GB1033928A - Improvements in or relating to the manufacture of polyurethanes - Google Patents

Improvements in or relating to the manufacture of polyurethanes

Info

Publication number
GB1033928A
GB1033928A GB3302762A GB3302762A GB1033928A GB 1033928 A GB1033928 A GB 1033928A GB 3302762 A GB3302762 A GB 3302762A GB 3302762 A GB3302762 A GB 3302762A GB 1033928 A GB1033928 A GB 1033928A
Authority
GB
United Kingdom
Prior art keywords
mixture
oxide
weight
lead
reaction product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3302762A
Inventor
Ian Spencer Fox
John Francis Wood
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB3302762A priority Critical patent/GB1033928A/en
Priority to FR945940A priority patent/FR84481E/en
Priority to DE19631520125 priority patent/DE1520125A1/en
Publication of GB1033928A publication Critical patent/GB1033928A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/26—Catalysts containing metal compounds of lead

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

A composition for use in polyurethane production consists of a mixture of lead octoate and a reaction product of an alkylene oxide with an active hydrogen-containing compound, said mixture containing from 0.5 to 5.0 parts by weight of said reaction product for each part by weight of lead octoate. Preferred alkylene oxide reaction products are those derived from triethanolamine or triisopropanolamine with propylene oxide, block copolymers of ethylene oxide and propylene oxide and reaction products of octyl or nonyl phenol with 2-8 moles of ethylene oxide. The composition may be mixed with a polyhydroxy compound and reacted with an organic polyisocyanate to form a cellular or homogeneous polyurethane. Polyhydroxyl compounds may be polyesters, polyethers, polyesteramides. Conventional polyisocyanates are specified. In Examples (1) diphenylmethane diisocyanate was added to a mixture of oxypropylated trimethylolpropane, tri(b -chloroethyl)phosphate, siloxane block copolymer, FCCl3 and equal parts of lead 2-ethylhexoate and ethoxylated octyl phenol to produce a rigid foam (3) a mixture of equal parts of lead 2-ethylhexoate and ethoxylated octyl phenol was dissolved in propoxylated glycerol and the solution continuously mixed with more propoxylated glycerol, tolylene diisocyanate, triethylene diamine, water and siloxane. A foam resulted.ALSO:A catalytic composition comprises a mixture of lead octoate and a reaction product of an alkylene oxide with an active hydrogen-containing compound, said mixture containing from 0.5 to 5.0 parts by weight of said reaction product for each part by weight of lead octoate. Preferred alkylene oxide reaction products are those derived from triethanolamine or triisopropanolamine with propylene oxide, block copolymers of ethylene oxide and propylene oxide and reaction products of octyl or nonyl phenol with 2-8 moles of ethylene oxide. The composition may be mixed with a polyhydroxy compound and reacted with an organic polyisocyanate to from a cellular or homogeneous polyurethane.
GB3302762A 1962-08-28 1962-08-28 Improvements in or relating to the manufacture of polyurethanes Expired GB1033928A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB3302762A GB1033928A (en) 1962-08-28 1962-08-28 Improvements in or relating to the manufacture of polyurethanes
FR945940A FR84481E (en) 1962-08-28 1963-08-28 Manufacturing process of polymeric materials
DE19631520125 DE1520125A1 (en) 1962-08-28 1963-08-28 Process for the production of polymeric substances

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3302762A GB1033928A (en) 1962-08-28 1962-08-28 Improvements in or relating to the manufacture of polyurethanes

Publications (1)

Publication Number Publication Date
GB1033928A true GB1033928A (en) 1966-06-22

Family

ID=10347551

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3302762A Expired GB1033928A (en) 1962-08-28 1962-08-28 Improvements in or relating to the manufacture of polyurethanes

Country Status (2)

Country Link
DE (1) DE1520125A1 (en)
GB (1) GB1033928A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3324054A (en) * 1963-10-17 1967-06-06 Int Lead Zinc Res Production of polyurethane foams using arylleadtriester catalysts
US6368714B1 (en) * 1993-10-14 2002-04-09 John Russell Robertson Moisture-activated adhesive compositions

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3324054A (en) * 1963-10-17 1967-06-06 Int Lead Zinc Res Production of polyurethane foams using arylleadtriester catalysts
US6368714B1 (en) * 1993-10-14 2002-04-09 John Russell Robertson Moisture-activated adhesive compositions

Also Published As

Publication number Publication date
DE1520125A1 (en) 1969-07-10

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