GB1037169A - Stabilization of polymers - Google Patents
Stabilization of polymersInfo
- Publication number
- GB1037169A GB1037169A GB892365A GB892365A GB1037169A GB 1037169 A GB1037169 A GB 1037169A GB 892365 A GB892365 A GB 892365A GB 892365 A GB892365 A GB 892365A GB 1037169 A GB1037169 A GB 1037169A
- Authority
- GB
- United Kingdom
- Prior art keywords
- diethyl
- methoxybenzylidene
- malonate
- incorporated
- malonates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Benzylidene malonic acid diesters may be prepared by reacting benzaldehydes with malonic acid diesters. In Example 1 p-methoxybenzaldehyde is reacted with diethyl malonate in benzene in the presence of piperidine. Corresponding products may be derived from benzaldehyde, o-methoxybenzaldehyde, p-hydroxybenzaldehyde, 2,4 - dimethoxybenzaldehyde, 2,5 - dimethoxybenzaldehyde, p - octyloxybenzaldehyde and p-dodecyloxybenzaldehyde, and from dimethyl, dioctyl, dibenzyl and diphenyl malonates.ALSO:Polymers are stabilized by incorporating therein a benzylidene malonic ester of formula <FORM:1037169/C3/1> where R and R1 are hydrogen, hydroxy, C1- 12 alkoxy, C1- 12 alkyl, C2- 12 alkanoyloxy, C2- 12 alkenyloxy or C3- 12 alkenoyloxy; and R11 and R111 are C1- 12 alkyl, aryl or aralkyl. The esters may be used together with phenolic antioxidants. Specified polymeric materials are cellulose acetate, polyethylene, polypropylene, polystyrene, polymethyl acrylate, polymetnyl methacrylate, polyvinyl chloride, polyvinylidene chloride, polyesters, polycarbonates and melamine resins. Specified phenolic antioxidants are 2,6-di-t-butyl 4-methyl-, 4-methylol-, 4 - ethyl- and 4 - octyl phenols, 2,6 - di - hexyl - 4 - methyl- and 4 - t - butyl - phenols, and 2,4,6-tri-t-butyl phenol. In comparative tests diethyl esters in which R1 is H and R is H or p-methoxy are incorporated in cellulose acetate, and in Examples (9) diethyl p-methoxybenzylidene, benzylidene, o-methoxybenzylidene, p-hydroxybenzylidene and 2,4-dimethoxybenzylidene malonates are incorporated in cellulose acetate; (10) diethyl p-methoxybenzylidene malonate and (11) diethyl 4-acryloxybenzylidene malonate, diethyl 4-octyloxybenzylidene malonate and dimethyl p-methoxybenzylidene malonate are incorporated in organo tin heat-stabilized polyvinyl chloride; (12) diethyl p-methoxybenzylidene, benzylidene, o-methoxybenzylidene, p-hydroxybenzylidene and 2,4-dimethoxybenzylidene malonates are incorporated in organo tin heat-stabilized vinyl chloride/vinyl acetate copolymers; (13) diethyl p-methoxybenzylidene, o-methoxybenzylidene, p-hydroxybenzylidene and 2,4-dimethoxybenzylidene malonates and (14) diethyl p-methoxybenzylidene malonate and 2,4,6-tri-t-butyl phenol are incorporated in polystyrene and (15) diethyl p-methoxybenzylidene malonate is incorporated in benzoguanamino - melamine - formaldehyde resins.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US36218264A | 1964-04-23 | 1964-04-23 | |
US38921064A | 1964-08-12 | 1964-08-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1037169A true GB1037169A (en) | 1966-07-27 |
Family
ID=27001588
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB892365A Expired GB1037169A (en) | 1964-04-23 | 1965-03-02 | Stabilization of polymers |
Country Status (4)
Country | Link |
---|---|
CH (1) | CH452185A (en) |
DE (1) | DE1544605C3 (en) |
GB (1) | GB1037169A (en) |
NL (1) | NL142443B (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0002837A2 (en) * | 1977-12-29 | 1979-07-11 | Gaf Corporation | Radiation curable coating composition comprising an oligomer, and an ultra-violet absorber |
EP0100651A1 (en) * | 1982-08-03 | 1984-02-15 | VAN DYK & COMPANY, INC. | Dialkyl malonates as organic suncreen adjuvants |
EP0350386A1 (en) * | 1988-07-08 | 1990-01-10 | L'oreal | Unsaturated derivatives of lipid soluble benzal malonates, and their use as UV absorbers in the cosmetic field |
