GB1278119A - Regeneration of deactivated catalyst containing a platinum group component and a sulfur component - Google Patents
Regeneration of deactivated catalyst containing a platinum group component and a sulfur componentInfo
- Publication number
- GB1278119A GB1278119A GB58707/69A GB5870769A GB1278119A GB 1278119 A GB1278119 A GB 1278119A GB 58707/69 A GB58707/69 A GB 58707/69A GB 5870769 A GB5870769 A GB 5870769A GB 1278119 A GB1278119 A GB 1278119A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- free
- suitably
- sulphur
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 title abstract 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract 5
- 230000008929 regeneration Effects 0.000 title abstract 2
- 238000011069 regeneration method Methods 0.000 title abstract 2
- 229910052717 sulfur Inorganic materials 0.000 title abstract 2
- 239000011593 sulfur Substances 0.000 title abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract 4
- 239000001257 hydrogen Substances 0.000 abstract 4
- 239000005864 Sulphur Substances 0.000 abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- -1 platinum metals Chemical class 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 229910052697 platinum Inorganic materials 0.000 abstract 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000969 carrier Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052762 osmium Inorganic materials 0.000 abstract 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 238000010926 purge Methods 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Abstract
1278119 Catalyst regeneration UNIVERSAL OIL PRODUCTS CO 2 Dec 1969 58707/69 Heading B1E [Also in Division C5] A catalyst containing a platinum group component and a sulphur component and which has been used in a hydrocarbon conversion process is regenerated by: (a) stopping contact of the hydrocarbon charge stock with the catalyst; (b) reducing the sulfur content of the catalyst to less than 0.02 wt. % by contacting the catalyst, without intervening treatment, with a sulphur-free and water free hydrogen stream, suitably at 430 to 595C and a pressure of 3.4 to 24 atmospheres gauge; (c) removing the substantial portion of the carbonaceous deposit by treating with oxygen, suitably at 370 to 595C; (d) purging free oxygen from the treated catalyst; (e) reducing the platinum group component by contact with a sulphurfree and water-free hydrogen stream, suitably at 480 to 595C; and (f) incorporating 0.05 to 0.50 wt. % of sulphur in the catalyst by treatment with an oxygen free sulphiding gas consisting predominantly of hydrogen and hydrogen sulphide, suitably at 480 to 595C using a gas containing an amount of sulphur equivalent to 0.1 to 2 moles of hydrogen sulphide per 100 moles of hydrogen. Specified platinum metals are platinum, palladium, rhodium, ruthenium, osmium and iridium and specified suitable carriers for the catalyst are alumina, silica, zirconia, magnesia, boria, thoria, titania, strontia, and mixtures of two or more thereof. The catalyst also preferably combined halogen.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB58707/69A GB1278119A (en) | 1969-12-02 | 1969-12-02 | Regeneration of deactivated catalyst containing a platinum group component and a sulfur component |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB58707/69A GB1278119A (en) | 1969-12-02 | 1969-12-02 | Regeneration of deactivated catalyst containing a platinum group component and a sulfur component |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1278119A true GB1278119A (en) | 1972-06-14 |
Family
ID=10482235
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB58707/69A Expired GB1278119A (en) | 1969-12-02 | 1969-12-02 | Regeneration of deactivated catalyst containing a platinum group component and a sulfur component |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1278119A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4710483A (en) * | 1977-07-21 | 1987-12-01 | Trw Inc. | Novel carbonaceous material and process for producing a high BTU gas from this material |
| DE102008015406A1 (en) | 2008-03-22 | 2009-09-24 | Bayer Materialscience Ag | Process for the regeneration of a catalyst containing sulfur in the form of sulfur compounds and containing ruthenium or ruthenium compounds |
| EP3403723A1 (en) | 2017-05-19 | 2018-11-21 | Covestro Deutschland AG | Method for regenerating a poisoned catalyst containing ruthenium or ruthenium compounds |
-
1969
- 1969-12-02 GB GB58707/69A patent/GB1278119A/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4710483A (en) * | 1977-07-21 | 1987-12-01 | Trw Inc. | Novel carbonaceous material and process for producing a high BTU gas from this material |
| DE102008015406A1 (en) | 2008-03-22 | 2009-09-24 | Bayer Materialscience Ag | Process for the regeneration of a catalyst containing sulfur in the form of sulfur compounds and containing ruthenium or ruthenium compounds |
| US8889578B2 (en) | 2008-03-22 | 2014-11-18 | Bayer Materialscience Ag | Processes for regenerating sulfur-poisoned, ruthenium and/or ruthenium compound-containing catalysts |
| EP3403723A1 (en) | 2017-05-19 | 2018-11-21 | Covestro Deutschland AG | Method for regenerating a poisoned catalyst containing ruthenium or ruthenium compounds |
| WO2018210770A1 (en) | 2017-05-19 | 2018-11-22 | Covestro Deutschland Ag | Method for regenerating a toxified catalyst containing ruthenium or ruthenium compounds |
| US11389791B2 (en) | 2017-05-19 | 2022-07-19 | Covestro Deutschland Ag | Method for regenerating a toxified catalyst containing ruthenium or ruthenium compounds |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |