additives; with layer-forming substances
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Plural Heterocyclic Compounds (AREA)
- Thiazole And Isothizaole Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
Abstract
1310760 Sensitizing dyes FUJI PHOTO FILM CO Ltd 22 May 1970 [27 May 1969] 24994/70 Heading C4P [Also in Division G2] Dyes used in supersensitized silver halide emulsions (see Divisions G2-G3) are of formula (in which Y and Y 1 each complete a thiazole, oxazole, benzothiazole, tetrahydrobenzothiazole, naphthothiazole, benzoxazole, naphthoxazole, benzselenazole, tetrahydroselenazole, naphthoselenazole, selenazole, thiazoline, 2- or 4- quinoline, 1- or 3-isoquinoline, benzimidazole, 3,3-dialkylindolenine or pyridine ring; R is allyl or optionally substituted alkyl; R 1 and R 2 are each allyl or optionally substituted alkyl or aryl; R 3 is H, alkyl or aryl; R 4 is H or optionally substituted alkyl; or when n 4 is 0, R 4 may be linked with any nitrogen atom in the nucleus completed by Y 1 , R 2 if necessary being absent; R 5 is H or optionally substituted alkoxy; n 1 , n 3 and n 4 are each 0 or 1; n 2 is 0-2; Q is O, S or -N-alkyl; X is anion; m is 1 or 2). In specified dyes Y completes a 2- or 4- quinoline, naphthothiazole, benzothiazole, thiazolidine or 4-methyl-thiazole ring; Q is O, S or -NC 2 H 5 ; Y 1 completes a benzoxazole, 5,6- dimethylbenzoxazole, benzothiazole, 5 - chlorobenzothiazole, 4,5 - diphenylthiazole, naphthothiazole or benzoselenazole ring; R is ethyl, methyl, allyl or hexyl; R 1 is ethyl; R 2 is ethyl, sulphopropyl, carboxyethoxyethyl or hydroxyethyl; R 3 is H or phenyl; R 4 is H or ethoxyethyl, or R 2 and R 4 are together -(CH 2 ) 4 -; R 5 is sulphopropoxy, methoxyethoxy or methoxy; n 4 is 0 or 1; n 2 is 1 or 2.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP44041169A JPS4925500B1 (en) | 1969-05-27 | 1969-05-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1310760A true GB1310760A (en) | 1973-03-21 |
Family
ID=12600907
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2499470A Expired GB1310760A (en) | 1969-05-27 | 1970-05-22 | Supersensitized silver halide photographic emulsions |
Country Status (7)
Country | Link |
---|---|
US (1) | US3674499A (en) |
JP (1) | JPS4925500B1 (en) |
BE (1) | BE750997A (en) |
CA (1) | CA934595A (en) |
DE (1) | DE2026091C3 (en) |
FR (1) | FR2092173A5 (en) |
GB (1) | GB1310760A (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3971664A (en) * | 1970-10-27 | 1976-07-27 | Fuji Photo Film Co., Ltd. | Fine grain silver halide emulsions with polyheteronuclear sensitizing dyes |
AU590628B2 (en) | 1985-10-15 | 1989-11-09 | Fuji Photo Film Co., Ltd. | Method of processing silver halide color photographic material |
US4851327A (en) | 1986-07-17 | 1989-07-25 | Fuji Photo Film Co., Ltd. | Photographic color photosensitive material with two layer reflective support |
JPH01108546A (en) | 1987-10-22 | 1989-04-25 | Fuji Photo Film Co Ltd | Silver halide color photographic sensitive material |
JPH01140153A (en) | 1987-11-27 | 1989-06-01 | Fuji Photo Film Co Ltd | Silver halide color photographic sensitive material |
JPH0690437B2 (en) | 1987-12-02 | 1994-11-14 | 富士写真フイルム株式会社 | Direct positive photographic material |
JPH0833628B2 (en) | 1987-12-15 | 1996-03-29 | 富士写真フイルム株式会社 | Silver halide color photographic light-sensitive material |
DE69131701T2 (en) | 1990-05-09 | 2000-03-09 | Fuji Photo Film Co Ltd | Processing method for a silver halide photographic material and light-sensitive material for photography |
WO1993010482A2 (en) * | 1991-11-12 | 1993-05-27 | International Paper Company | Photographic emulsions and materials with reduced pressure sensitivity |
-
1969
- 1969-05-27 JP JP44041169A patent/JPS4925500B1/ja active Pending
-
1970
- 1970-05-22 GB GB2499470A patent/GB1310760A/en not_active Expired
- 1970-05-26 CA CA083948A patent/CA934595A/en not_active Expired
- 1970-05-26 FR FR7019098A patent/FR2092173A5/fr not_active Expired
- 1970-05-27 BE BE750997D patent/BE750997A/en unknown
- 1970-05-27 US US41092A patent/US3674499A/en not_active Expired - Lifetime
- 1970-05-27 DE DE2026091A patent/DE2026091C3/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE2026091C3 (en) | 1973-09-27 |
CA934595A (en) | 1973-10-02 |
JPS4925500B1 (en) | 1974-07-01 |
DE2026091B2 (en) | 1973-03-15 |
US3674499A (en) | 1972-07-04 |
BE750997A (en) | 1970-11-03 |
DE2026091A1 (en) | 1970-12-17 |
FR2092173A5 (en) | 1972-01-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |