GB1175766A - Carboxylated Polymers - Google Patents

Carboxylated Polymers

Info

Publication number
GB1175766A
GB1175766A GB4463568A GB4463568A GB1175766A GB 1175766 A GB1175766 A GB 1175766A GB 4463568 A GB4463568 A GB 4463568A GB 4463568 A GB4463568 A GB 4463568A GB 1175766 A GB1175766 A GB 1175766A
Authority
GB
United Kingdom
Prior art keywords
polymer
reacted
hydrogen
alkyl group
carboxylated polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4463568A
Inventor
Ghazi Mourad Dickakian
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Priority to GB4463568A priority Critical patent/GB1175766A/en
Priority to BE739044D priority patent/BE739044A/xx
Priority to FR6931976A priority patent/FR2018456A1/en
Priority to DE19691947653 priority patent/DE1947653A1/en
Publication of GB1175766A publication Critical patent/GB1175766A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4403—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/04—Oxidation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1,175,766. Carboxylated polymers. ESSO RESEARCH & ENG. CO. 19 Sept., 1968, No. 44635/68. Heading C3P. An unsaturated polymer is reacted with molecular oxygen in the presence of a heavy metal salt catalyst and a saturated aliphatic acid of formula where X is hydrogen or a C 1-10 alkyl group and Y is hydrogen, a C 1-10 alkyl group, or -COOH; or acetic anhydride or propionic anhydride. In the examples a solution of polybutadiene is reacted with oxygen in the presence of cobalt octoate and either acetic or propionic acid. The product may be neutralized with ammonium hydroxide to give an aqueous solution. A polymer of butadiene having a molecular weight of 500 to 10,000, a 1,2-configuration of at least 50% and an acid number of 50-100 mg. KOH/gram of polymer may be obtained.
GB4463568A 1968-09-19 1968-09-19 Carboxylated Polymers Expired GB1175766A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
GB4463568A GB1175766A (en) 1968-09-19 1968-09-19 Carboxylated Polymers
BE739044D BE739044A (en) 1968-09-19 1969-09-18
FR6931976A FR2018456A1 (en) 1968-09-19 1969-09-19 Prepn of carboxylated polymers from polyolefins by - oxidation
DE19691947653 DE1947653A1 (en) 1968-09-19 1969-09-19 Carboxylated polymers, their production and use

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4463568A GB1175766A (en) 1968-09-19 1968-09-19 Carboxylated Polymers

Publications (1)

Publication Number Publication Date
GB1175766A true GB1175766A (en) 1969-12-23

Family

ID=10434151

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4463568A Expired GB1175766A (en) 1968-09-19 1968-09-19 Carboxylated Polymers

Country Status (4)

Country Link
BE (1) BE739044A (en)
DE (1) DE1947653A1 (en)
FR (1) FR2018456A1 (en)
GB (1) GB1175766A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5018503B1 (en) * 1970-06-05 1975-06-30
CN109092355A (en) * 2018-07-27 2018-12-28 北京化工大学 A kind of catalyst and the method for preparing carboxyl HNBR

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5018503B1 (en) * 1970-06-05 1975-06-30
CN109092355A (en) * 2018-07-27 2018-12-28 北京化工大学 A kind of catalyst and the method for preparing carboxyl HNBR
CN109092355B (en) * 2018-07-27 2020-07-31 北京化工大学 Catalyst and method for preparing carboxyl HNBR

Also Published As

Publication number Publication date
DE1947653A1 (en) 1970-03-26
FR2018456A1 (en) 1970-05-29
BE739044A (en) 1970-03-18

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees