GB1092908A - Improvements in the bonding of polyethylene terephthalate fibres to rubber - Google Patents

Improvements in the bonding of polyethylene terephthalate fibres to rubber

Info

Publication number
GB1092908A
GB1092908A GB4149863A GB4149863A GB1092908A GB 1092908 A GB1092908 A GB 1092908A GB 4149863 A GB4149863 A GB 4149863A GB 4149863 A GB4149863 A GB 4149863A GB 1092908 A GB1092908 A GB 1092908A
Authority
GB
United Kingdom
Prior art keywords
fibres
reaction
resorcinol
butadiene
resin solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4149863A
Inventor
Thomas James Meyrick
David Buchanan Wootton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB4149863A priority Critical patent/GB1092908A/en
Priority to NL6412183A priority patent/NL6412183A/xx
Priority to BE654660A priority patent/BE654660A/xx
Priority to FR992190A priority patent/FR1422170A/en
Publication of GB1092908A publication Critical patent/GB1092908A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/54—Polycondensates of aldehydes
    • C08G18/542—Polycondensates of aldehydes with phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/69—Polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/8064—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with monohydroxy compounds
    • C08G18/8067—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with monohydroxy compounds phenolic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00—Characterised by the use of unspecified rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

The bonding of polyethylene terephthalate fibres to natural or synthetic rubber, e.g. cispolymers of butadiene and isoprene, polymers of chlorobutadiene and copolymers of these monomers with styrene, acrylonitrile, methyl methacrylate, ethylene, propylene or isobutylene, is improved by treating the fibres with an aqueous adhesive system comprising a butadiene/vinyl pyridine copolymer and a resorcinol-formaldehyde resin solution and with an aqueous suspension of an isocyanate generator prepared by the reaction of a polyisocyanate-polyhydric alcohol reaction product with a phenol. The dispersion of the isocyanate generator may be mixed with the aqueous butadiene/vinyl pyridine latex and resorcinol-formaldehyde resin solution and the fibres impregnated with this dispersion and heated for a short time at temperatures above 140 DEG C. Alternatively the fibres may be impregnated with the p isocyanate generator and with the latex and resorcinol-formaldehyde resin solution separately in either order, the fibres optionally being heated between the two impregnation treatments. The isocyanate generator may be prepared by the reaction of 2,4-or 2,6-tolylene diisocyanate with ethylene glycol, diethylene glycol or glycerol followed by reaction with phenol or with a substituted phenol.
GB4149863A 1963-10-21 1963-10-21 Improvements in the bonding of polyethylene terephthalate fibres to rubber Expired GB1092908A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
GB4149863A GB1092908A (en) 1963-10-21 1963-10-21 Improvements in the bonding of polyethylene terephthalate fibres to rubber
NL6412183A NL6412183A (en) 1963-10-21 1964-10-20
BE654660A BE654660A (en) 1963-10-21 1964-10-21
FR992190A FR1422170A (en) 1963-10-21 1964-10-21 Method for adhering polyethylene terephthalate fibers to rubbers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4149863A GB1092908A (en) 1963-10-21 1963-10-21 Improvements in the bonding of polyethylene terephthalate fibres to rubber

Publications (1)

Publication Number Publication Date
GB1092908A true GB1092908A (en) 1967-11-29

Family

ID=10419968

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4149863A Expired GB1092908A (en) 1963-10-21 1963-10-21 Improvements in the bonding of polyethylene terephthalate fibres to rubber

Country Status (3)

Country Link
BE (1) BE654660A (en)
GB (1) GB1092908A (en)
NL (1) NL6412183A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1690702A3 (en) * 1998-12-28 2010-08-25 Bridgestone Corporation Adhesive composition, resin material, rubber article and pneumatic tire

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1690702A3 (en) * 1998-12-28 2010-08-25 Bridgestone Corporation Adhesive composition, resin material, rubber article and pneumatic tire

Also Published As

Publication number Publication date
NL6412183A (en) 1965-04-22
BE654660A (en) 1965-04-21

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