GB1082409A - An electrolytic descaling solution - Google Patents

An electrolytic descaling solution

Info

Publication number
GB1082409A
GB1082409A GB4724364A GB4724364A GB1082409A GB 1082409 A GB1082409 A GB 1082409A GB 4724364 A GB4724364 A GB 4724364A GB 4724364 A GB4724364 A GB 4724364A GB 1082409 A GB1082409 A GB 1082409A
Authority
GB
United Kingdom
Prior art keywords
article
passed
solution
hno3
anode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4724364A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Publication of GB1082409A publication Critical patent/GB1082409A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25FPROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
    • C25F1/00Electrolytic cleaning, degreasing, pickling or descaling
    • C25F1/02Pickling; Descaling
    • C25F1/04Pickling; Descaling in solution
    • C25F1/06Iron or steel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

An article of iron or steel is electrolytically descaled while immersed in a bath of anaqueous solution comprising by weight at least 2%, preferably more than 10%, of one or more Na or K salts of H2SO4 or HNO3, 0.1 to 10% of a soluble fluoride, e.g. NaF, KF, KHF2, NH4F or SnF2, and 0.25 to 10% of an organic substance capable of forming complex ions with metal ions removed from the article surface, e.g. citric or tartaric acid or Na or K salt thereof. The pH of the solution may be adjusted from 3 to 13 by adding H2SO4, HF and/or HNO3, or NaOH and/or KOH. D. C. may be passed with the article as cathode or anode, or A. C. may be passed with the article as one or both electrodes, or current may be passed indirectly through the article disposed between an anode and a cathode.
GB4724364A 1963-12-04 1964-11-19 An electrolytic descaling solution Expired GB1082409A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6487463 1963-12-04

Publications (1)

Publication Number Publication Date
GB1082409A true GB1082409A (en) 1967-09-06

Family

ID=13270698

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4724364A Expired GB1082409A (en) 1963-12-04 1964-11-19 An electrolytic descaling solution

Country Status (2)

Country Link
DE (1) DE1496906B2 (en)
GB (1) GB1082409A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005085502A1 (en) * 2004-03-10 2005-09-15 Andreas Stepan Method for pickling steels and regenerating pickling solutions
EP1051545B1 (en) * 1998-02-02 2006-06-21 Outokumpu Stainless AB Method for treating a metal product
EP2725121A3 (en) * 2012-10-24 2016-10-05 Zen Material Technologies, Inc. Method for removing rust from a rusted steel

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE409474B (en) * 1975-05-13 1979-08-20 Wennborg Ab C J SEE CONTINUOUS AND DISCONTINUAL ELECTROCHEMIC CLEANING OF ALLOY STEELS, SPECIAL STAINLESS STEEL IN THE FORM OF BANDS, BARS, PROFILES, THREADS, RODS AND PIECES WITH SURFACES AND LOSS
US4012299A (en) * 1976-04-01 1977-03-15 Allegheny Ludlum Industries, Inc. Metallic descaling system
GB1520705A (en) * 1976-04-01 1978-08-09 Allegheny Ludlum Ind Inc Electrolytic descaling of metals
US4174269A (en) * 1978-06-21 1979-11-13 Ppg Industries, Inc. Method of treating electrodes

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1051545B1 (en) * 1998-02-02 2006-06-21 Outokumpu Stainless AB Method for treating a metal product
WO2005085502A1 (en) * 2004-03-10 2005-09-15 Andreas Stepan Method for pickling steels and regenerating pickling solutions
EP2725121A3 (en) * 2012-10-24 2016-10-05 Zen Material Technologies, Inc. Method for removing rust from a rusted steel

Also Published As

Publication number Publication date
DE1496906B2 (en) 1971-07-01
DE1496906A1 (en) 1970-10-01

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