FR3079235B1 - Utilisation d'un copolymere d'ethylene et d'acrylate(s) prepare dans un reacteur tubulaire pour modifier la rheologie a l'etat fondu d'une composition thermoplastique - Google Patents

Utilisation d'un copolymere d'ethylene et d'acrylate(s) prepare dans un reacteur tubulaire pour modifier la rheologie a l'etat fondu d'une composition thermoplastique Download PDF

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Publication number
FR3079235B1
FR3079235B1 FR1852598A FR1852598A FR3079235B1 FR 3079235 B1 FR3079235 B1 FR 3079235B1 FR 1852598 A FR1852598 A FR 1852598A FR 1852598 A FR1852598 A FR 1852598A FR 3079235 B1 FR3079235 B1 FR 3079235B1
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France
Prior art keywords
acrylate
ethylene
copolymer
tubular reactor
thermoplastic composition
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Application number
FR1852598A
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English (en)
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FR3079235A1 (fr
Inventor
Paul Coupillaud
Sebastien Quinebeche
Alain Bouilloux
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Arkema France SA
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Arkema France SA
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Publication date
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to FR1852598A priority Critical patent/FR3079235B1/fr
Priority to TW108110263A priority patent/TWI845502B/zh
Priority to EP19720939.8A priority patent/EP3775045A1/fr
Priority to JP2020551355A priority patent/JP7412345B2/ja
Priority to KR1020207027955A priority patent/KR20200135375A/ko
Priority to US17/041,326 priority patent/US11555116B2/en
Priority to PCT/FR2019/050691 priority patent/WO2019186056A1/fr
Priority to CN201980022889.4A priority patent/CN111936579B/zh
Publication of FR3079235A1 publication Critical patent/FR3079235A1/fr
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Publication of FR3079235B1 publication Critical patent/FR3079235B1/fr
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B11/00—Making preforms
    • B29B11/06—Making preforms by moulding the material
    • B29B11/10—Extrusion moulding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0869—Acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/04—Thermoplastic elastomer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

La présente invention concerne l'utilisation d'un copolymère d'éthylène et d'acrylate(s) ayant un indice de fluidité à l'état fondu (MFI) supérieur ou égal à 50 g/ 10 minute obtenu par un procédé de copolymérisation radicalaire sous haute pression effectué dans un réacteur tubulaire. La présente invention est aussi relative à une composition thermoplastique, notamment destinée à être extrudée ou injectée par moulage, comprenant un ou plusieurs copolymères d'éthylène et d'acrylate(s), tel(s) que défini(s) ci-avant, dans une teneur allant de 0,1 à 20% en poids, et un ou plusieurs polymères thermoplastiques.
FR1852598A 2018-03-26 2018-03-26 Utilisation d'un copolymere d'ethylene et d'acrylate(s) prepare dans un reacteur tubulaire pour modifier la rheologie a l'etat fondu d'une composition thermoplastique Active FR3079235B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR1852598A FR3079235B1 (fr) 2018-03-26 2018-03-26 Utilisation d'un copolymere d'ethylene et d'acrylate(s) prepare dans un reacteur tubulaire pour modifier la rheologie a l'etat fondu d'une composition thermoplastique
TW108110263A TWI845502B (zh) 2018-03-26 2019-03-25 管狀反應器中製備的乙烯及丙烯酸酯共聚物於調整熱塑性組合物之熔體流變性之用途
JP2020551355A JP7412345B2 (ja) 2018-03-26 2019-03-26 熱可塑性組成物の溶融レオロジーを改質するために管型反応器で製造されたエチレンとアクリレートの共重合体の用途
KR1020207027955A KR20200135375A (ko) 2018-03-26 2019-03-26 열가소성 조성물의 용융 레올로지를 개질시키기 위해 관형 반응기에서 제조된 에틸렌과 아크릴레이트(들)의 공중합체의 용도
EP19720939.8A EP3775045A1 (fr) 2018-03-26 2019-03-26 Utilisation d'un copolymère d'éthylène et d'acrylate(s) préparé dans un réacteur tubulaire pour modifier la rhéologie à l'état fondu d'une composition thermoplastique
US17/041,326 US11555116B2 (en) 2018-03-26 2019-03-26 Use of a copolymer of ethylene and of acrylate(s) prepared in a tubular reactor for modifying the melt rheology of a thermoplastic composition
PCT/FR2019/050691 WO2019186056A1 (fr) 2018-03-26 2019-03-26 Utilisation d'un copolymère d'éthylène et d'acrylate(s) préparé dans un réacteur tubulaire pour modifier la rhéologie à l'état fondu d'une composition thermoplastique
CN201980022889.4A CN111936579B (zh) 2018-03-26 2019-03-26 在管式反应器中制备的乙烯和丙烯酸酯共聚物用于改变热塑性组合物的熔体流变性的用途

