ES361201A1 - Amides derived from trichlorothiophene - Google Patents
Amides derived from trichlorothiopheneInfo
- Publication number
- ES361201A1 ES361201A1 ES361201A ES361201A ES361201A1 ES 361201 A1 ES361201 A1 ES 361201A1 ES 361201 A ES361201 A ES 361201A ES 361201 A ES361201 A ES 361201A ES 361201 A1 ES361201 A1 ES 361201A1
- Authority
- ES
- Spain
- Prior art keywords
- trichlorothiophene
- reacting
- optionally substituted
- carboxylic acid
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D333/38—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Heterocyclic Compounds Containing Sulfur Atoms (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Novel trichlorothiophene-2-carboxylic acid amides of the Formula (I) wherein each of R and R1 is a hydrogen atom or an optionally substituted C 1-6 aliphatic, alkoxyalkyl, optionally substituted aryl, optionally substituted heterocyclic, or optionally substituted cycloaliphatic radical, or R and R1 complete a heterocyclic ring, are obtained by reacting trichlorothiophene-2-carboxylic acid chloride with ammonia or appropriate amines. The compounds have pesticidal properties (see Division A5). Trichlorothiophene-2-carboxylic acid chloride, used as starting material, may be obtained by reacting tetrachlorothiophene with magnesium in deperoxidized tetrahydrofuran to give an organo-magnesium compound, reacting this with carbon dioxide and hydrolysing the product and reacting the trichlorothiophene- 2-carboxylic acid so produced with thionyl chloride.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR69049417 | 1967-12-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES361201A1 true ES361201A1 (en) | 1970-11-01 |
Family
ID=9694953
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES361201A Expired ES361201A1 (en) | 1967-12-08 | 1968-12-07 | Amides derived from trichlorothiophene |
Country Status (10)
Country | Link |
---|---|
BE (1) | BE725017A (en) |
CH (1) | CH509746A (en) |
DE (1) | DE1813195A1 (en) |
DK (1) | DK119385B (en) |
ES (1) | ES361201A1 (en) |
FR (1) | FR1563735A (en) |
GB (1) | GB1241589A (en) |
IL (1) | IL31149A (en) |
NL (1) | NL6817502A (en) |
OA (1) | OA02941A (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE7694T1 (en) * | 1980-02-14 | 1984-06-15 | Grigg, Ronald Ernest | DERIVATIVES OF 2-METHYL-5-THIAZOLMETHYLAMINE AND CARBOXAMIDE. |
DE4011172A1 (en) * | 1990-04-06 | 1991-10-10 | Degussa | COMPOUNDS FOR CONTROLLING PLANT DISEASES |
DE4412333A1 (en) * | 1994-04-11 | 1995-10-12 | Bayer Ag | Microbicidal agents based on dibromo-thiophene-carboxylic acid derivatives |
MX2018008139A (en) * | 2015-12-30 | 2018-09-03 | Du Pont | Nematocidal heterocyclic amides. |
TWI823960B (en) * | 2018-07-05 | 2023-12-01 | 德商拜耳廠股份有限公司 | Substituted thiophenecarboxamides and analogues |
US20230055705A1 (en) * | 2019-12-20 | 2023-02-23 | Bayer Aktiengesellschaft | Substituted thiophene carboxamides and derivatives thereof |
-
1967
- 1967-12-08 FR FR69049417A patent/FR1563735A/fr not_active Expired
-
1968
- 1968-11-25 IL IL31149A patent/IL31149A/en unknown
- 1968-11-29 OA OA53435A patent/OA02941A/en unknown
- 1968-12-06 DK DK597768AA patent/DK119385B/en unknown
- 1968-12-06 GB GB58040/68A patent/GB1241589A/en not_active Expired
- 1968-12-06 BE BE725017D patent/BE725017A/fr unknown
- 1968-12-06 DE DE19681813195 patent/DE1813195A1/en active Pending
- 1968-12-06 NL NL6817502A patent/NL6817502A/xx unknown
- 1968-12-06 CH CH1827268A patent/CH509746A/en not_active IP Right Cessation
- 1968-12-07 ES ES361201A patent/ES361201A1/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
CH509746A (en) | 1971-07-15 |
GB1241589A (en) | 1971-08-04 |
DE1813195A1 (en) | 1969-08-14 |
OA02941A (en) | 1970-12-15 |
BE725017A (en) | 1969-06-06 |
FR1563735A (en) | 1969-04-18 |
IL31149A0 (en) | 1969-01-29 |
NL6817502A (en) | 1969-06-10 |
DK119385B (en) | 1970-12-21 |
IL31149A (en) | 1973-03-30 |
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