GB1263139A - Improved bismuth molybdate on silica catalysts - Google Patents

Improved bismuth molybdate on silica catalysts

Info

Publication number
GB1263139A
GB1263139A GB6061869A GB6061869A GB1263139A GB 1263139 A GB1263139 A GB 1263139A GB 6061869 A GB6061869 A GB 6061869A GB 6061869 A GB6061869 A GB 6061869A GB 1263139 A GB1263139 A GB 1263139A
Authority
GB
United Kingdom
Prior art keywords
bismuth
silica
carbonate
molybdate
metals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB6061869A
Inventor
William Robert Mcclellan
Alvin Barber Stiles
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to GB6061869A priority Critical patent/GB1263139A/en
Publication of GB1263139A publication Critical patent/GB1263139A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/31—Chromium, molybdenum or tungsten combined with bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,263,139. Bismuth molybdate or bismuth phosphomolybdate. E.I. DU PONT DE NEMOURS & CO. 11 Dec., 1969, No. 60618/69. Heading B1E. [Also in Divisions C2 and C5] Bismuth molybdate or bismuth phosphomolybdate on silica catalysts are formed by: (i) adding ammonium carbonate or bicarbonate to a aqueous mixture of colloidal silica and oxides or precursers of oxides of bismuth, molybdenum and optionally phosphorus, the amount of carbonate or bicarbonate adding being such as to give a composition of pH 5-7.5; (ii) drying; and (iii) calcining at 400- 550‹C. The final catalyst contains 5-90wt% silica. Specified reactants are: bismuth nitrate, chloride, bromide, sulphate, formate or acetate; ammonium molybdate, alkali molybdates or molybdic acid; and other, meta or pyrophosphoric acid. The colloidal silica is suitably derived from an aqueous silica sol. Auxiliary supports specified are silicon carbide, alumina, aluminasilica and titania. The catalyst may also contain as promoter 0.1- 10wt% of alkaline earth metal, rare earth metals, Gp. VIII metals, Gp. V metals or manganese. The catalyst after drying may contain combined carbonate e.g. in excess of 0.1% carbon dioxide, however this is apparently driven out on calcination.
GB6061869A 1969-12-11 1969-12-11 Improved bismuth molybdate on silica catalysts Expired GB1263139A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB6061869A GB1263139A (en) 1969-12-11 1969-12-11 Improved bismuth molybdate on silica catalysts

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB6061869A GB1263139A (en) 1969-12-11 1969-12-11 Improved bismuth molybdate on silica catalysts

Publications (1)

Publication Number Publication Date
GB1263139A true GB1263139A (en) 1972-02-09

Family

ID=10485826

Family Applications (1)

Application Number Title Priority Date Filing Date
GB6061869A Expired GB1263139A (en) 1969-12-11 1969-12-11 Improved bismuth molybdate on silica catalysts

Country Status (1)

Country Link
GB (1) GB1263139A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0389255A1 (en) * 1989-03-23 1990-09-26 Nitto Chemical Industry Co., Ltd. Process for producing molybdenum bismuth-containing metal oxide catalyst
US5907066A (en) * 1996-11-27 1999-05-25 Lehigh University Treating methanol-containing waste gas streams
US6028228A (en) * 1997-09-26 2000-02-22 Georgia-Pacific Corporation Production of formaldehyde from CH4 and H2 S
US6037290A (en) * 1998-04-15 2000-03-14 Lehigh University In situ regeneration of metal-molybdate catalysts for methanol oxidation to formaldehyde
US6084135A (en) * 1997-12-31 2000-07-04 Lehigh University Production of formaldehyde using carbon oxides, hydrogen and H2 S
US6198005B1 (en) 1998-04-23 2001-03-06 Lehigh University Treating methanol containing waste gas streams
CN113083281A (en) * 2021-04-08 2021-07-09 齐鲁工业大学 Bismuth molybdate/carbon flexible membrane photocatalytic material and preparation method and application thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0389255A1 (en) * 1989-03-23 1990-09-26 Nitto Chemical Industry Co., Ltd. Process for producing molybdenum bismuth-containing metal oxide catalyst
US5071814A (en) * 1989-03-23 1991-12-10 Nitto Chemical Industry Co., Ltd. Process for producing molybdenum bismuth-containing metal oxide catalyst
US5907066A (en) * 1996-11-27 1999-05-25 Lehigh University Treating methanol-containing waste gas streams
US6028228A (en) * 1997-09-26 2000-02-22 Georgia-Pacific Corporation Production of formaldehyde from CH4 and H2 S
US6084135A (en) * 1997-12-31 2000-07-04 Lehigh University Production of formaldehyde using carbon oxides, hydrogen and H2 S
US6037290A (en) * 1998-04-15 2000-03-14 Lehigh University In situ regeneration of metal-molybdate catalysts for methanol oxidation to formaldehyde
US6198005B1 (en) 1998-04-23 2001-03-06 Lehigh University Treating methanol containing waste gas streams
CN113083281A (en) * 2021-04-08 2021-07-09 齐鲁工业大学 Bismuth molybdate/carbon flexible membrane photocatalytic material and preparation method and application thereof

Similar Documents

Publication Publication Date Title
GB1291323A (en) Manufacture of catalysts of the iron molybdate type for use particularly in the catalytic oxidation of alcohols to aldehydes
US5663113A (en) Ammoxidation catalyst composition
GB1294171A (en) Process for converting a nitrile to the corresponding amide
GB1074794A (en) Selective removal of oxides of nitrogen from gas mixtures containing oxygen
GB1523849A (en) Process for preparing heteropoly-acids
GB1495303A (en) Process for producing antimony-containing catalysts
GB1296212A (en)
GB1249290A (en) Catalyst and process for oxidising olefins
GB1362659A (en) Oxidative dehydrogenation of organic compounds
GB1298784A (en) Process for the preparation of unsaturated carbonyl compounds
GB1263139A (en) Improved bismuth molybdate on silica catalysts
GB1185109A (en) Production of Unsaturated Aliphatic Acids
GB1366367A (en) Methanol synthesis catalysts
EP0713724B1 (en) Ammoxidation catalyst composition and process for producing acrylonitrile or methacrylonitrile by using the same
ES8207441A1 (en) Catalysts preparation process based on molybden and/or tungsten oxides and oxides of other metals.
US3959384A (en) Oxidation catalyst and process for oxidation of olefins to unsaturated aldehydes
GB1286970A (en) Low temperature methanol synthesis catalyst precursor
GB1327738A (en) Catalyst for the conversion of hydrocarbons and its manufacture and use
GB1244001A (en) Oxygenated hydrocarbons production
FR2076288A5 (en) Silica supported bismuth molybdate catalysts
GB1157821A (en) New Compounds useful as Oxidation Catalyst
GB1219282A (en) Improvements relating to catalysts
GB1486916A (en) Catalyst for preparation of alpha,beta-unsaturated aldehydes
KR880001328A (en) Silver-containing catalyst and preparation method thereof
GB1309083A (en) Hydrocarbon dehydrogenation process