US9051448B2 (en) | 2004-08-31 | 2015-06-09 | Basf Se | Stabilization of organic materials |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2310135C3 (en) * | 1973-03-01 | 1982-05-06 | Bayer Ag, 5090 Leverkusen | 4-Phenylbenzylidenemalonic acid derivatives and their use for stabilizing polymers against UV radiation |
-
1965
- 1965-03-02 GB GB892365A patent/GB1037169A/en not_active Expired
- 1965-03-16 NL NL6503314A patent/NL142443B/en unknown
- 1965-03-27 DE DE19651544605 patent/DE1544605C3/en not_active Expired
- 1965-04-22 CH CH559065A patent/CH452185A/en not_active IP Right Cessation
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0002837A2 (en) * | 1977-12-29 | 1979-07-11 | Gaf Corporation | Radiation curable coating composition comprising an oligomer, and an ultra-violet absorber |
EP0002837A3 (en) * | 1977-12-29 | 1979-07-25 | Gaf Corporation | Radiation curable coating composition comprising an oligomer, and an ultra-violet absorber |
EP0100651A1 (en) * | 1982-08-03 | 1984-02-15 | VAN DYK & COMPANY, INC. | Dialkyl malonates as organic suncreen adjuvants |
EP0350386A1 (en) * | 1988-07-08 | 1990-01-10 | L'oreal | Unsaturated derivatives of lipid soluble benzal malonates, and their use as UV absorbers in the cosmetic field |
US5175340A (en) * | 1988-07-08 | 1992-12-29 | L'oreal | New liposoluble unsaturated benzalmalonate derivatives and their use as absorbers for ultraviolet radiation in cosmetics |
US9051448B2 (en) | 2004-08-31 | 2015-06-09 | Basf Se | Stabilization of organic materials |
EP1791901B1 (en) * | 2004-08-31 | 2018-03-28 | Basf Se | Stabilization of organic materials |
Also Published As
Publication number | Publication date |
---|---|
CH452185A (en) | 1968-05-31 |
DE1544605C3 (en) | 1975-10-09 |
NL6503314A (en) | 1965-10-25 |
NL142443B (en) | 1974-06-17 |
DE1544605A1 (en) | 1969-05-08 |
DE1544605B2 (en) | 1975-02-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB1037169A (en) | Stabilization of polymers | |
GB1367788A (en) | Saponificationresistant polycabonates | |
SE399016B (en) | KIT FOR THE MANUFACTURE OF AN OLEFINE POLYMER LAMINATED METAL CONTAINER WALL WITH AN OPENING DEVICE CONSISTING BY CUTTING FROM A SEPARABLE SECTOR | |
GB1304551A (en) | ||
GB1087880A (en) | Preparation of 2,6-dialkyl phenols | |
GB1356319A (en) | Process for the preparation of a pyrazolone derivative | |
GB1066068A (en) | Stabilized polyolefins | |
BE751153A (en) | PROCESS FOR STABILIZING POLYMERS OR A MIXTURE OF POLYMERS CONTAINING PHENOPLASTS AS WELL AS FRICTION MATERIALS CONTAINING THESE | |
GB1525348A (en) | Multinuclear phenols and their use in the production of resol resins | |
GB1060067A (en) | Vinyl chloride and vinylidene chloride polymers | |
GB924639A (en) | Process for the preparation of polycarbonates | |
FR2168352A1 (en) | Synergistic stabiliser comprising a phosphite and 2,6-disubstd - phenol - prevents discoloration of flame-retarded thermoplastics on | |
GB1343082A (en) | Strip storage device | |
ES8501752A1 (en) | Process for the preparation of symmetric 1,4-dihydropyridine-carboxylic esters. | |
JPS4828777B1 (en) | ||
GB1294371A (en) | PRODUCTION OF alpha-HYDROXYCARBOXYLIC ESTERS | |
GB1308657A (en) | Stabilisation of organic material by phosphonate esters | |
GB1037465A (en) | Process for the production of high molecular weight thermoplastic polycarbonates | |
GB1147250A (en) | Uv absorbing polymers | |
GB1458819A (en) | Film cassettes | |
GB1017432A (en) | Novel light-stabilizing compounds, a process for producing the same and novel light-stabilized polymer compositions | |
GB1068794A (en) | Stabilized olefin polymers | |
GB858776A (en) | Improvements in and relating to plastic compositions | |
GB1177766A (en) | Polymerization Catalysts for Episulphides | |
GB971066A (en) | Stabilized polypropylene compositions |