GB1197802A - Process for the preparation of 3,5-Dimethyl Phenol - Google Patents

Process for the preparation of 3,5-Dimethyl Phenol

Info

Publication number
GB1197802A
GB1197802A GB4413667A GB4413667A GB1197802A GB 1197802 A GB1197802 A GB 1197802A GB 4413667 A GB4413667 A GB 4413667A GB 4413667 A GB4413667 A GB 4413667A GB 1197802 A GB1197802 A GB 1197802A
Authority
GB
United Kingdom
Prior art keywords
dimethyl phenol
oxide
sept
alkali metal
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4413667A
Inventor
Charles Rex Adams
Guenther Bernhardt
Juergen Friedrich Falbe
Hans Juergen Arpe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB1197802A publication Critical patent/GB1197802A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions decreasing the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by condensation involving hydroxy groups of phenols or alcohols or the ether or mineral ester group derived therefrom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

1,197,802. 3,5-Dimethyl phenol. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 28 Sept., 1967 [30 Sept., 1966], No. 44136/67. Heading C2C. 3,5-Dimethyl phenol is obtained by catalytically splitting off methane from isophorone in the gaseous phase, in the presence of a catalyst containing alumina, chromium III oxide and 15-40 mol. per cent of an alkali metal oxide based on the chromium III oxide. The preferred alkali metal oxide is potassium oxide and preferably the process is carried out at a temperature in the range 600-650‹ C.
GB4413667A 1966-09-30 1967-09-28 Process for the preparation of 3,5-Dimethyl Phenol Expired GB1197802A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DES0106251 1966-09-30
GB626967A GB1181437A (en) 1966-09-30 1967-02-09 Process for the preparation of 2,3,5-trimethyl phenol.

Publications (1)

Publication Number Publication Date
GB1197802A true GB1197802A (en) 1970-07-08

Family

ID=25998629

Family Applications (4)

Application Number Title Priority Date Filing Date
GB626967A Expired GB1181437A (en) 1966-09-30 1967-02-09 Process for the preparation of 2,3,5-trimethyl phenol.
GB6171969A Expired GB1197803A (en) 1966-09-30 1967-09-28 Process for the preparation of 3,5-Dimethyl Phenol
GB6172169A Expired GB1197804A (en) 1966-09-30 1967-09-28 Process for the preparation of 3,5-Dimethyl Phenol
GB4413667A Expired GB1197802A (en) 1966-09-30 1967-09-28 Process for the preparation of 3,5-Dimethyl Phenol

Family Applications Before (3)

Application Number Title Priority Date Filing Date
GB626967A Expired GB1181437A (en) 1966-09-30 1967-02-09 Process for the preparation of 2,3,5-trimethyl phenol.
GB6171969A Expired GB1197803A (en) 1966-09-30 1967-09-28 Process for the preparation of 3,5-Dimethyl Phenol
GB6172169A Expired GB1197804A (en) 1966-09-30 1967-09-28 Process for the preparation of 3,5-Dimethyl Phenol

Country Status (4)

Country Link
BE (1) BE704437A (en)
CH (1) CH490300A (en)
GB (4) GB1181437A (en)
NL (1) NL153848B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0080759A1 (en) * 1981-12-02 1983-06-08 Shell Internationale Researchmaatschappij B.V. Process for the preparation of 3,5-dimethylphenol
US4533769A (en) * 1984-05-24 1985-08-06 General Electric Company Method of making methylated phenol from methylated cyclohexeneone
US4551563A (en) * 1984-05-24 1985-11-05 General Electric Company Method for making polymethylated phenols

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1768875B1 (en) * 1968-07-10 1972-02-10 Ruetgerswerke Ag Process for the production of 3,5-dimethylphenol
US4048239A (en) * 1976-04-13 1977-09-13 General Electric Company Process for the ortho alkylation of phenols using aldehydes and hydrogen in the presence of a copper-chromium catalyst
GB1522775A (en) * 1976-04-13 1978-08-31 Gen Electric Process for the selective ortho-alkylation of a phenol
CN112263969B (en) * 2020-11-22 2022-09-09 浙江金科日化原料有限公司 Production method of 3, 5-dimethylphenol and pressure-controlled production device used in production method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0080759A1 (en) * 1981-12-02 1983-06-08 Shell Internationale Researchmaatschappij B.V. Process for the preparation of 3,5-dimethylphenol
US4533769A (en) * 1984-05-24 1985-08-06 General Electric Company Method of making methylated phenol from methylated cyclohexeneone
US4551563A (en) * 1984-05-24 1985-11-05 General Electric Company Method for making polymethylated phenols

Also Published As

Publication number Publication date
GB1197803A (en) 1970-07-08
NL153848B (en) 1977-07-15
NL6713253A (en) 1968-04-01
DE1543878A1 (en) 1970-01-02
CH490300A (en) 1970-05-15
BE704437A (en) 1968-03-28
GB1181437A (en) 1970-02-18
DE1543878B2 (en) 1975-06-05
GB1197804A (en) 1970-07-08

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee