GB1047772A - Improvements in or relating to novel sulphonated detergents and compositions containing them - Google Patents

Improvements in or relating to novel sulphonated detergents and compositions containing them

Info

Publication number
GB1047772A
GB1047772A GB2435763D GB2435763D GB1047772A GB 1047772 A GB1047772 A GB 1047772A GB 2435763 D GB2435763 D GB 2435763D GB 2435763 D GB2435763 D GB 2435763D GB 1047772 A GB1047772 A GB 1047772A
Authority
GB
United Kingdom
Prior art keywords
alkyl
salts
ch2ch
sulpho
neutral
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2435763D
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stepan Co
Original Assignee
Stepan Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stepan Chemical Co filed Critical Stepan Chemical Co
Publication of GB1047772A publication Critical patent/GB1047772A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Detergent compositions comprise a polyvalent metal salt (neutral or basic) of an a -sulpho carboxylic ester or amide of formula <FORM:1047772/C4-C5/1> where R is C4-20 alkyl, Y is C:O.O or C:O.NH, and X is C1-6 alkyl, -CH2CH(OH)CH2OH, -CH2CH(OH)CH2O(C1-6 alkyl) or (C2-4 alkyleneoxy)n-H, where n is an integer from 1 to 10, the total number of carbon atoms in R and in any C-C chain in X being 8 to 24. Salts derived from metals of Groups II to VIII are disclosed, typical ones being neutral and basic calcium methyl a -sulphomyristate and zinc N-glyceryl a -sulphopalmitamide. Other ingredients such as alkaline builders, N-alkylol fatty acid amides, amine oxides, alkali metal and amine salt of the above sulpho compounds, soap, sodium sulphate, oxyalkylated alkyl phenols and thiophenols or salts of sulphated derivatives thereof, metal alkaryl sulphonates, chelating agents and carboxymethylcellulose may be present. Solid and liquid compositions, e.g. in water/ethanol are described as are a drycleaning compositions containing also organic ammonium salts of sulphated alkylphenol/alkylene oxide condensates. The barium salts of the above a -sulpho compounds may be added to high temperature lubricants and the aluminium salts used in gelling fuels such as mineral spirits or gasoline.ALSO:The invention comprises polyvalent metal salts (both neutral and basic) of a -sulpho carboxylic ester or amide of formula <FORM:1047772/C2/1> where R is C4- 20 alkyl, Y is C:O.O or C:O.NH and X is C1- 6 alkyl, -CH2CH(OH)CH2OH, -CH2CH(OH)CH2O (C1- 6 alkyl) or (C2- 4 alkyleneoxy)n-H, wherein n is an integer from 1 to 10, the total number of carbon atoms in R and in any C-C chain in X being 8 to 24. Many salts derived from metals of Groups II to VIII are described. They are prepared by various neutralization tranesterification oxyalkylation. Products are useful as detergents, medicinals, pesticides, antiseptics and paint dryers.
GB2435763D 1962-04-24 1963-04-22 Improvements in or relating to novel sulphonated detergents and compositions containing them Expired GB1047772A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US18971762A 1962-04-24 1962-04-24
US18971862A 1962-04-24 1962-04-24

Publications (1)

Publication Number Publication Date
GB1047772A true GB1047772A (en) 1966-11-09

Family

ID=26885433

Family Applications (2)

Application Number Title Priority Date Filing Date
GB2435763D Expired GB1047772A (en) 1962-04-24 1963-04-22 Improvements in or relating to novel sulphonated detergents and compositions containing them
GB1578963A Expired GB1047771A (en) 1962-04-24 1963-04-22 Improvements in or relating to synthetic detergent compositions

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB1578963A Expired GB1047771A (en) 1962-04-24 1963-04-22 Improvements in or relating to synthetic detergent compositions

Country Status (5)

Country Link
BE (1) BE631335A (en)
CH (1) CH490486A (en)
DE (1) DE1297273B (en)
GB (2) GB1047772A (en)
LU (1) LU43598A1 (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7666828B2 (en) 2008-01-22 2010-02-23 Stepan Company Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them
WO2010085279A1 (en) * 2009-01-21 2010-07-29 Stepan Company Light duty liquid detergent compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
US7879790B2 (en) 2008-01-22 2011-02-01 Stepan Company Mixed salts of sulfonated estolides and other derivatives of fatty acids, and methods of making them
US7884064B2 (en) 2009-01-21 2011-02-08 Stepan Company Light duty liquid detergent compositions of sulfonated estolides and other derivatives of fatty acids
US7998920B2 (en) 2008-01-22 2011-08-16 Stepan Company Sulfonated estolide compositions containing magnesium sulfate and processes employing them
US8058223B2 (en) 2009-01-21 2011-11-15 Stepan Company Automatic or machine dishwashing compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
US8119588B2 (en) 2009-01-21 2012-02-21 Stepan Company Hard surface cleaner compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
US8124577B2 (en) 2009-01-21 2012-02-28 Stepan Company Personal care compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
US8536112B2 (en) 2009-09-11 2013-09-17 Stepan Company Liquid cleaning compositions containing sulfonated estolides and alkyl ester sulfonates

