GB1059137A - Electrophotographic recording members and processes of preparing same - Google Patents
Electrophotographic recording members and processes of preparing sameInfo
- Publication number
- GB1059137A GB1059137A GB43884/63A GB4388463A GB1059137A GB 1059137 A GB1059137 A GB 1059137A GB 43884/63 A GB43884/63 A GB 43884/63A GB 4388463 A GB4388463 A GB 4388463A GB 1059137 A GB1059137 A GB 1059137A
- Authority
- GB
- United Kingdom
- Prior art keywords
- coat
- styrene
- water
- substrate
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/14—Inert intermediate or cover layers for charge-receiving layers
- G03G5/142—Inert intermediate layers
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/14—Inert intermediate or cover layers for charge-receiving layers
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photoreceptors In Electrophotography (AREA)
Abstract
1,059,137. Electrophotographic materials. ADDRESSOGRAPH - MULTIGRAPH CORPORATION. Nov. 6, 1963 [Nov. 29. 1962], No. 43884/63. Heading H1K. The upper surface of a substrate for an electrophotographic material is given a pre-coat before the photoconductive layer is' applied. The pre-coat contains the reaction product of a water-soluble aminoplast pre-condensate and a film-forming polymeric material having reactive carboxyl or hydroxyl groups. Suggested aminoplasts include various methylated methylol melamines, other alkylated melamine formaldehyde resins, urea - formaldehyde, aniline -formaldehyde, and cyanamide-formaldehyde. Suggested polymers are an interpolymer of styrene, hexyl acrylate, acrylonitrile, and methacrylic acid; polyvinyl alcohol; carboxylated styrene-maleic anhydride copolymers; carboxylated ethylene-maleic anhydride copolymers; crotonic acid-vinyl acetate copolymers; and hydroxy ethyl cellulose. The pre-coat may contain materials to improve its flexibility. For example, the composition may contain polyvinyl acetate. Common substrate materials may be used including fabrics and organic and metallic foils but an electrically conductive paper which may have a sealing coat on its under surface is preferred. The sealing coat may consist of -the pre-coating .material. In the examples the substrate consists of a bleached sulphite paper. The photoconductive layer consists of a particular photoconductor dispersed in a resinous binder. Many suitable photoconductors are listed. The precoat is formed by applying an aqueous material to the substrate. This is either an aqueous solution of the components or, a mixture of a solution of the aminoplast precondensate and a latex or dispersion of the polymeric material. "The composition may contain a stabilizer to delay thereaction between the main components. Spray or roll coating is suitableimmersion coating may be used if a sealing coat of the same composition as the pre-coat is .wanted. The pre-coating composition is cured by heating in a hot air oven to 250-360 F. for from 30 sees. to 5 mins. A dispersion of the photoconductor - in a resin solution is . then applied. The pre-coat prevents the solvent used from penetrating the substrate. The material is heated in hot air to 200-250 F. to remove volatiles-the solvent may. be removed in other ways if desired. In the specific examples the photocondtictive layer consists of zinc oxide and either a silicone resin or a styrene-butadiene copolymer as binder. The pre-coating compositions were of four main types:-(A) Dimethyl trimethylol melamine, water, the four component acrylic-styrene interpolymer mentioned above, and ammonia. (The ammonia acts as a stabilizer.). (B) Dimethyl trimethylol melamine, water, polyvinyl acetate, and either polyvinyl alcohol or hydroxy ethyl cellulose. (C) Ureaformaldehyde, water, and a copolymer of maleic anhydride with either styrene or ethylene. (D) Dimethyl trimethylol melamine, water, polyvinyl acetate, and copolymer of vinyl acetate and crotonic acid. The pre-coat increases the surface resistivity of the support.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US241008A US3241958A (en) | 1962-11-29 | 1962-11-29 | Electrophotographic recording members and processes of preparing same |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1059137A true GB1059137A (en) | 1967-02-15 |
Family
ID=22908862
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB43884/63A Expired GB1059137A (en) | 1962-11-29 | 1963-11-06 | Electrophotographic recording members and processes of preparing same |
Country Status (5)
Country | Link |
---|---|
US (1) | US3241958A (en) |
BE (1) | BE639812A (en) |
DE (1) | DE1272123B (en) |
GB (1) | GB1059137A (en) |
NL (2) | NL139211B (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3468660A (en) * | 1963-02-15 | 1969-09-23 | Azoplate Corp | Electrophotographic material comprising a multilayer support having a barrier layer over a duplex paper base |
US3489559A (en) * | 1965-05-28 | 1970-01-13 | Mead Corp | Components for electrophotographic compositions and processes |
GB1232406A (en) * | 1967-09-01 | 1971-05-19 | ||
JPS5651343B2 (en) * | 1972-04-28 | 1981-12-04 | ||
US4133684A (en) * | 1976-03-22 | 1979-01-09 | Konishiroku Photo Industry Co., Ltd. | Electrophotographic material with intermediate layer |
-
0
- BE BE639812D patent/BE639812A/xx unknown
- NL NL300364D patent/NL300364A/xx unknown
-
1962
- 1962-11-29 US US241008A patent/US3241958A/en not_active Expired - Lifetime
-
1963
- 1963-11-05 DE DEP1272A patent/DE1272123B/en active Pending
- 1963-11-06 GB GB43884/63A patent/GB1059137A/en not_active Expired
- 1963-11-11 NL NL63300364A patent/NL139211B/en unknown
Also Published As
Publication number | Publication date |
---|---|
DE1272123B (en) | 1968-07-04 |
BE639812A (en) | |
NL300364A (en) | |
US3241958A (en) | 1966-03-22 |
NL139211B (en) | 1973-06-15 |
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