GB1264741A - - Google Patents

Info

Publication number
GB1264741A
GB1264741A GB1264741DA GB1264741A GB 1264741 A GB1264741 A GB 1264741A GB 1264741D A GB1264741D A GB 1264741DA GB 1264741 A GB1264741 A GB 1264741A
Authority
GB
United Kingdom
Prior art keywords
block
alphamethylstyrene
polymer block
initiator
lithium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1264741A publication Critical patent/GB1264741A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
    • C08G81/022—Block or graft polymers containing only sequences of polymers of C08C or C08F containing sequences of polymers of conjugated dienes and of polymers of alkenyl aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation

Abstract

1,264,741. Alphamethylstyrene block copolymers. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 31 March, 1970 [1 April, 1969], No. 15180/70. Heading C3P. A block copolymer of the formula in which each A is a random copolymer block of styrene and alphamethylstyrene and each B is a conjugated diene polymer block, an alpha olefin polymer block or a hydrogenated conjugated diene polymer block, is obtained by (a) sequential polymerization using a mono- or difunctional lithium compound as initiator or (b) forming a two-block copolymer and coupling, using a polar additive in the alpha-methyl styrene polymerization. The product may be hydrogenated. In examples, B is formed from butadiene, the initiator is a s-butyl lithium or lithium-alphamethylstyrene reaction product, the polar additive is tetrahydrofuran, and the coupling agent in the former case is phenyl benzoate.
GB1264741D 1969-04-01 1970-03-31 Expired GB1264741A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US81237569A 1969-04-01 1969-04-01

Publications (1)

Publication Number Publication Date
GB1264741A true GB1264741A (en) 1972-02-23

Family

ID=25209381

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1264741D Expired GB1264741A (en) 1969-04-01 1970-03-31

Country Status (6)

Country Link
AU (1) AU1317570A (en)
BE (1) BE747591A (en)
DE (1) DE2015249A1 (en)
FR (1) FR2042247A5 (en)
GB (1) GB1264741A (en)
NL (1) NL7004513A (en)

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3912793A (en) * 1972-09-29 1975-10-14 Denki Kagaku Kogyo Kk Block copolymers and process for the preparation thereof
US4075253A (en) 1974-05-15 1978-02-21 Denki Kagaku Kogyo Kabushiki Kaisha Organolithium polymerization initiators and their preparations
EP0719833A2 (en) 1994-12-30 1996-07-03 General Electric Company Thermoplastic compositions containing polyphenylene ether resin and polyolefins
US5556911A (en) * 1994-11-15 1996-09-17 The Dow Chemical Company Films from aqueous dispersions of block copolymers having hydrogenated conjugated diene block
US5905097A (en) * 1993-01-08 1999-05-18 The Dow Chemical Company High-strength breathable films of block copolymer lattices
US6221283B1 (en) 1999-05-07 2001-04-24 General Electric Company Conductive compositions with compositionally controlled bulk resistivity
WO2002015302A2 (en) * 2000-08-14 2002-02-21 World Properties Inc. Thermosetting composition for electrochemical cell components and methods of making thereof
US6353050B1 (en) 2000-10-13 2002-03-05 General Electric Co. Thermoplastic blend comprising poly(arylene ether) and polyamide
US6469093B1 (en) 1999-11-12 2002-10-22 General Electric Company Conductive polyphenylene ether-polyamide blend
US6500895B1 (en) 2000-10-13 2002-12-31 General Electric Company Thermoplastic blend comprising poly(arylene ether) and polyamide
US6583205B2 (en) 2001-05-07 2003-06-24 General Electric Company Flame retardant expandable poly(arylene ether)/polystyrene compositions and preparation thereof
US6630527B2 (en) 2001-10-19 2003-10-07 General Electric Company UV stabilized, impact modified polyester/polycarbonate blends, articles, and methods of manufacture thereof
US6936652B2 (en) 2000-05-04 2005-08-30 General Electric Company Method for improving the paint adhesion of compatibilized polyphenylene ether-polyamide compositions
US7037986B2 (en) 2003-12-19 2006-05-02 General Electric Company Lead free solder friendly thermoplastic blends and methods of manufacture thereof
US7405249B2 (en) 2005-08-31 2008-07-29 General Electric Company High flow polyester composition, method of manufacture, and uses thereof
US7449518B2 (en) 2006-03-24 2008-11-11 Kraton Polymers U.S. Llc High temperature block copolymers and process for making same
US7612130B2 (en) 2006-10-16 2009-11-03 Sabic Innovative Plastics Ip B.V. Composition of polyester, aromatic epoxy compound and epoxy-functional polyolefin and/or copolyester
WO2010078089A1 (en) 2008-12-30 2010-07-08 Sabic Innovative Plastics Ip B.V. Flame retardant resinous compositions and process
WO2010078108A1 (en) 2008-12-30 2010-07-08 Sabic Innovative Plastics Ip B.V. Flame retardant resinous compositions and process
US7782190B1 (en) 2004-04-19 2010-08-24 Advanced Neuromodulation Systems, Inc. Implantable device and system and method for wireless communication
US7868090B2 (en) 2006-12-28 2011-01-11 Sabic Innovative Plastics Ip B.V. Polyester molding compositions
US7947204B2 (en) 2004-04-16 2011-05-24 Sabic Innovative Plastics Ip B.V. Poly(arylene ether) compression molding
US8034870B2 (en) 2003-12-17 2011-10-11 Sabic Innovative Plastics Ip B.V. Flame-retardant polyester composition
US8222347B2 (en) 2007-07-25 2012-07-17 Sabic Innovative Plastics Ip B.V. Polyester-polycarbonate compositions
US10131769B2 (en) 2014-12-05 2018-11-20 Sabic Global Technologies B.V. Flame-retardant polystyene composition
WO2022179867A1 (en) 2021-02-25 2022-09-01 Basf Se Curable composition comprising light polymerizable liquid and epoxy precursor for coating, 2d object formation and 3d printing

