GB1018374A - Electrical resistor and conducting film - Google Patents
Electrical resistor and conducting filmInfo
- Publication number
- GB1018374A GB1018374A GB1345064A GB1345064A GB1018374A GB 1018374 A GB1018374 A GB 1018374A GB 1345064 A GB1345064 A GB 1345064A GB 1345064 A GB1345064 A GB 1345064A GB 1018374 A GB1018374 A GB 1018374A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight
- sno2
- sb2o3
- metal oxide
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 abstract 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 5
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 abstract 5
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 abstract 5
- 229910044991 metal oxide Inorganic materials 0.000 abstract 4
- 150000004706 metal oxides Chemical class 0.000 abstract 4
- 239000000243 solution Substances 0.000 abstract 3
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 239000011521 glass Substances 0.000 abstract 2
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 abstract 2
- PSCMQHVBLHHWTO-UHFFFAOYSA-K indium(iii) chloride Chemical compound Cl[In](Cl)Cl PSCMQHVBLHHWTO-UHFFFAOYSA-K 0.000 abstract 2
- 230000001681 protective effect Effects 0.000 abstract 2
- 239000000758 substrate Substances 0.000 abstract 2
- KHMOASUYFVRATF-UHFFFAOYSA-J tin(4+);tetrachloride;pentahydrate Chemical compound O.O.O.O.O.Cl[Sn](Cl)(Cl)Cl KHMOASUYFVRATF-UHFFFAOYSA-J 0.000 abstract 2
- 229910001413 alkali metal ion Inorganic materials 0.000 abstract 1
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 1
- 238000000889 atomisation Methods 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001805 chlorine compounds Chemical class 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/18—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material comprising a plurality of layers stacked between terminals
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/25—Oxides by deposition from the liquid phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/25—Oxides by deposition from the liquid phase
- C03C17/253—Coating containing SnO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3417—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials all coatings being oxide coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/02—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material having positive temperature coefficient
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/02—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material having positive temperature coefficient
- H01C7/021—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material having positive temperature coefficient formed as one or more layers or coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/215—In2O3
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/228—Other specific oxides
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/23—Mixtures
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/23—Mixtures
- C03C2217/231—In2O3/SnO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/112—Deposition methods from solutions or suspensions by spraying
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Electromagnetism (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Non-Adjustable Resistors (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
An electrical resistor comprises a glass or ceramic substrate, preferably an aluminosilicate type glass free from alkali metal ions, over which is applied a primary conducting element consisting of a metal oxide film composed of 100-37% by weight of In2O3 and O-63% by weight of either SnO2 or a combination of SnO2 and Sb2O3 in which the ratio by weight of SnO2 to Sb2O3 is at least 3:2, and an outer modifying and protective metal oxide film composed of 100-50% by weight of Sb2O3 and 0-50% by weight of SnO2, spaced electrical terminals being in electrical contact with both metal oxide films. The metal oxide films may be produced by conventional iridizing techniques and it is convenient to use an aqueous solution in which chlorides of the relevant metals are dissolved in hydrochloric acid, the aqueous solution being atomized with suitable spray equipment and directed on to the heated substrate surface. A suitable solution for producing the primary conducting element by the atomization method is prepared by mixing 50 ml. of diluted aqueous HCl (1 part conc. HCl to 5 parts H2O) containing 50 gm. InCl3 with 50 ml. of the same diluted aqueous HCl containing 49,5 gm. SnCl4.5H2O and 0,5 gm. SbCl3. As calculated on the basis of molecular weight conversion factors, the conducting oxide film produced from this solution will contain approximately 60% by weight of In2O3, 39,4% by weight of SnO2 and 0,6% by weight of Sb2O3. A film forming solution for the outer modifying and protective film may contain 60 parts by weight of SbCl3 to 40 parts by weight of SnCl4.5H2O, the calculated oxide equivalents being 69% by weight of Sb2O3 and 31% by weight of SnO2. Graphs are given showing the relationship between surface resistivity and temperature coefficient of resistivity for resistors with oxide films of different compositions and thicknesses. Resistors according to this invention have been produced which have substantially zero temperature coefficients, stable resistance characteristics and resistivity values up to about 6000 ohms/square.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US27192763A | 1963-04-10 | 1963-04-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1018374A true GB1018374A (en) | 1966-01-26 |
Family
ID=23037669
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB192465A Expired GB1018375A (en) | 1963-04-10 | 1964-04-01 | An article comprising a substrate and a metal oxide film |
| GB1345064A Expired GB1018374A (en) | 1963-04-10 | 1964-04-01 | Electrical resistor and conducting film |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB192465A Expired GB1018375A (en) | 1963-04-10 | 1964-04-01 | An article comprising a substrate and a metal oxide film |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE646428A (en) |
| CH (2) | CH432610A (en) |
| DE (1) | DE1465365A1 (en) |
| FR (1) | FR1407090A (en) |
| GB (2) | GB1018375A (en) |
| NL (2) | NL6403878A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0996538A1 (en) * | 1997-07-07 | 2000-05-03 | Libbey-Owens-Ford Co. | Neutral grey absorbing film |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4618508A (en) * | 1983-03-21 | 1986-10-21 | Commissariat A L'energie Atomique | Process for producing composite layers |
| US4992772A (en) * | 1988-03-14 | 1991-02-12 | Taiyo Yuden Co., Ltd. | Metal oxide film resistor |
| DE10162276C5 (en) * | 2001-12-19 | 2019-03-14 | Watlow Electric Manufacturing Co. | Tubular water heater and heating plate and method for their preparation |
-
0
- NL NL127687D patent/NL127687C/xx active
-
1964
- 1964-04-01 GB GB192465A patent/GB1018375A/en not_active Expired
- 1964-04-01 GB GB1345064A patent/GB1018374A/en not_active Expired
- 1964-04-08 DE DE19641465365 patent/DE1465365A1/en active Pending
- 1964-04-09 FR FR970257A patent/FR1407090A/en not_active Expired
- 1964-04-10 CH CH459064A patent/CH432610A/en unknown
- 1964-04-10 CH CH436764A patent/CH432607A/en unknown
- 1964-04-10 NL NL6403878A patent/NL6403878A/xx unknown
- 1964-04-10 BE BE646428A patent/BE646428A/xx unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0996538A1 (en) * | 1997-07-07 | 2000-05-03 | Libbey-Owens-Ford Co. | Neutral grey absorbing film |
| EP0996538A4 (en) * | 1997-07-07 | 2002-11-04 | Libbey Owens Ford Co | Neutral grey absorbing film |
Also Published As
| Publication number | Publication date |
|---|---|
| NL6403878A (en) | 1964-10-12 |
| CH432610A (en) | 1967-03-31 |
| FR1407090A (en) | 1965-07-30 |
| NL127687C (en) | |
| GB1018375A (en) | 1966-01-26 |
| DE1465365A1 (en) | 1969-10-02 |
| CH432607A (en) | 1967-03-31 |
| BE646428A (en) | 1964-07-31 |
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