FR3044666B1 - Copolyesters thermoplastiques comprenant du 1,4 : 3,6-dianhydrohexitol et divers diacides aromatiques - Google Patents

Copolyesters thermoplastiques comprenant du 1,4 : 3,6-dianhydrohexitol et divers diacides aromatiques Download PDF

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Publication number
FR3044666B1
FR3044666B1 FR1561757A FR1561757A FR3044666B1 FR 3044666 B1 FR3044666 B1 FR 3044666B1 FR 1561757 A FR1561757 A FR 1561757A FR 1561757 A FR1561757 A FR 1561757A FR 3044666 B1 FR3044666 B1 FR 3044666B1
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FR
France
Prior art keywords
dianhydrohexitol
units
various aromatic
aromatic diacids
thermoplastic copolyesters
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Active
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FR1561757A
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English (en)
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FR3044666A1 (fr
Inventor
Nicolas Jacquel
Gabriel Degand
Rene Saint-Loup
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roquette Freres SA
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Roquette Freres SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1561757A priority Critical patent/FR3044666B1/fr
Application filed by Roquette Freres SA filed Critical Roquette Freres SA
Priority to US15/781,406 priority patent/US20180355101A1/en
Priority to JP2018528614A priority patent/JP2018536072A/ja
Priority to KR1020187015251A priority patent/KR20180089419A/ko
Priority to EP16819969.3A priority patent/EP3383933A1/fr
Priority to CA3006898A priority patent/CA3006898A1/fr
Priority to MX2018006684A priority patent/MX2018006684A/es
Priority to PCT/FR2016/053179 priority patent/WO2017093684A1/fr
Priority to CN201680070700.5A priority patent/CN108368242A/zh
Publication of FR3044666A1 publication Critical patent/FR3044666A1/fr
Application granted granted Critical
Publication of FR3044666B1 publication Critical patent/FR3044666B1/fr
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/185—Acids containing aromatic rings containing two or more aromatic rings
    • C08G63/187—Acids containing aromatic rings containing two or more aromatic rings containing condensed aromatic rings
    • C08G63/189—Acids containing aromatic rings containing two or more aromatic rings containing condensed aromatic rings containing a naphthalene ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/80—Solid-state polycondensation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Materials Engineering (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

L'invention concerne un polyester thermoplastique comprenant : - au moins un motif 1,4 : 3,6-dianhydrohexitol (A) ; - au moins un motif diol alicyclique (B) autre que les motifs 1,4 : 3,6-dianhydrohexitol (A) ; - au moins un motif diacide carboxylique (C) choisi parmi les motifs acide furane 2,5-dicarboxylique , acide 2,6-naphtalique et acide isophtalique ; ledit polyester présentant au moins 10% de motifs 1,4 : 3,6-dianhydrohexitol (A) et étant exempt de motifs éthylène glycol et de motifs acide téréphtalique, sa fabrication et son utilisation.
FR1561757A 2015-12-02 2015-12-02 Copolyesters thermoplastiques comprenant du 1,4 : 3,6-dianhydrohexitol et divers diacides aromatiques Active FR3044666B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR1561757A FR3044666B1 (fr) 2015-12-02 2015-12-02 Copolyesters thermoplastiques comprenant du 1,4 : 3,6-dianhydrohexitol et divers diacides aromatiques
JP2018528614A JP2018536072A (ja) 2015-12-02 2016-12-02 １，４：３，６−ジアンヒドロヘキシトールと種々の芳香族二酸を含む、熱可塑性コポリエステル
KR1020187015251A KR20180089419A (ko) 2015-12-02 2016-12-02 1,4:3,6-디안하이드로헥시톨 및 다양한 방향족 이산을 포함하는 열가소성 코폴리에스테르
EP16819969.3A EP3383933A1 (fr) 2015-12-02 2016-12-02 Copolyesters thermoplastiques comprenant du 1,4 : 3,6-dianhydrohexitol et divers diacides aromatiques
US15/781,406 US20180355101A1 (en) 2015-12-02 2016-12-02 Thermoplastic copolyesters comprising 1,4:3,6-dianhydrohexitol and various aromatic diacids
CA3006898A CA3006898A1 (fr) 2015-12-02 2016-12-02 Copolyesters thermoplastiques comprenant du 1,4 : 3,6-dianhydrohexitol et divers diacides aromatiques
MX2018006684A MX2018006684A (es) 2015-12-02 2016-12-02 Copoliesteres termoplasticos que comprenden 1,4:3,6-dianhidrohexit ol y diversos diacidos aromaticos.
PCT/FR2016/053179 WO2017093684A1 (fr) 2015-12-02 2016-12-02 Copolyesters thermoplastiques comprenant du 1,4 : 3,6-dianhydrohexitol et divers diacides aromatiques
CN201680070700.5A CN108368242A (zh) 2015-12-02 2016-12-02 含1,4:3,6-双脱水己糖醇和各种芳香族二酸的热塑性共聚酯

