FR3027603B1 - Composition a base de polyarylene-ether-cetone a proprietes ameliorees - Google Patents

Composition a base de polyarylene-ether-cetone a proprietes ameliorees

Info

Publication number: FR3027603B1
Authority: FR; France
Prior art keywords: ketone; improved properties; composition based; polyarylene ether; polyarylene
Prior art date: 2014-10-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

FR1460158A

Other languages

English (en)

Other versions

FR3027603A1 (fr

Inventor

Benoit Brule

Richard Audry

Jerome Pascal

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Arkema France SA

Original Assignee

Arkema France SA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2014-10-22

Filing date

2014-10-22

Publication date

2016-11-18

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=52589492&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=FR3027603(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

2014-10-22 Application filed by Arkema France SA filed Critical Arkema France SA

2014-10-22 Priority to FR1460158A priority Critical patent/FR3027603B1/fr

2015-10-09 Priority to EP15775727.9A priority patent/EP3209729B1/fr

2015-10-09 Priority to MX2017005144A priority patent/MX2017005144A/es

2015-10-09 Priority to US15/520,913 priority patent/US10150866B2/en

2015-10-09 Priority to CA2965371A priority patent/CA2965371C/fr

2015-10-09 Priority to CN201580062632.3A priority patent/CN107001787B/zh

2015-10-09 Priority to BR112017007941-0A priority patent/BR112017007941B1/pt

2015-10-09 Priority to RU2017115887A priority patent/RU2677666C2/ru

2015-10-09 Priority to KR1020177013482A priority patent/KR101855054B1/ko

2015-10-09 Priority to PCT/EP2015/073349 priority patent/WO2016062558A1/fr

2015-10-09 Priority to JP2017521508A priority patent/JP6505219B2/ja

2015-10-09 Priority to EP15189066.2A priority patent/EP3012297B2/fr

2015-10-09 Priority to ES15189066.2T priority patent/ES2638654T3/es

2015-10-09 Priority to ES15775727T priority patent/ES2711305T3/es

2015-10-22 Priority to US14/920,075 priority patent/US9624371B2/en

2016-04-29 Publication of FR3027603A1 publication Critical patent/FR3027603A1/fr

2016-11-18 Publication of FR3027603B1 publication Critical patent/FR3027603B1/fr

2016-11-18 Application granted granted Critical

2018-11-29 Priority to US16/204,290 priority patent/US20190203044A1/en

2019-02-12 Priority to JP2019022785A priority patent/JP6823675B2/ja

2022-11-28 Priority to US18/059,120 priority patent/US20230085897A1/en

Status Active legal-status Critical Current

2034-10-22 Anticipated expiration legal-status Critical

Links

229920000412 polyarylene Polymers 0.000 title 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
- C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
- C08G65/4012—Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/48—Polymers modified by chemical after-treatment
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/16—Condensation polymers of aldehydes or ketones with phenols only of ketones with phenols
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G2650/28—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
- C08G2650/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing oxygen in addition to the ether group
- C08G2650/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing oxygen in addition to the ether group containing ketone groups, e.g. polyarylethylketones, PEEK or PEK
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Compositions Of Macromolecular Compounds (AREA)
Processes Of Treating Macromolecular Substances (AREA)
Injection Moulding Of Plastics Or The Like (AREA)

FR1460158A 2014-10-22 2014-10-22 Composition a base de polyarylene-ether-cetone a proprietes ameliorees Active FR3027603B1 (fr)

Priority Applications (18)

Application Number	Priority Date	Filing Date	Title
FR1460158A FR3027603B1 (fr)	2014-10-22	2014-10-22	Composition a base de polyarylene-ether-cetone a proprietes ameliorees
JP2017521508A JP6505219B2 (ja)	2014-10-22	2015-10-09	改善された特性を有するポリ（アリーレンエーテルケトン）に基づく組成物
ES15189066.2T ES2638654T3 (es)	2014-10-22	2015-10-09	Composición basada en poli(arilenoetercetona) que tiene propiedades mejoradas
US15/520,913 US10150866B2 (en)	2014-10-22	2015-10-09	Composition based on poly (arylene ether ketone) having improved properties
CA2965371A CA2965371C (fr)	2014-10-22	2015-10-09	Composition a base de poly(arylene ether cetone) ayant des proprietes ameliorees
CN201580062632.3A CN107001787B (zh)	2014-10-22	2015-10-09	具有改善的性质的基于聚(亚芳基醚酮)的组合物
BR112017007941-0A BR112017007941B1 (pt)	2014-10-22	2015-10-09	Composição com base em poli(arileno éter cetona), processo para a preparação da referida composição, uso da mesma e objeto fabricado a partir desta
RU2017115887A RU2677666C2 (ru)	2014-10-22	2015-10-09	Композиция на основе поли(ариленэфиркетона), имеющая улучшенные свойства
KR1020177013482A KR101855054B1 (ko)	2014-10-22	2015-10-09	개선된 특성을 갖는 폴리(아릴렌 에테르 케톤)을 기반으로 하는 조성물
PCT/EP2015/073349 WO2016062558A1 (fr)	2014-10-22	2015-10-09	Composition à base de poly(arylène éther cétone) ayant des propriétés améliorées
EP15775727.9A EP3209729B1 (fr)	2014-10-22	2015-10-09	Composition a base de polyarylene-ether-cetone a proprietes ameliorees
EP15189066.2A EP3012297B2 (fr)	2014-10-22	2015-10-09	Composition à base de poly (arylène éther cétone) ayant des propriétés améliorées
MX2017005144A MX2017005144A (es)	2014-10-22	2015-10-09	Composicion basada en poli(arilen-eter-cetona) que tiene propiedades mejoradas.
ES15775727T ES2711305T3 (es)	2014-10-22	2015-10-09	Composición basada en poli(arilenoetercetona) que tiene propiedades mejoradas
US14/920,075 US9624371B2 (en)	2014-10-22	2015-10-22	Composition based on poly(arylene ether ketone) having improved properties
US16/204,290 US20190203044A1 (en)	2014-10-22	2018-11-29	Composition based on poly (arylene ether ketone) having improved properties
JP2019022785A JP6823675B2 (ja)	2014-10-22	2019-02-12	改善された特性を有するポリ（アリーレンエーテルケトン）に基づく組成物
US18/059,120 US20230085897A1 (en)	2014-10-22	2022-11-28	Composition based on poly (arylene ether ketone) having improved properties

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR1460158A FR3027603B1 (fr)	2014-10-22	2014-10-22	Composition a base de polyarylene-ether-cetone a proprietes ameliorees

Publications (2)

Publication Number	Publication Date
FR3027603A1 FR3027603A1 (fr)	2016-04-29
FR3027603B1 true FR3027603B1 (fr)	2016-11-18

Family

ID=52589492

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FR1460158A Active FR3027603B1 (fr)	2014-10-22	2014-10-22	Composition a base de polyarylene-ether-cetone a proprietes ameliorees

Country Status (12)

Country	Link
US (4)	US10150866B2 (fr)
EP (2)	EP3012297B2 (fr)
JP (2)	JP6505219B2 (fr)
KR (1)	KR101855054B1 (fr)
CN (1)	CN107001787B (fr)
BR (1)	BR112017007941B1 (fr)
CA (1)	CA2965371C (fr)
ES (2)	ES2638654T3 (fr)
FR (1)	FR3027603B1 (fr)
MX (1)	MX2017005144A (fr)
RU (1)	RU2677666C2 (fr)
WO (1)	WO2016062558A1 (fr)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR3027603B1 (fr) *	2014-10-22	2016-11-18	Arkema France	Composition a base de polyarylene-ether-cetone a proprietes ameliorees
WO2017153290A1 (fr)	2016-03-09	2017-09-14	Solvay Specialty Polymers Usa, Llc	Compositions de polyaryléthercétone et procédé de revêtement d'une surface métallique
US11352480B2 (en)	2016-03-18	2022-06-07	Ticona Llc	Polyaryletherketone composition
CN109843973B (zh)	2016-08-02	2021-12-03	索尔维特殊聚合物美国有限责任公司	包含低分子量芳香族化合物的聚(芳醚酮)(paek)组合物
FR3065002B1 (fr) *	2017-04-05	2020-05-15	Arkema France	Procede d'impregnation de fibres de renfort avec des polyarylethercetones et semi-produits ainsi obtenus
FR3070979B1 (fr) *	2017-09-08	2019-08-30	Arkema France	Pieces en polyether cetone cetone presentant une stabilite dimensionnelle amelioree
BR112020005065A2 (pt) *	2017-09-15	2020-09-15	Arkema Inc.	processos e produtos de fabricação de aditivos para extrusão de pekk
FR3071184B1 (fr) *	2017-09-18	2021-11-19	Arkema France	Procede d'impregnation de fibres de renfort avec des polyarylethercetones et semi-produits ainsi obtenus
FR3074184B1 (fr) *	2017-11-27	2020-07-24	Arkema France	Utilisation de pekk pour la fabrication de pieces a faible permeabilite gazeuse
US11118053B2 (en)	2018-03-09	2021-09-14	Ticona Llc	Polyaryletherketone/polyarylene sulfide composition
JP7197420B2 (ja) *	2019-03-29	2022-12-27	エセックス古河マグネットワイヤジャパン株式会社	絶縁電線、コイル、及び電気・電子機器
EP3825345A1 (fr) *	2019-11-19	2021-05-26	Arkema France	Poudre améliorée pour une fabrication additive
CN115702209A (zh) *	2020-06-11	2023-02-14	索尔维特殊聚合物美国有限责任公司	纤维增强热塑性基质复合材料
CN115698130A (zh) *	2020-06-11	2023-02-03	索尔维特殊聚合物美国有限责任公司	聚(醚酮酮)聚合物的共混物
EP4008742A1 (fr) *	2020-12-04	2022-06-08	Arkema France	Composition pulvérulente à base de paek(s), procédé de construction de frittage et objet dérivé de ceux-ci
EP4271725A1 (fr) *	2020-12-30	2023-11-08	Arkema France	Procédé de fabrication additive par extrusion d'une composition à base de poly-éther-cétone-cétone

