FR3045366B1 - Polymere ethylenique phosphonique et ses applications en cosmetique - Google Patents
Polymere ethylenique phosphonique et ses applications en cosmetique Download PDFInfo
- Publication number
- FR3045366B1 FR3045366B1 FR1563115A FR1563115A FR3045366B1 FR 3045366 B1 FR3045366 B1 FR 3045366B1 FR 1563115 A FR1563115 A FR 1563115A FR 1563115 A FR1563115 A FR 1563115A FR 3045366 B1 FR3045366 B1 FR 3045366B1
- Authority
- FR
- France
- Prior art keywords
- meth
- weight
- acrylates
- branched
- linear
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002537 cosmetic Substances 0.000 title abstract 3
- 229920000573 polyethylene Polymers 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 4
- -1 polydimethylsiloxanes Polymers 0.000 abstract 3
- 102000011782 Keratins Human genes 0.000 abstract 2
- 108010076876 Keratins Proteins 0.000 abstract 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 abstract 1
- 229910021645 metal ion Inorganic materials 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 abstract 1
- 229920000768 polyamine Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 210000002374 sebum Anatomy 0.000 abstract 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 abstract 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 abstract 1
- 230000000699 topical effect Effects 0.000 abstract 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/882—Mixing prior to application
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/884—Sequential application
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
L'invention concerne un procédé cosmétique de soin ou de maquillage des matières kératiniques comprenant l'application topique sur les matières kératiniques d'une composition cosmétique comprenant un polymère phosphonique issu de la polymérisation de : (a) 45 à 95 % en poids, de monomère éthylénique ayant un groupe alkyle au moins en C8, linéaire ou ramifié ; (b) 5 à 25 % en poids de monomère acide vinyl phosphonique; (c) 0 à 50 % en poids de monomère additionnel choisi parmi les (méth)acrylates d'alkyl en C1-C6, linéaire ou ramifié, les (méth)acrylates de cycloalkyle en C6-C12, les polydiméthylsiloxanes à groupement terminal mono(méth)acryloyloxy, éventuellement associé avec un composé additionnel choisi parmi les composés polyaminés ayant plusieurs groupes amine primaire et/ou amine secondaire, les aminosilanes, les sels d'ions de métal divalent ou trivalent, les argiles, les oxydes métalliques. Le procédé permet d'obtenir un dépôt filmogène ayant une bonne résistance à l'eau, à l'huile et au sébum. Le film est également non collant et non transfert. L'invention concerne aussi les polymères contenant les 3 monomères (a), (b) et (c).
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1563115A FR3045366B1 (fr) | 2015-12-22 | 2015-12-22 | Polymere ethylenique phosphonique et ses applications en cosmetique |
CN201680075633.6A CN108430435A (zh) | 2015-12-22 | 2016-12-16 | 膦酸烯属聚合物及其化妆用途 |
ES16809854T ES2851302T3 (es) | 2015-12-22 | 2016-12-16 | Polímero etilénico fosfónico y usos cosméticos del mismo |
BR112018012682A BR112018012682A2 (pt) | 2015-12-22 | 2016-12-16 | processo cosmético, kit, composições e polímeros |
EP16809854.9A EP3393429B1 (fr) | 2015-12-22 | 2016-12-16 | Polymère éthylénique phosphonique et utilisations cosmétiques de celui-ci |
US16/062,946 US11207260B2 (en) | 2015-12-22 | 2016-12-16 | Phosphonic ethylenic polymer and cosmetic uses thereof |
KR1020187020817A KR20180095067A (ko) | 2015-12-22 | 2016-12-16 | 포스포닉 에틸렌 중합체 및 이의 미용적 용도 |
PCT/EP2016/081352 WO2017108599A1 (fr) | 2015-12-22 | 2016-12-16 | Polymère éthylénique phosphonique et utilisations cosmétiques de celui-ci |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1563115A FR3045366B1 (fr) | 2015-12-22 | 2015-12-22 | Polymere ethylenique phosphonique et ses applications en cosmetique |
FR1563115 | 2015-12-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3045366A1 FR3045366A1 (fr) | 2017-06-23 |
FR3045366B1 true FR3045366B1 (fr) | 2019-03-29 |
Family
ID=56068988
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR1563115A Active FR3045366B1 (fr) | 2015-12-22 | 2015-12-22 | Polymere ethylenique phosphonique et ses applications en cosmetique |