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4476044A (en) * 1982-05-13 1984-10-09 Henkel Corporation Surfactant product
US4476043A (en) * 1982-05-13 1984-10-09 Henkel Corporation Surfactant product
US4477372A (en) * 1982-05-13 1984-10-16 Henkel Corporation Anionic nonionic surfactant mixture
US4476045A (en) * 1982-05-13 1984-10-09 Henkel Corporation Surfactant
DE3632107A1 (en) * 1986-09-22 1988-03-31 Henkel Kgaa REDUCED PHOSPHATE DETERGENT CONTAINING N-ALKOXYLATED FATTY ACID AMIDES
WO1993025646A1 (en) * 1992-06-17 1993-12-23 Lion Corporation Detergent composition having low skin irritability
CA2205592C (en) * 1995-09-18 2001-12-11 Stepan Company Heavy duty liquid detergent compositions comprising salts of alpha sulfonated fatty acid methyl esters and use of alpha-sulfonated fatty acid salts to inhibit redeposition of soilon fabric
IT1307262B1 (en) * 1999-07-20 2001-10-30 Zschimmer & Schwarz Italiana S DETERGENT OR COSMETIC COMPOSITIONS INCLUDING ALCHYL SULPHATES AND / OALKYL (POLES) ZINC ETHOXY SULPHATES SUCH AS SURFACTIVE AGENTS AND
US6696394B1 (en) * 2002-11-14 2004-02-24 Ecolab Inc. Conveyor lubricants for use in the food and beverage industries
CZ305526B6 (en) * 2013-06-28 2015-11-18 Ústav Fyzikální Chemie J. Heyrovského Akademie Věd České Republiky, V. V. I. Cleaning mixture for removing coatings of water-based dispersions of acrylate polymers and method of removing thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH195464A (en) * 1936-12-04 1938-01-31 Ernst Suter Method of making a shampoo.
US2303212A (en) * 1939-05-26 1942-11-24 Solvay Process Co Soap composition
US2236528A (en) * 1939-06-22 1941-04-01 Emulsol Corp Derivatives of alcohol amines
US2915473A (en) * 1956-04-17 1959-12-01 Alexander J Stirton Detergent compositions
DE1115398B (en) * 1960-04-11 1961-10-19 Chem Fab Dueren G M B H Strong foaming detergents and cleaning agents

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7666828B2 (en) 2008-01-22 2010-02-23 Stepan Company Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them
US7879790B2 (en) 2008-01-22 2011-02-01 Stepan Company Mixed salts of sulfonated estolides and other derivatives of fatty acids, and methods of making them
US7998920B2 (en) 2008-01-22 2011-08-16 Stepan Company Sulfonated estolide compositions containing magnesium sulfate and processes employing them
US8129328B2 (en) 2008-01-22 2012-03-06 Stepan Company Compositions comprising sulfonated estolides and alkyl ester sulfonates, methods of making them, and compositions and processes employing them
US8338358B2 (en) 2008-01-22 2012-12-25 Stepan Company Compositions comprising sulfonated estolides and alkyl ester sulfonates, methods of making them, and compositions and processes employing them
WO2010085279A1 (en) * 2009-01-21 2010-07-29 Stepan Company Light duty liquid detergent compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
US7884064B2 (en) 2009-01-21 2011-02-08 Stepan Company Light duty liquid detergent compositions of sulfonated estolides and other derivatives of fatty acids
US8058223B2 (en) 2009-01-21 2011-11-15 Stepan Company Automatic or machine dishwashing compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
US8119588B2 (en) 2009-01-21 2012-02-21 Stepan Company Hard surface cleaner compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
US8124577B2 (en) 2009-01-21 2012-02-28 Stepan Company Personal care compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
US8536112B2 (en) 2009-09-11 2013-09-17 Stepan Company Liquid cleaning compositions containing sulfonated estolides and alkyl ester sulfonates

Also Published As

Publication number Publication date
BE631335A (en)
LU43598A1 (en) 1963-07-31
GB1047771A (en) 1966-11-09
CH490486A (en) 1970-05-15
DE1297273B (en) 1969-06-12

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