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US3516966A (en) *	1968-02-05	1970-06-23	Du Pont	Polyketone copolymers
US4609714A (en)	1983-09-29	1986-09-02	Union Carbide Corporation	Blends of poly(aryl ketones)
JPS61500021A (ja) *	1983-09-29	1986-01-09	アモコ、コ−ポレ−ション	ポリ（アリ−ルケトン）から成るブレンド
US4774296A (en) *	1985-05-02	1988-09-27	Amoco Corporation	Block polymers containing a poly(aryl ether ketone) and methods for their production
US4668744A (en) *	1985-10-15	1987-05-26	Amoco Corporation	Novel poly(aryl ether ketone) polyester block copolymers
US4959423A (en)	1987-04-20	1990-09-25	Amoco Corporation	Nucleating agents for poly(aryl ether ketones)
US4996287A (en) *	1988-12-13	1991-02-26	E. I. Du Pont De Nemours And Company	Thermoformable polyaryletherketone sheet
US5124413A (en) *	1990-09-13	1992-06-23	E. I. Du Pont De Nemours And Company	Films or sheets of blends of amorpous poly(aryl ether ketones) with polyarylates and laminates thereof
DE4039924A1 (de) *	1990-12-14	1992-06-17	Hoechst Ag	Legierungen aus teilkristallinen und amorphen polyaryletherketonen
WO2009058362A1 (fr)	2007-11-02	2009-05-07	Polymics, Ltd.	Structure de protection de substrat à haute température
US9895842B2 (en) *	2008-05-20	2018-02-20	Eos Gmbh Electro Optical Systems	Selective sintering of structurally modified polymers
JP2010095615A (ja) *	2008-10-16	2010-04-30	Kaneka Corp	ポリエーテルエーテルケトン、それを含有する樹脂組成物、およびその成形体
US9422654B2 (en) *	2009-03-20	2016-08-23	Arkema Inc.	Polyetherketoneketone nonwoven mats
FR3027603B1 (fr) *	2014-10-22	2016-11-18	Arkema France	Composition a base de polyarylene-ether-cetone a proprietes ameliorees

2014
- 2014-10-22 FR FR1460158A patent/FR3027603B1/fr active Active
2015
- 2015-10-09 MX MX2017005144A patent/MX2017005144A/es unknown
- 2015-10-09 CN CN201580062632.3A patent/CN107001787B/zh active Active
- 2015-10-09 EP EP15189066.2A patent/EP3012297B2/fr active Active
- 2015-10-09 ES ES15189066.2T patent/ES2638654T3/es active Active
- 2015-10-09 US US15/520,913 patent/US10150866B2/en active Active
- 2015-10-09 ES ES15775727T patent/ES2711305T3/es active Active
- 2015-10-09 CA CA2965371A patent/CA2965371C/fr active Active
- 2015-10-09 JP JP2017521508A patent/JP6505219B2/ja active Active
- 2015-10-09 BR BR112017007941-0A patent/BR112017007941B1/pt active IP Right Grant
- 2015-10-09 KR KR1020177013482A patent/KR101855054B1/ko active IP Right Grant
- 2015-10-09 EP EP15775727.9A patent/EP3209729B1/fr active Active
- 2015-10-09 RU RU2017115887A patent/RU2677666C2/ru active
- 2015-10-09 WO PCT/EP2015/073349 patent/WO2016062558A1/fr active Application Filing
- 2015-10-22 US US14/920,075 patent/US9624371B2/en active Active
2018
- 2018-11-29 US US16/204,290 patent/US20190203044A1/en not_active Abandoned
2019
- 2019-02-12 JP JP2019022785A patent/JP6823675B2/ja active Active
2022
- 2022-11-28 US US18/059,120 patent/US20230085897A1/en active Pending