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1852598A FR3079235B1 (fr) 2018-03-26 2018-03-26 Utilisation d'un copolymere d'ethylene et d'acrylate(s) prepare dans un reacteur tubulaire pour modifier la rheologie a l'etat fondu d'une composition thermoplastique
FR1852598 2018-03-26

Publications (2)

Publication Number Publication Date
FR3079235A1 FR3079235A1 (fr) 2019-09-27
FR3079235B1 true FR3079235B1 (fr) 2020-12-25

Family

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FR1852598A Active FR3079235B1 (fr) 2018-03-26 2018-03-26 Utilisation d'un copolymere d'ethylene et d'acrylate(s) prepare dans un reacteur tubulaire pour modifier la rheologie a l'etat fondu d'une composition thermoplastique

Country Status (7)

Country Link
US (1) US11555116B2 (fr)
EP (1) EP3775045A1 (fr)
JP (1) JP7412345B2 (fr)
KR (1) KR20200135375A (fr)
CN (1) CN111936579B (fr)
FR (1) FR3079235B1 (fr)
WO (1) WO2019186056A1 (fr)

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9018144D0 (en) 1990-08-17 1990-10-03 Unilever Plc Polymerisation process
DE102004027872A1 (de) 2004-06-08 2006-01-05 Lanxess Deutschland Gmbh Polyamid-Formmassen mit verbesserter Fließfähigkeit
PL1756223T3 (pl) * 2004-06-08 2009-04-30 Lanxess Deutschland Gmbh Masy do formowania na bazie termoplastycznego poliestru o polepszonej zdolności płynięcia
KR100801832B1 (ko) * 2004-06-08 2008-02-11 란세스 도이치란트 게엠베하 유동성이 개선된 폴리아미드 성형 화합물
KR100630887B1 (ko) 2004-11-19 2006-10-02 삼성토탈 주식회사 다양한 물성의 제품을 높은 생산성으로 제조하기 위한에틸렌 중합방법 및 이에 이용되는 관형 반응기
DE102006006167A1 (de) 2005-04-06 2006-10-12 Lanxess Deutschland Gmbh Formmassen auf Basis eines thermoplastischen Polycarbonats
BRPI0614392A2 (pt) 2005-08-05 2011-03-22 Exxonmobil Chemical Patentes Inc processo e aparelho para fabricação de polìmeros e copolìmeros de etileno
DE102005050957A1 (de) * 2005-10-25 2007-04-26 Lanxess Deutschland Gmbh Formmassen auf Basis eines thermoplastischen Polyesters mit verbesserter Fließfähigkeit
DE102005050958A1 (de) * 2005-10-25 2007-04-26 Lanxess Deutschland Gmbh Polyamid-Formmassen mit verbesserter Fließfähigkeit
FR2912150B1 (fr) * 2007-02-06 2009-04-10 Arkema France Composition thermoplastique souple a tenue aux huiles amelioree et utilisation d'une telle composition
FR2938845B1 (fr) 2008-11-25 2012-12-28 Arkema France Composition thermoplastique a base de polyamide et de polyolefine
JP5879593B2 (ja) * 2012-01-30 2016-03-08 オリヱント化学工業株式会社 レーザー溶着用樹脂組成物及びその溶着体
FR3019553B1 (fr) * 2014-04-02 2020-07-31 Arkema France Nouvelle composition thermoplastique modifiee choc presentant une plus grande fluidite a l'etat fondu
EP3006506B9 (fr) * 2014-10-08 2017-07-19 Ems-Patent Ag Polyamide pouvant s'écouler

Also Published As

Publication number Publication date
US11555116B2 (en) 2023-01-17
TW201940527A (zh) 2019-10-16
JP7412345B2 (ja) 2024-01-12
US20210163739A1 (en) 2021-06-03
JP2021519353A (ja) 2021-08-10
EP3775045A1 (fr) 2021-02-17
WO2019186056A1 (fr) 2019-10-03
CN111936579B (zh) 2023-05-09
CN111936579A (zh) 2020-11-13
FR3079235A1 (fr) 2019-09-27
KR20200135375A (ko) 2020-12-02

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