GB1071472A - Production of halogens - Google Patents
Production of halogensInfo
- Publication number
- GB1071472A GB1071472A GB3292364A GB3292364A GB1071472A GB 1071472 A GB1071472 A GB 1071472A GB 3292364 A GB3292364 A GB 3292364A GB 3292364 A GB3292364 A GB 3292364A GB 1071472 A GB1071472 A GB 1071472A
- Authority
- GB
- United Kingdom
- Prior art keywords
- zone
- hygroscopic solution
- drying zone
- dried
- effluent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/09—Bromine; Hydrogen bromide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C01B7/03—Preparation from chlorides
- C01B7/04—Preparation of chlorine from hydrogen chloride
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/13—Iodine; Hydrogen iodide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Drying Of Gases (AREA)
Abstract
In an oxidation reaction of hydrogen halide, the effluent gases containing water, halogen and hydrogen halide are dried under adiabatic conditions with hygroscopic solution of a metal halide (e.g. CaCl2) or H2SO4. The hygroscopic solution increases in temperature and is subsequently dehydrated by flashing under reduced pressure and adiabatic conditions; it is recycled to the drying zone. The dried effluent gas is condensed to obtain substantially pure halogen; if this is chlorine the effluent gases should be dried to a water dew point of less than - 30 DEG F. in the drying zone. A portion of the flashed hygroscopic solution (e.g. 20%) may be recycled to the drying zone at a temperature below that at which the dried effluent is removed. A two-stage drying zone may be employed, the hygroscopic solution is supplied to the first stage at the temperature at which it leaves the flashing zone and at least 85% of the moisture may be removed in this zone, the remainder being removed by the cooled hygroscopic solution which is supplied to the second portion of the zone. The drying zone is constructed of acid resistant material and the H2SO4 supplied countercurrent to the effluent gas flow in a zone packed, e.g., with raschig rings.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP0034874 | 1964-08-12 | ||
NL6409278A NL6409278A (en) | 1964-08-12 | 1964-08-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1071472A true GB1071472A (en) | 1967-06-07 |
Family
ID=25990325
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3292364A Expired GB1071472A (en) | 1964-08-12 | 1964-08-12 | Production of halogens |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB1071472A (en) |
NL (2) | NL6409278A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1207506B (en) * | 1985-10-15 | 1989-05-25 | Montedipe Spa | PROCESS FOR THE RECOVERY OF THE IODINE FROM THE SODIUM IODIDE. |
-
0
- NL NL134068D patent/NL134068C/xx active
-
1964
- 1964-08-12 GB GB3292364A patent/GB1071472A/en not_active Expired
- 1964-08-12 NL NL6409278A patent/NL6409278A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
NL134068C (en) | |
NL6409278A (en) | 1966-02-14 |
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