Also Published As

Publication number	Publication date
RU2017115887A3 (fr)	2018-11-23
KR20170063961A (ko)	2017-06-08
RU2677666C2 (ru)	2019-01-18
JP6505219B2 (ja)	2019-04-24
FR3027603A1 (fr)	2016-04-29
US9624371B2 (en)	2017-04-18
US20170335101A1 (en)	2017-11-23
BR112017007941B1 (pt)	2021-08-24
WO2016062558A1 (fr)	2016-04-28
US20190203044A1 (en)	2019-07-04
ES2638654T3 (es)	2017-10-23
EP3209729B1 (fr)	2018-07-11
RU2017115887A (ru)	2018-11-23
KR101855054B1 (ko)	2018-05-04
CA2965371C (fr)	2019-08-06
EP3012297A1 (fr)	2016-04-27
JP2019112640A (ja)	2019-07-11
EP3209729A1 (fr)	2017-08-30
CA2965371A1 (fr)	2016-04-28
US10150866B2 (en)	2018-12-11
ES2711305T3 (es)	2019-05-03
JP2017531726A (ja)	2017-10-26
CN107001787B (zh)	2019-08-02
EP3012297B1 (fr)	2017-06-28
CN107001787A (zh)	2017-08-01
JP6823675B2 (ja)	2021-02-03
BR112017007941A2 (pt)	2017-12-19
US20160115314A1 (en)	2016-04-28
US20230085897A1 (en)	2023-03-23
MX2017005144A (es)	2017-07-24
EP3012297B2 (fr)	2020-08-26

Legal Events

Date	Code	Title	Description
2015-09-08	PLFP	Fee payment	Year of fee payment: 2
2016-04-29	PLSC	Publication of the preliminary search report	Effective date: 20160429
2016-09-19	PLFP	Fee payment	Year of fee payment: 3
2017-09-18	PLFP	Fee payment	Year of fee payment: 4
2018-09-13	PLFP	Fee payment	Year of fee payment: 5
2019-09-13	PLFP	Fee payment	Year of fee payment: 6
2020-09-14	PLFP	Fee payment	Year of fee payment: 7
2021-09-13	PLFP	Fee payment	Year of fee payment: 8
2022-09-08	PLFP	Fee payment	Year of fee payment: 9
2023-09-11	PLFP	Fee payment	Year of fee payment: 10

Publication	Publication Date	Title
FR3027603B1 (fr)	2016-11-18	Composition a base de polyarylene-ether-cetone a proprietes ameliorees
DK3151672T3 (da)	2021-02-01	Forbedrede t-celle-sammensætninger
DK3140008T3 (da)	2019-06-24	Hurtigtvirkende insulinsammensætninger
DK2984138T3 (da)	2017-11-27	Polymersammensætning
DE112015004002A5 (de)	2017-05-18	Leuchtdiodenbauteil
DK3034453T4 (da)	2024-06-03	Udstyr med sideskifter
SG11201703172XA (en)	2017-05-30	Polymer compositions
DK3133931T3 (da)	2021-08-23	Støbemaskine med stikforbindelse
DK3129474T3 (da)	2019-10-28	Laccasevarianter med forbedrede egenskaber
SG11201700510XA (en)	2017-02-27	Self-lubricating polymer composition
DE112015001058A5 (de)	2016-12-01	Schalter
PL2985779T3 (pl)	2021-10-25	Podstawa uchwytu bezpiecznikowego
BR112016026478A2 (pt)	2017-08-15	Composição de polímero à base de propileno
TWI560454B (en)	2016-12-01	Testing base
PL3102633T3 (pl)	2018-09-28	Kompozycja polimerowa
DE112015005367A5 (de)	2017-08-10	Lichtemittierendes Bauelement
FR3021870B1 (fr)	2017-10-27	Composition dermatologique a base de niacinamide
DK3265518T3 (da)	2023-07-10	Fyldstoffer
FR3020371B1 (fr)	2016-05-27	Composition thermoplastique
TH1501007505A (th)	2017-12-21	องค์ประะกอบโพลีเมอร์
TH177000B (th)	2018-06-14	การย่อยสลายพอลิเมอร์
FI11113U1 (fi)	2016-01-21	Ruiskutuslaitteisto
ES1141181Y (es)	2015-09-30	Envase con abrefacil incorporado
TH1601000601A (th)	2018-04-26	อุปกรณ์การฉีด
ES1138958Y (es)	2015-07-29	Aguja percutora