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5338315B2 (en) * 1972-09-29 1978-10-14
US3949020A (en) * 1974-09-03 1976-04-06 The Goodyear Tire & Rubber Company Thermoplastic block polymers
EP0014947B1 (en) * 1979-02-15 1985-09-18 The Dow Chemical Company Block copolymers of diene having their terminal end blocks of a random copolymer of styrene or alkylstyrene and an alpha-methylstyrene, and their preparation
AU569998B2 (en) * 1981-03-27 1988-03-03 Dow Chemical Company, The Process for preparation of diene styrene alpha- methylstyrene block polymers
EP0135168B1 (en) * 1983-08-22 1990-02-28 The Dow Chemical Company A process for preparation of copolymers of isopropenyl aromatic monomer and vinyl aromatic monomer
IT1186752B (en) * 1985-07-10 1987-12-16 Eniricerche Spa HYDROGENATED BLOCK COPOLYMERS AND THEIR SYNTHESIS PROCESS
US5578674A (en) * 1993-01-08 1996-11-26 The Dow Chemical Company High-strength films of block copolymer latices
JPH08505426A (en) * 1993-01-08 1996-06-11 ザ ダウ ケミカル カンパニー High strength film of block copolymer latex
US5563204A (en) * 1993-01-08 1996-10-08 The Dow Chemical Company High-strength films of block copolymer latices

