GB1142354A - Methyl-methoxymethyl-urea derivatives - Google Patents

Methyl-methoxymethyl-urea derivatives

Info

Publication number
GB1142354A
GB1142354A GB23528/66A GB2352866A GB1142354A GB 1142354 A GB1142354 A GB 1142354A GB 23528/66 A GB23528/66 A GB 23528/66A GB 2352866 A GB2352866 A GB 2352866A GB 1142354 A GB1142354 A GB 1142354A
Authority
GB
United Kingdom
Prior art keywords
methyl
halides
reaction
urea derivatives
methoxymethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB23528/66A
Inventor
Karl-Heinz Koenig
Adolf Fischer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB1142354A publication Critical patent/GB1142354A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/28—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C275/30—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by halogen atoms, or by nitro or nitroso groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/26—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/28—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/28—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C275/32—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by singly-bound oxygen atoms
    • C07C275/34—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by singly-bound oxygen atoms having nitrogen atoms of urea groups and singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring
    • C07C275/36—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by singly-bound oxygen atoms having nitrogen atoms of urea groups and singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring with at least one of the oxygen atoms further bound to a carbon atom of a six-membered aromatic ring, e.g. N-aryloxyphenylureas
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/14—All rings being cycloaliphatic
    • C07C2602/22—All rings being cycloaliphatic the ring system containing eight carbon atoms, e.g. pentalene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1,142,354. N - Methyl - N - methoxymethyl urea derivatives. BADISCHE ANILIN- & SODA-FABRIK A.G. 26 May, 1966 [4 June, 1965], No. 23528/66. Heading C2C. [Also in Division A5] The invention comprises N-methyl-N-methoxymethyl urea derivatives of formula wherein R<SP>1</SP> is a mono-, bi- or tri-cycloaliphatic radical or a phenyl radical which may be substituted by one or more C 1-3 alkyl, fluorine, bromine or alkoxy substituents, or a -CF 3 or halophenoxy substituents or a halogen atom and one or more of the above mentioned substituents and R 2 is H or CH 3 . The compounds are prepared by (i) reaction of appropriate cycloalkylamines or substituted anilines with N-methyl-N-methoxymethylcarbamyl halides in an inert solvent or diluent and in the presence of acid-binding agents or (ii) reaction of the corresponding N-methyl urea derivative with HCHO and CH 3 OH in the presence of, e.g. Ba(OH) 2 , as catalyst. N - Methyl - N - methoxymethylcarbamyl halides may be prepared by reaction of N- methyl-N-chloromethylcarbamyl halides with methanol or an alkali metal methylate.
GB23528/66A 1965-06-04 1966-05-26 Methyl-methoxymethyl-urea derivatives Expired GB1142354A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB0082280 1965-06-04

Publications (1)

Publication Number Publication Date
GB1142354A true GB1142354A (en) 1969-02-05

Family

ID=6981439

Family Applications (1)

Application Number Title Priority Date Filing Date
GB23528/66A Expired GB1142354A (en) 1965-06-04 1966-05-26 Methyl-methoxymethyl-urea derivatives

Country Status (10)

Country Link
AT (1) AT260616B (en)
BE (1) BE681248A (en)
BR (1) BR6680160D0 (en)
DE (1) DE1542687A1 (en)
DK (1) DK115159B (en)
ES (1) ES327573A1 (en)
FR (1) FR1481391A (en)
GB (1) GB1142354A (en)
NL (1) NL6607762A (en)
SE (1) SE337015B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3978123A (en) * 1973-07-12 1976-08-31 Chevron Research Company Herbicidal n-alkylsulfoxymethyl-and-n-alkylsulfonyl-methyl-n-aryl
US3991093A (en) * 1971-01-15 1976-11-09 Basf Aktiengesellschaft Substituted m-trifluoromethylphenylurea derivatives
US4111682A (en) 1975-01-13 1978-09-05 Stauffer Chemical Company N-(aminoalkylene thiomethyl)-N'-(aryl) urea herbicides

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2247310A1 (en) * 1972-09-27 1974-04-04 Bayer Ag TETRA-SUBSTITUTED UREA, METHOD OF MANUFACTURING AND USE AS HERBICIDES

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3991093A (en) * 1971-01-15 1976-11-09 Basf Aktiengesellschaft Substituted m-trifluoromethylphenylurea derivatives
US3978123A (en) * 1973-07-12 1976-08-31 Chevron Research Company Herbicidal n-alkylsulfoxymethyl-and-n-alkylsulfonyl-methyl-n-aryl
US4111682A (en) 1975-01-13 1978-09-05 Stauffer Chemical Company N-(aminoalkylene thiomethyl)-N'-(aryl) urea herbicides

Also Published As

Publication number Publication date
BE681248A (en) 1966-11-18
AT260616B (en) 1968-03-11
ES327573A1 (en) 1967-07-16
SE337015B (en) 1971-07-26
FR1481391A (en) 1967-05-19
DE1542687A1 (en) 1970-07-23
BR6680160D0 (en) 1973-12-26
DK115159B (en) 1969-09-08
NL6607762A (en) 1966-12-05

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