GB701150A - 3-substituted-3,4-dihydro-coumarins and process for the manufacture thereof - Google Patents
3-substituted-3,4-dihydro-coumarins and process for the manufacture thereofInfo
- Publication number
- GB701150A GB701150A GB1428653A GB1428653A GB701150A GB 701150 A GB701150 A GB 701150A GB 1428653 A GB1428653 A GB 1428653A GB 1428653 A GB1428653 A GB 1428653A GB 701150 A GB701150 A GB 701150A
- Authority
- GB
- United Kingdom
- Prior art keywords
- reacting
- carbalkoxy
- general formula
- radical
- compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/78—Ring systems having three or more relevant rings
- C07D311/92—Naphthopyrans; Hydrogenated naphthopyrans
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Abstract
The invention comprises compounds of the general formula <FORM:0701150/IV (b)/1> wherein X is a carbalkoxy other than carbethoxy, carbobenzyloxy or nitrile radical. Compounds of that formula, where X may also be a carbalkoxy radical in general, are produced by reacting a compound of the general formula <FORM:0701150/IV (b)/2> with an alkali-metal derivative of a compound of the formula CH2(X)Z wherein Z is a carbalkoxy radical. The reaction may be carried out in solution, e.g. in xylene. In examples compounds of the first general formula above in which X represents carbethoxy, nitrile and carbobenzyloxy radicals respectively are produced by reacting a -dimethylaminomethyl-b -naphthol with the sodium derivative of (1) ethyl malonate, (2) ethyl cyanoacetate, and (3) and (4) dibenzyl malonate. The a -dialkylaminomethyl-b -naphthols can be prepared by reacting b -naphthol with the appropriate dialkylamine.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1428653A GB701150A (en) | 1951-03-22 | 1951-03-22 | 3-substituted-3,4-dihydro-coumarins and process for the manufacture thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1428653A GB701150A (en) | 1951-03-22 | 1951-03-22 | 3-substituted-3,4-dihydro-coumarins and process for the manufacture thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
GB701150A true GB701150A (en) | 1953-12-16 |
Family
ID=10038421
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1428653A Expired GB701150A (en) | 1951-03-22 | 1951-03-22 | 3-substituted-3,4-dihydro-coumarins and process for the manufacture thereof |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB701150A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2878138A (en) * | 1955-09-28 | 1959-03-17 | Bayer Ag | Method of brightening material |
US4892923A (en) * | 1988-02-22 | 1990-01-09 | Eastman Kodak Company | Polyester compositions containing the residue of a naphthopyran compound and shaped articles produced therefrom |
-
1951
- 1951-03-22 GB GB1428653A patent/GB701150A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2878138A (en) * | 1955-09-28 | 1959-03-17 | Bayer Ag | Method of brightening material |
US4892923A (en) * | 1988-02-22 | 1990-01-09 | Eastman Kodak Company | Polyester compositions containing the residue of a naphthopyran compound and shaped articles produced therefrom |
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