Country Status (8)
Country | Link |
---|---|
US (1) | US11207260B2 (fr) |
EP (1) | EP3393429B1 (fr) |
KR (1) | KR20180095067A (fr) |
CN (1) | CN108430435A (fr) |
BR (1) | BR112018012682A2 (fr) |
ES (1) | ES2851302T3 (fr) |
FR (1) | FR3045366B1 (fr) |
WO (1) | WO2017108599A1 (fr) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3064912B1 (fr) | 2017-04-07 | 2019-04-05 | L'oreal | Procede de coloration des cheveux comprenant un polymere ethylenique phosphonique et un pigment |
EP3787753A1 (fr) | 2018-05-03 | 2021-03-10 | HFC Prestige International Holding Switzerland S.a.r.l. | Composition à composants multiples |
EP3817826A2 (fr) * | 2018-07-06 | 2021-05-12 | HFC Prestige International Holding Switzerland S.a.r.l. | Composition à constituants multiples |
US11904042B2 (en) | 2018-07-06 | 2024-02-20 | HFC Prestige International Holding Switzerland S.a.r.l. | Hair coloring composition and methods for its application and removal |
FR3097438B1 (fr) * | 2019-06-24 | 2021-12-03 | Oreal | Composition anhydre comprenant au moins une silicone aminée, au moins un alcoxysilane et au moins un agent colorant |
FR3103704B1 (fr) | 2019-11-29 | 2022-07-08 | Oreal | Composition comprenant un filtre UV, un polymère éthylénique à groupe acide phosphonique et une huile hydrocarbonée |
FR3103705B1 (fr) | 2019-11-29 | 2021-12-17 | Oreal | Composition comprenant un filtre UV, un polymère séquencé à groupe acide phosphonique et une huile hydrocarbonée |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3817000A1 (de) * | 1988-05-19 | 1989-11-23 | Basf Ag | Kraftstoffe fuer ottomotoren |
DE4126230C2 (de) * | 1991-08-08 | 1994-02-17 | Lohmann Gmbh & Co Kg | Haftklebeband und seine Verwendung |
US6114426A (en) * | 1997-11-20 | 2000-09-05 | Lucent Technologies, Inc. | Pressure-sensitive flame retardant adhesive |
FR2867970B1 (fr) * | 2004-03-25 | 2006-05-05 | Oreal | Composition comprenant un compose monomerique a effet optique et procede employant ladite composition |
FR2871470B1 (fr) * | 2004-06-11 | 2007-01-12 | Oreal | Copolymere a gradient, composition et procede cosmetique de maquillage ou de soin |
US7813562B2 (en) * | 2004-09-27 | 2010-10-12 | Intel Corporation | Low-latency remote display rendering using tile-based rendering systems |
DE102005038608A1 (de) * | 2005-08-16 | 2007-02-22 | Basf Ag | Polymerzusammensetzung für den Korrosionsschutz |
DE202007014211U1 (de) * | 2007-10-10 | 2007-12-06 | Heuchemer, Klaus | Blendrahmen mit Wechselprofil |
WO2009050122A1 (fr) * | 2007-10-12 | 2009-04-23 | Basf Se | Copolymères de l'acide vinylphosphonique utilisés comme additifs dans des formulations de vernis durcissables par réticulation |
FR2937645B1 (fr) * | 2008-10-24 | 2010-12-17 | Oreal | Dispersion de particules souples de polymere, compostion cosmetique la comprenant et procede de traitement cosmetique |
JP5852301B2 (ja) * | 2009-07-02 | 2016-02-03 | キヤノン株式会社 | クリアインク、インクジェット記録方法、インクセット、インクカートリッジ、記録ユニット、及びインクジェット記録装置 |
JP6020185B2 (ja) * | 2013-01-17 | 2016-11-02 | 株式会社リコー | インクジェット記録用インク、インクカートリッジ、インクジェット記録方法、インクジェット記録装置、インク記録物、インク記録物の製造方法 |
-
2015
- 2015-12-22 FR FR1563115A patent/FR3045366B1/fr active Active
-
2016
- 2016-12-16 EP EP16809854.9A patent/EP3393429B1/fr active Active
- 2016-12-16 KR KR1020187020817A patent/KR20180095067A/ko active IP Right Grant
- 2016-12-16 BR BR112018012682A patent/BR112018012682A2/pt active Search and Examination
- 2016-12-16 WO PCT/EP2016/081352 patent/WO2017108599A1/fr active Application Filing
- 2016-12-16 US US16/062,946 patent/US11207260B2/en active Active
- 2016-12-16 ES ES16809854T patent/ES2851302T3/es active Active
- 2016-12-16 CN CN201680075633.6A patent/CN108430435A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
WO2017108599A1 (fr) | 2017-06-29 |
US11207260B2 (en) | 2021-12-28 |
EP3393429B1 (fr) | 2020-11-18 |
EP3393429A1 (fr) | 2018-10-31 |
ES2851302T3 (es) | 2021-09-06 |
KR20180095067A (ko) | 2018-08-24 |
FR3045366A1 (fr) | 2017-06-23 |
BR112018012682A2 (pt) | 2018-12-04 |
CN108430435A (zh) | 2018-08-21 |
US20180360729A1 (en) | 2018-12-20 |
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