GB1020866A - Epoxidised esters and their uses as plasticisers - Google Patents

Epoxidised esters and their uses as plasticisers

Info

Publication number
GB1020866A
GB1020866A GB2178661D GB2178661D GB1020866A GB 1020866 A GB1020866 A GB 1020866A GB 2178661 D GB2178661 D GB 2178661D GB 2178661 D GB2178661 D GB 2178661D GB 1020866 A GB1020866 A GB 1020866A
Authority
GB
United Kingdom
Prior art keywords
glycerol
tall oil
propylene glycol
ethylene glycol
tallate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2178661D
Inventor
Ronald Owen Brookings
James Lincoln
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Acordis UK Ltd
Original Assignee
British Celanese Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Celanese Ltd filed Critical British Celanese Ltd
Priority to GB2178661D priority Critical patent/GB1020866A/en
Publication of GB1020866A publication Critical patent/GB1020866A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/38—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D303/40—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by ester radicals
    • C07D303/42—Acyclic compounds having a chain of seven or more carbon atoms, e.g. epoxidised fats
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016—Plasticisers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1515—Three-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Epoxy Compounds (AREA)

Abstract

Epoxidized di-tall oil esters of propylene glycol, ethylene glycol or glycerol, or mixtures thereof (see Division C2) are suitable for use as P.V.C. plasticizers. An example of the use of glycerol diepoxy tallate is included.ALSO:Tall oil is esterified with one of the alcohols glycerol, propylene glycol or ethylene glycol or mixtures thereof in the mol. ratio substantially two moles of tall oil to one mol. of alcohol and the resulting diester is epoxidized, especially with peracetic acid to provide a plasticizer suitable for polyvinyl chloride compositions (see Division C3). In the examples a mixture of oxalic acid and triphenyl phosphite is employed as esterification catalyst in the preparation of the di-tall oil esters of propylene glycol, ethylene glycol and glycerol. The propylene glycol di-tallate is purified prior to epoxidation by passing a solution thereof through a column of ion exchanger.
GB2178661D 1961-06-16 1961-06-16 Epoxidised esters and their uses as plasticisers Expired GB1020866A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2178661D GB1020866A (en) 1961-06-16 1961-06-16 Epoxidised esters and their uses as plasticisers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2178661D GB1020866A (en) 1961-06-16 1961-06-16 Epoxidised esters and their uses as plasticisers

Publications (1)

Publication Number Publication Date
GB1020866A true GB1020866A (en) 1966-02-23

Family

ID=10168785

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2178661D Expired GB1020866A (en) 1961-06-16 1961-06-16 Epoxidised esters and their uses as plasticisers

Country Status (1)

Country Link
GB (1) GB1020866A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014072987A1 (en) * 2012-11-12 2014-05-15 Dow Global Technologies Llc Epoxidized fatty acid alkyl ester plasticizers and methods for making epoxidized fatty acid alkyl ester plasticizers
DE102013203972A1 (en) 2013-03-08 2014-09-11 Evonik Industries Ag Isononyl esters based on fatty acids or fatty acid mixtures of tall oil or linseed oil

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014072987A1 (en) * 2012-11-12 2014-05-15 Dow Global Technologies Llc Epoxidized fatty acid alkyl ester plasticizers and methods for making epoxidized fatty acid alkyl ester plasticizers
US9499681B2 (en) 2012-11-12 2016-11-22 Dow Global Technologies Llc Epoxidized fatty acid alkyl ester plasticizers and methods for making epoxidized fatty acid alkyl ester plasticizers
DE102013203972A1 (en) 2013-03-08 2014-09-11 Evonik Industries Ag Isononyl esters based on fatty acids or fatty acid mixtures of tall oil or linseed oil
WO2014135355A1 (en) 2013-03-08 2014-09-12 Evonik Industries Ag Fatty-acid based isononyl ester or fatty acid mixtures consisting of tall oil or linseed oil

Similar Documents

Publication Publication Date Title
GB943731A (en) Novel tertiary spiro phosphites and their production
US2895966A (en) Monoglyceride diacetates
GB1020866A (en) Epoxidised esters and their uses as plasticisers
GB969180A (en) Production of axerophthyl phosphonium salts
GB857382A (en) Prevention of development in color by iron compounds in plastics
GB920233A (en) Improvements in laminated safety glass and in the production thereof
US3050481A (en) Epoxidized monoglyceride diacetates as plasticizers for polymerized vinyl chloride
GB805252A (en) Plasticized polyvinyl resin compositions
GB874574A (en) Improvements in or relating to the stabilisation of polyvinylchloride
ES327415A1 (en) Procedure for preparing epoxy compounds. (Machine-translation by Google Translate, not legally binding)
GB513117A (en) Improvements in or relating to the manufacture of polyvinyl acetal resins
GB915624A (en) Catalyst compositions
GB786948A (en) New hexahydrotetralic esters, their preparation and their uses
GB1005192A (en) Plasticised polyvinyl acetate compositions
GB908184A (en) Polyvinyl resin compositions and epoxy-ester plasticisers therefor
GB1072245A (en) Improvements relating to microporous plastic materials
US2063144A (en) Ether alcohol esters of alicyclic carboxylic acids
GB747310A (en) Safety glass and adhesives for use in the production thereof
GB629142A (en) Improvements in or relating to stabilized vinyl halide compositions
GB1374360A (en) Transesterification of quinoxaline-2-carboxylic acid esters
US2424652A (en) Polyhydric alcohol esters of phenoxyacetoxyacetic acid
JPS5513765A (en) Fatty acid cellulose ester resin composition
GB996254A (en) Stabilized cellulose esters
GB833149A (en) Rauwolfia alkaloids and their extraction
GB943734A (en) Tris(tetrahydrofurfuryl)phosphate, the preparation thereof and use thereof as a plasticizer