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1561757A FR3044666B1 (fr) 2015-12-02 2015-12-02 Copolyesters thermoplastiques comprenant du 1,4 : 3,6-dianhydrohexitol et divers diacides aromatiques

Publications (2)

Publication Number Publication Date
FR3044666A1 FR3044666A1 (fr) 2017-06-09
FR3044666B1 true FR3044666B1 (fr) 2020-10-30

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
FR1561757A Active FR3044666B1 (fr) 2015-12-02 2015-12-02 Copolyesters thermoplastiques comprenant du 1,4 : 3,6-dianhydrohexitol et divers diacides aromatiques

Country Status (9)

Country Link
US (1) US20180355101A1 (fr)
EP (1) EP3383933A1 (fr)
JP (1) JP2018536072A (fr)
KR (1) KR20180089419A (fr)
CN (1) CN108368242A (fr)
CA (1) CA3006898A1 (fr)
FR (1) FR3044666B1 (fr)
MX (1) MX2018006684A (fr)
WO (1) WO2017093684A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITUA20162764A1 (it) * 2016-04-20 2017-10-20 Novamont Spa Nuovo poliestere e composizioni che lo contengono
KR102654779B1 (ko) 2016-11-24 2024-04-03 에스케이케미칼 주식회사 다층 mdo 내열 열수축성 필름
KR102654778B1 (ko) * 2016-11-24 2024-04-03 에스케이케미칼 주식회사 내열성 mdo 열수축 필름
CN109648966B (zh) * 2018-12-27 2020-11-13 合肥乐凯科技产业有限公司 一种高阻隔聚酯薄膜
US20230272161A1 (en) * 2020-08-27 2023-08-31 Furanix Technologies B.V. Ppreparing polyester comprising 2,5-furandicarboxylate units with germanium catalyst
CN113214611B (zh) * 2021-05-13 2022-07-01 浙江汇盎新材料科技有限公司 一种生物降解高阻隔复合用膜及其制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6063464A (en) * 1998-04-23 2000-05-16 Hna Holdings, Inc. Isosorbide containing polyesters and methods for making same
US6914120B2 (en) * 2002-11-13 2005-07-05 Eastman Chemical Company Method for making isosorbide containing polyesters
US10800878B2 (en) * 2011-10-14 2020-10-13 Eastman Chemical Company Polyester compositions containing furandicarboxylic acid or an ester thereof, cyclobutanediol and ethylene glycol
WO2014100257A2 (fr) * 2012-12-20 2014-06-26 Dow Global Technologies Llc Polyesters à base de ndca fabriqués avec de l'isosorbide
FR3020811B1 (fr) * 2014-05-09 2016-06-10 Roquette Freres Polyesters aromatiques thermoplastiques comprenant des motifs tetrahydrofuranedimethanol et acide furanedicarboxylique

Also Published As

Publication number Publication date
CN108368242A (zh) 2018-08-03
JP2018536072A (ja) 2018-12-06
EP3383933A1 (fr) 2018-10-10
CA3006898A1 (fr) 2017-06-08
KR20180089419A (ko) 2018-08-08
US20180355101A1 (en) 2018-12-13
FR3044666A1 (fr) 2017-06-09
MX2018006684A (es) 2018-08-24
WO2017093684A1 (fr) 2017-06-08

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