Cited By (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3912793A (en) * 1972-09-29 1975-10-14 Denki Kagaku Kogyo Kk Block copolymers and process for the preparation thereof
US4075253A (en) 1974-05-15 1978-02-21 Denki Kagaku Kogyo Kabushiki Kaisha Organolithium polymerization initiators and their preparations
US5905097A (en) * 1993-01-08 1999-05-18 The Dow Chemical Company High-strength breathable films of block copolymer lattices
US5556911A (en) * 1994-11-15 1996-09-17 The Dow Chemical Company Films from aqueous dispersions of block copolymers having hydrogenated conjugated diene block
US5567760A (en) * 1994-11-15 1996-10-22 The Dow Chemical Company Films from aqueous dispersions of block copolymers having hydrogenated conjugated diene block
EP0719833A2 (en) 1994-12-30 1996-07-03 General Electric Company Thermoplastic compositions containing polyphenylene ether resin and polyolefins
US6221283B1 (en) 1999-05-07 2001-04-24 General Electric Company Conductive compositions with compositionally controlled bulk resistivity
EP2071585A1 (en) 1999-05-07 2009-06-17 Sabic Innovative Plastics IP B.V. Conductive compositions with compositionally controlled bulk resistivity
EP2192156A1 (en) 1999-11-12 2010-06-02 Sabic Innovative Plastics IP B.V. Conductive polyphenylene ether-polyamide blend
US6469093B1 (en) 1999-11-12 2002-10-22 General Electric Company Conductive polyphenylene ether-polyamide blend
US6486255B2 (en) 1999-11-12 2002-11-26 General Electric Company Conductive polyphenylene ether-polyamide blend
US6593411B2 (en) 1999-11-12 2003-07-15 General Electric Company Conductive polyphenylene ether-polyamide blend
US7226963B2 (en) 1999-11-12 2007-06-05 General Electric Company Conductive polyphenylene ether-polyamide blend
US6936652B2 (en) 2000-05-04 2005-08-30 General Electric Company Method for improving the paint adhesion of compatibilized polyphenylene ether-polyamide compositions
US6811917B2 (en) 2000-08-14 2004-11-02 World Properties, Inc. Thermosetting composition for electrochemical cell components and methods of making thereof
WO2002015302A3 (en) * 2000-08-14 2003-01-23 World Properties Inc Thermosetting composition for electrochemical cell components and methods of making thereof
WO2002015302A2 (en) * 2000-08-14 2002-02-21 World Properties Inc. Thermosetting composition for electrochemical cell components and methods of making thereof
GB2383892A (en) * 2000-08-14 2003-07-09 World Properties Inc Thermosetting composition for electrochemical cell components and methods of making thereof
GB2383892B (en) * 2000-08-14 2004-10-27 World Properties Inc Thermosetting composition for electrochemical cell components and methods of making thereof
US6500895B1 (en) 2000-10-13 2002-12-31 General Electric Company Thermoplastic blend comprising poly(arylene ether) and polyamide
US6353050B1 (en) 2000-10-13 2002-03-05 General Electric Co. Thermoplastic blend comprising poly(arylene ether) and polyamide
US6583205B2 (en) 2001-05-07 2003-06-24 General Electric Company Flame retardant expandable poly(arylene ether)/polystyrene compositions and preparation thereof
US6743846B2 (en) 2001-05-07 2004-06-01 General Electric Company Preparation of flame retardant expandable poly(arylene ether)/polystyrene compositions
US6630527B2 (en) 2001-10-19 2003-10-07 General Electric Company UV stabilized, impact modified polyester/polycarbonate blends, articles, and methods of manufacture thereof
US8034870B2 (en) 2003-12-17 2011-10-11 Sabic Innovative Plastics Ip B.V. Flame-retardant polyester composition
US7037986B2 (en) 2003-12-19 2006-05-02 General Electric Company Lead free solder friendly thermoplastic blends and methods of manufacture thereof
US8703028B2 (en) 2004-04-16 2014-04-22 Sabic Innovative Plastics Ip B.V. Poly(arylene ether) compression molding
US7947204B2 (en) 2004-04-16 2011-05-24 Sabic Innovative Plastics Ip B.V. Poly(arylene ether) compression molding
US7782190B1 (en) 2004-04-19 2010-08-24 Advanced Neuromodulation Systems, Inc. Implantable device and system and method for wireless communication
US7405249B2 (en) 2005-08-31 2008-07-29 General Electric Company High flow polyester composition, method of manufacture, and uses thereof
US7825176B2 (en) 2005-08-31 2010-11-02 Sabic Innovative Plastics Ip B.V. High flow polyester composition
EP2287243A1 (en) 2005-08-31 2011-02-23 SABIC Innovative Plastics IP B.V. High flow polyester composition
EP2088168A1 (en) 2005-08-31 2009-08-12 Sabic Innovative Plastics IP B.V. High flow polyester composition
US7405250B2 (en) 2005-08-31 2008-07-29 General Electric Company High flow polyester composition, method of manufacture, and uses thereof
US7449518B2 (en) 2006-03-24 2008-11-11 Kraton Polymers U.S. Llc High temperature block copolymers and process for making same
EP1999208A4 (en) * 2006-03-24 2009-12-30 Kraton Polymers Us Llc High temperature block copolymers and process for making same
CN101421350B (en) * 2006-03-24 2012-02-15 科腾聚合物美国有限责任公司 High temperature block copolymers and process for making same
EP1999208A2 (en) * 2006-03-24 2008-12-10 Kraton Polymers U.S. LLC High temperature block copolymers and process for making same
US7612130B2 (en) 2006-10-16 2009-11-03 Sabic Innovative Plastics Ip B.V. Composition of polyester, aromatic epoxy compound and epoxy-functional polyolefin and/or copolyester
US7868090B2 (en) 2006-12-28 2011-01-11 Sabic Innovative Plastics Ip B.V. Polyester molding compositions
US8222347B2 (en) 2007-07-25 2012-07-17 Sabic Innovative Plastics Ip B.V. Polyester-polycarbonate compositions
WO2010078089A1 (en) 2008-12-30 2010-07-08 Sabic Innovative Plastics Ip B.V. Flame retardant resinous compositions and process
US7915329B2 (en) 2008-12-30 2011-03-29 Sabic Innovative Plastics Ip B.V. Flame retardant resinous compositions and process
US7915328B2 (en) 2008-12-30 2011-03-29 Sabic Innovative Plastics Ip B.V. Flame retardant resinous compositions and process
WO2010078108A1 (en) 2008-12-30 2010-07-08 Sabic Innovative Plastics Ip B.V. Flame retardant resinous compositions and process
US10131769B2 (en) 2014-12-05 2018-11-20 Sabic Global Technologies B.V. Flame-retardant polystyene composition
WO2022179867A1 (en) 2021-02-25 2022-09-01 Basf Se Curable composition comprising light polymerizable liquid and epoxy precursor for coating, 2d object formation and 3d printing

Also Published As

Publication number Publication date
NL7004513A (en) 1970-10-05
DE2015249A1 (en) 1970-10-08
FR2042247A5 (en) 1971-02-05
AU1317570A (en) 1971-10-17
BE747591A (en) 1970-09-21

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees