GB1036980A - Production of di-isocyanates - Google Patents

Production of di-isocyanates

Info

Publication number
GB1036980A
GB1036980A GB29071/65A GB2907165A GB1036980A GB 1036980 A GB1036980 A GB 1036980A GB 29071/65 A GB29071/65 A GB 29071/65A GB 2907165 A GB2907165 A GB 2907165A GB 1036980 A GB1036980 A GB 1036980A
Authority
GB
United Kingdom
Prior art keywords
reaction
isocyanates
production
diaminocyclohexanes
trimethylcyclohexylamine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB29071/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Scholven Chemie AG
Original Assignee
Scholven Chemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scholven Chemie AG filed Critical Scholven Chemie AG
Publication of GB1036980A publication Critical patent/GB1036980A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C263/00—Preparation of derivatives of isocyanic acid
    • C07C263/10—Preparation of derivatives of isocyanic acid by reaction of amines with carbonyl halides, e.g. with phosgene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • C—CHEMISTRY; METALLURGY
    • C14—SKINS; HIDES; PELTS; LEATHER
    • C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C3/00—Tanning; Compositions for tanning
    • C14C3/02—Chemical tanning
    • C14C3/08—Chemical tanning by organic agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

In the manufacture of diisocyanates by reaction of diamines with phosgene in known manner, use is made of diaminocyclohexanes of the formula <FORM:1036980/C2/1> in which each symbol R denotes an alkyl group. The reaction may be effected in gaseous or liquid phase, and in the latter event decahydronaphthalene is the preferred solvent. Examples are given of the phosgenation of 3-aminomethyl-3,5,5 - trimethylcyclohexylamine, which may be prepared by reaction of isophorone with hydrocyanic acid followed by hydrogenation of the resulting nitrile in the presence of ammonia.
GB29071/65A 1964-07-21 1965-07-08 Production of di-isocyanates Expired GB1036980A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DESCH35500A DE1202785B (en) 1964-07-21 1964-07-21 Process for the preparation of 1-isocyanato-3- (isocyanatomethyl) -3, 5, 5-trimethylcyclohexane

Publications (1)

Publication Number Publication Date
GB1036980A true GB1036980A (en) 1966-07-20

Family

ID=7433510

Family Applications (1)

Application Number Title Priority Date Filing Date
GB29071/65A Expired GB1036980A (en) 1964-07-21 1965-07-08 Production of di-isocyanates

Country Status (8)

Country Link
US (1) US3401190A (en)
AT (1) AT267494B (en)
CH (1) CH454123A (en)
DE (1) DE1202785B (en)
GB (1) GB1036980A (en)
LU (1) LU48904A1 (en)
NL (1) NL151694B (en)
SE (1) SE312797B (en)

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US3625986A (en) * 1967-12-28 1971-12-07 Nat Distillers Chem Corp Bis 1, 1 isocyanatoalkyl cycloalkanes
US3936409A (en) * 1969-03-10 1976-02-03 Textron, Inc. Urea-urethane compositions and films prepared therefrom
US3717612A (en) * 1970-06-22 1973-02-20 Hitco Curable epoxy resin composition containing a substituted diurea compound
US3789071A (en) * 1971-10-07 1974-01-29 Hitco Epoxy curing agent
FR2204189A5 (en) * 1972-10-23 1974-05-17 Rhone Poulenc Sa
DE2614243C2 (en) * 1976-04-02 1982-10-07 Bayer Ag, 5090 Leverkusen Cycloaliphatic triisocyanates, process for their preparation and their use
US4174240A (en) * 1976-10-01 1979-11-13 Bayer Aktiengesellschaft Novel transparent polyurethane polyureas for lamination of glazing materials
US4166149A (en) * 1976-10-01 1979-08-28 Bayer Aktiengesellschaft Novel transparent polyurethane polyureas for lamination of glazing materials
DE3135948A1 (en) * 1981-09-10 1983-03-24 Bayer Ag, 5090 Leverkusen CYCLIC KETO-BUTYRALDEHYDE, A METHOD FOR THE PRODUCTION THEREOF AND THEIR USE FOR THE PRODUCTION OF CYCLIC DIISOCYANATES
DE4216535A1 (en) * 1991-08-21 1993-02-25 Bayer Ag FORMKOERPER FOR CONTROLLING SHAEDLINGEN
US5256170A (en) * 1992-01-22 1993-10-26 Minnesota Mining And Manufacturing Company Coated abrasive article and method of making same
US20080108719A1 (en) * 1999-10-25 2008-05-08 Geiger Eric J Phthalic Anhydride Based Polyester-Ether Polyols and Double Metal Cyanide Catalyst System for Preparing Same
US20050085658A1 (en) * 1999-10-25 2005-04-21 Geiger Eric J. Phthalic anhydride based polyester-ether polyols and double metal cyanide catalyst system for preparing same
US20060175575A1 (en) * 2001-06-15 2006-08-10 Kaplan Warren A Method for preparing phthalate polyester polyol-based dimensionally stable spray polyurethane foam
US6773756B2 (en) * 2002-03-20 2004-08-10 Bayer Polymers Llc Process to manufacture three dimensionally shaped substrate for sound abatement
US20060035994A1 (en) * 2004-05-17 2006-02-16 Kaplan Warren A Method for preparing phthalate polyester polyol-based dimensionally stable spray polyurethane foam
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US9453115B2 (en) * 2007-10-12 2016-09-27 Honeywell International Inc. Stabilization of polyurethane foam polyol premixes containing halogenated olefin blowing agents
US9550854B2 (en) * 2007-10-12 2017-01-24 Honeywell International Inc. Amine catalysts for polyurethane foams
US20090099273A1 (en) * 2007-10-12 2009-04-16 Williams David J Non-silicone surfactants for polyurethane or polyisocyanurate foam containing halogenated olefins as blowing agents
US8101672B2 (en) 2007-12-13 2012-01-24 Honeywell International Inc. Azeotrope-like compositions of 1,1,2,3,3-pentafluoropropene
WO2010009090A2 (en) 2008-07-16 2010-01-21 Honeywell International Inc. Hfo-1234ze mixed isomers with hfc-245fa as a blowing agent, aerosol, and solvent
US9546311B2 (en) 2008-08-19 2017-01-17 Honeywell International Inc. Azeotrope-like compositions of 1,1,1,2-tetrafluoropropene and 1,1,1,2-tetrafluoroethane
DE102008051882A1 (en) 2008-10-16 2010-04-29 Bayer Materialscience Ag Process for the preparation of polyetherester polyols
US10239985B2 (en) 2008-12-23 2019-03-26 Covestro Llc Polymer polyols comprising a natural oil base polyol, polyurethane foams comprising these polymer polyols and processes for their preparation
WO2012080185A1 (en) 2010-12-15 2012-06-21 Bayer Materialscience Ag Foams of high thermal stability
WO2012084760A1 (en) 2010-12-20 2012-06-28 Bayer Materialscience Ag Method for producing polyether ester polyols
US9556303B2 (en) 2011-02-21 2017-01-31 Honeywell International Inc. Catalysts for polyurethane foam polyol premixes containing halogenated olefin blowing agents
US20140171527A1 (en) * 2011-02-21 2014-06-19 Honeywell International Inc. Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same
US9051442B2 (en) 2011-02-21 2015-06-09 Honeywell International Inc. Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same
ES2746532T3 (en) 2011-02-21 2020-03-06 Honeywell Int Inc Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from these
US20140093721A1 (en) 2011-05-02 2014-04-03 Bayer Intellectual Property Gmbh High-temperature-resistant foams having low thermal conductivity
JP2015500362A (en) 2011-12-09 2015-01-05 ハネウェル・インターナショナル・インコーポレーテッド Articles made from foam and foam comprising HCFO or HFO blowing agent
WO2013127850A1 (en) 2012-02-29 2013-09-06 Bayer Intellectual Property Gmbh 2-k pultrusion formulation and process
RU2015139226A (en) 2013-02-26 2017-04-03 Ханивелл Интернешнл Инк. PREMIXES FOR POLYURETHANE FOAMS CONTAINING FOAMING AGENTS BASED ON HALOGENED OLEFINS AND FOAMS PRODUCED FROM THEM
EP2894180A1 (en) 2014-01-08 2015-07-15 Bayer MaterialScience AG Polymer Polyols comprising a Polyether Carbonate Polyol as the Base Polyol
US10280333B2 (en) 2015-02-03 2019-05-07 Seagrave Coatings Corp. Coating compositions
US10526463B2 (en) 2015-02-20 2020-01-07 Covestro Deutschland Ag Foam materials resistant to high temperatures
CA2987302C (en) 2015-05-28 2023-10-24 Coim Asia Pacific Pte. Ltd. Flame retardant and auto-catalytic polyesters for polyurethanes
JP2018531169A (en) 2015-09-17 2018-10-25 ロベルト ベロッツィ ヘレス Yield strength composite panels, materials, products, and methods of manufacture and use
KR20240018678A (en) 2017-01-31 2024-02-13 바스프 에스이 Hfo containing pu formulation
JP2021512202A (en) 2018-02-02 2021-05-13 ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆ Ｓｅ Simultaneous optimization of fiber sizing process inlined in pultrusion method
EP3741788A1 (en) 2019-05-24 2020-11-25 Covestro Deutschland AG Method for the preparation of polyoxyalkylenpolyol mixtures
EP3838963A1 (en) 2019-12-17 2021-06-23 Covestro Deutschland AG Method for producing polyoxyalkylene polyesterpolyols
WO2022096390A1 (en) 2020-11-06 2022-05-12 Covestro Deutschland Ag Method for producing a polyol mixture
WO2023057328A1 (en) 2021-10-07 2023-04-13 Covestro Deutschland Ag Process for preparing polyoxyalkylene polyester polyols

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2728787A (en) * 1953-03-03 1955-12-27 Rohm & Haas Process for preparing organic diisocyanates
US2911429A (en) * 1956-07-09 1959-11-03 Gen Aniline & Film Corp Process for the preparation of isocyanates
DE1240521B (en) * 1961-10-09 1967-05-18 Hibernia Chemie Ges Mit Beschr Process for the production of gamma-ketocarboxylic acid nitriles from alpha, beta-unsaturated ketones

Also Published As

Publication number Publication date
LU48904A1 (en) 1965-08-24
NL6508424A (en) 1966-01-24
SE312797B (en) 1969-07-28
CH454123A (en) 1968-04-15
DE1202785B (en) 1965-10-14
AT267494B (en) 1968-12-27
NL151694B (en) 1976-12-15
US3401190A (en) 1968-09-10

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