GB1185960A - N-hydrocarbylmercapto methyl amidophosphoroxy derivatives - Google Patents
N-hydrocarbylmercapto methyl amidophosphoroxy derivativesInfo
- Publication number
- GB1185960A GB1185960A GB6016768A GB6016768A GB1185960A GB 1185960 A GB1185960 A GB 1185960A GB 6016768 A GB6016768 A GB 6016768A GB 6016768 A GB6016768 A GB 6016768A GB 1185960 A GB1185960 A GB 1185960A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phenyl
- derivatives
- alkyl
- acid
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 title 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 6
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- -1 phenyl ester Chemical class 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical class NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- HRRYXTFQZLAZSH-UHFFFAOYSA-N N-diphenoxyphosphoryl-1-ethylsulfanylmethanamine Chemical compound C1(=CC=CC=C1)OP(OC1=CC=CC=C1)(=O)NCSCC HRRYXTFQZLAZSH-UHFFFAOYSA-N 0.000 abstract 1
- 229930040373 Paraformaldehyde Natural products 0.000 abstract 1
- 125000003368 amide group Chemical group 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- DMSZORWOGDLWGN-UHFFFAOYSA-N ctk1a3526 Chemical compound NP(N)(N)=O DMSZORWOGDLWGN-UHFFFAOYSA-N 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229920002866 paraformaldehyde Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
- C07F9/224—Phosphorus triamides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
- C07F9/24—Esteramides
- C07F9/2454—Esteramides the amide moiety containing a substituent or a structure which is considered as characteristic
- C07F9/2458—Esteramides the amide moiety containing a substituent or a structure which is considered as characteristic of aliphatic amines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,185,960. N - Hydrocarbylmercaptomethyl amidophosphoric acid derivatives. UNION RHEINISCHE BRAUNKOHLEN KRAFTSTOFF A.G. 18 Dec., 1968 [15 Jan., 1968], No. 60167/68. Heading C2C. N - Hydrocarbylmercaptomethyl amido - phosphoroxy derivatives are obtained by reacting phosphorus oxytriamide or an alkyl or phenyl ester of amidophosphoric acid with formaldehyde and then reacting the product with an alkyl or phenyl mercaptan in the presence of an inorganic acid, e.g. HC1 or H 2 SO 4 . Specified products obtainable are those of the formula R.S.CH 2 .N(Q).P(O)(X)(Y) wherein X is -OR or -N(CH 2 SR) 2 , Y is -OR<SP>1</SP> or N(CH 2 SR) 2 , Q is H or is R-S-CH 2 -and R and R<SP>1</SP> are C 1 -C 7 alkyl radicals or are phenyl and the invention includes such products per se. The process can be effected with paraformaldehyde or with aqueous formaldehyde solutions and an organic solvent, e.g. acetone or alcohol may be present. Examples are given for the production of N,N,N<SP>1</SP>,N<SP>1</SP>,N<SP>11</SP>,N<SP>11</SP>-hexakis methyl (and phenyl) mercaptomethyl phosphoroxy triamides, N,N,N<SP>1</SP>,N<SP>1</SP>-tetrakisethylmercaptomethyl diamido phosphoric acid monoethyl (and monophenyl) esters and N-ethylmercaptomethyl amidophosphoric acid diphenyl ester. The products have insecticidal and bactericidal properties.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19681668801 DE1668801A1 (en) | 1968-01-15 | 1968-01-15 | Process for the production of phosphorus compounds containing sulfur and nitrogen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1185960A true GB1185960A (en) | 1970-04-02 |
Family
ID=5686129
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB6016768A Expired GB1185960A (en) | 1968-01-15 | 1968-12-18 | N-hydrocarbylmercapto methyl amidophosphoroxy derivatives |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE725542A (en) |
| FR (1) | FR1596197A (en) |
| GB (1) | GB1185960A (en) |
-
1968
- 1968-12-16 BE BE725542D patent/BE725542A/xx unknown
- 1968-12-18 GB GB6016768A patent/GB1185960A/en not_active Expired
- 1968-12-19 FR FR1596197D patent/FR1596197A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE725542A (en) | 1972-05-29 |
| FR1596197A (en) | 1970-06-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |