FR2987498B1 - Sulfates utiles comme materiaux d'electrode - Google Patents

Sulfates utiles comme materiaux d'electrode

Info

Publication number
FR2987498B1
FR2987498B1 FR1251854A FR1251854A FR2987498B1 FR 2987498 B1 FR2987498 B1 FR 2987498B1 FR 1251854 A FR1251854 A FR 1251854A FR 1251854 A FR1251854 A FR 1251854A FR 2987498 B1 FR2987498 B1 FR 2987498B1
Authority
FR
France
Prior art keywords
electrode materials
sulfates useful
sulfates
useful
electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1251854A
Other languages
English (en)
Other versions
FR2987498A1 (fr
Inventor
Marine Reynaud
Mohamed Ati
Jean-Noel Chotard
Jean-Marie Tarascon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Universite de Picardie Jules Verne
Original Assignee
Centre National de la Recherche Scientifique CNRS
Universite de Picardie Jules Verne
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Universite de Picardie Jules Verne filed Critical Centre National de la Recherche Scientifique CNRS
Priority to FR1251854A priority Critical patent/FR2987498B1/fr
Priority to EP13714986.0A priority patent/EP2820705A1/fr
Priority to JP2014559277A priority patent/JP6228142B2/ja
Priority to PCT/FR2013/050397 priority patent/WO2013128115A1/fr
Priority to US14/378,699 priority patent/US20150017322A1/en
Publication of FR2987498A1 publication Critical patent/FR2987498A1/fr
Application granted granted Critical
Publication of FR2987498B1 publication Critical patent/FR2987498B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/96—Methods for the preparation of sulfates in general
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
    • C01D5/02—Preparation of sulfates from alkali metal salts and sulfuric acid or bisulfates; Preparation of bisulfates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/009—Compounds containing, besides iron, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/14—Sulfates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0438—Processes of manufacture in general by electrochemical processing
    • H01M4/044—Activating, forming or electrochemical attack of the supporting material
    • H01M4/0445—Forming after manufacture of the electrode, e.g. first charge, cycling
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/049—Manufacturing of an active layer by chemical means
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)
FR1251854A 2012-02-29 2012-02-29 Sulfates utiles comme materiaux d'electrode Expired - Fee Related FR2987498B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1251854A FR2987498B1 (fr) 2012-02-29 2012-02-29 Sulfates utiles comme materiaux d'electrode
EP13714986.0A EP2820705A1 (fr) 2012-02-29 2013-02-27 Sulfates utiles comme matériaux d'électrode
JP2014559277A JP6228142B2 (ja) 2012-02-29 2013-02-27 電極物質として使用する硫酸塩
PCT/FR2013/050397 WO2013128115A1 (fr) 2012-02-29 2013-02-27 Sulfates utiles comme matériaux d'électrode
US14/378,699 US20150017322A1 (en) 2012-02-29 2013-02-27 Sulphates of use as electrode materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1251854A FR2987498B1 (fr) 2012-02-29 2012-02-29 Sulfates utiles comme materiaux d'electrode

Publications (2)

Publication Number Publication Date
FR2987498A1 FR2987498A1 (fr) 2013-08-30
FR2987498B1 true FR2987498B1 (fr) 2017-08-11

Family

ID=46489362

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1251854A Expired - Fee Related FR2987498B1 (fr) 2012-02-29 2012-02-29 Sulfates utiles comme materiaux d'electrode

Country Status (5)

Country Link
US (1) US20150017322A1 (fr)
EP (1) EP2820705A1 (fr)
JP (1) JP6228142B2 (fr)
FR (1) FR2987498B1 (fr)
WO (1) WO2013128115A1 (fr)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160226069A1 (en) * 2013-09-11 2016-08-04 The University Of Tokyo Positive electrode material for sodium ion secondary batteries
GB201414959D0 (en) * 2014-08-22 2014-10-08 Faradion Ltd Sodium-ion energy storage devices
JP6583434B2 (ja) * 2016-01-06 2019-10-02 株式会社村田製作所 非水系二次電池、並びに、非水系二次電池用の正極活物質及びその製造方法
US11289700B2 (en) 2016-06-28 2022-03-29 The Research Foundation For The State University Of New York KVOPO4 cathode for sodium ion batteries
CN106058251B (zh) * 2016-08-12 2018-05-25 中南大学 一种钠离子电池正极Na2Fe2(SO4)3@氧化铝复合材料及其制备方法
CN106848236B (zh) * 2017-02-20 2019-04-09 中南大学 一种用于钠离子电池的硫酸亚铁钠/石墨烯复合正极材料及其制备方法
CN110326136B (zh) * 2017-09-13 2022-07-08 辽宁星空钠电电池有限公司 一种新型高电位多层碳包覆聚阴离子型钠离子电池正极材料及其制备方法
PL236442B1 (pl) * 2017-11-27 2021-01-11 Akademia Gorniczo Hutnicza Im Stanislawa Staszica W Krakowie Sposób otrzymywania materiału na katody dla odwracalnych ogniw sodowych
CN108023083A (zh) * 2017-12-04 2018-05-11 惠州亿纬锂能股份有限公司 一种提升电池高温储存性能和过充安全性能的方法
CN111063871B (zh) * 2019-12-09 2020-11-24 苏州大学 一种钠离子全电池及其制备方法
CN110931784B (zh) * 2019-12-09 2020-11-24 苏州大学 铁基钠离子电池正极材料及其制备方法
US20210202946A1 (en) * 2019-12-09 2021-07-01 Soochow University Iron-based cathode material for sodium-ion battery, preparation method thereof, and corresponding sodium-ion full battery
US11688853B2 (en) * 2021-01-13 2023-06-27 Nrgtek, Inc. Metal-free high-voltage cathodes for secondary lithium-ion and alkali-ion batteries
CN114792788A (zh) * 2022-04-08 2022-07-26 江苏众钠能源科技有限公司 一种钠离子全电池及其制备方法
CN115849454B (zh) * 2022-11-22 2023-07-11 湖北万润新能源科技股份有限公司 硫酸亚铁钠正极材料的制备方法
CN116154154B (zh) * 2023-04-13 2023-07-04 深圳珈钠能源科技有限公司 纯相聚阴离子型硫酸盐钠离子电池正极材料及其制备方法
CN116435487B (zh) * 2023-04-28 2024-01-19 深圳先进技术研究院 一种NaxFe3-0.5x(SO4)3@C正极材料的制备方法和应用
CN117326595B (zh) * 2023-09-15 2024-04-19 广东钠壹新能源科技有限公司 一种硫酸铁钠正极材料及其制备方法和应用

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5695893A (en) * 1995-05-18 1997-12-09 Nippon Telegraph And Telephone Corporation Material for use in the positive electrodes of lithium batteries, its manufacture, and lithium batteries incorporating this material
JP3436292B2 (ja) * 1995-05-18 2003-08-11 日本電信電話株式会社 リチウム電池用正極材料、その製造方法及びそれを用いたリチウム電池
JP4001947B2 (ja) * 1995-12-21 2007-10-31 ソニー株式会社 リチウム二次電池用正極活物質の製造方法
JPH10116628A (ja) * 1996-10-11 1998-05-06 Hitachi Ltd リチウム二次電池
US5908716A (en) * 1997-04-15 1999-06-01 Valence Technology, Inc. Lithium--containing sulfates, method of preparation and uses thereof
CA2270771A1 (fr) * 1999-04-30 2000-10-30 Hydro-Quebec Nouveaux materiaux d'electrode presentant une conductivite de surface elevee
US7087348B2 (en) * 2002-07-26 2006-08-08 A123 Systems, Inc. Coated electrode particles for composite electrodes and electrochemical cells
US20050163699A1 (en) 2004-01-23 2005-07-28 Jeremy Barker Fluorosulfate-based electrode active materials and method of making the same
EP1880436B1 (fr) * 2005-04-22 2017-07-19 LG Chem, Ltd. Systeme de batterie aux ions lithium contenant un materiau a haute capacite irreversible
JP5607058B2 (ja) * 2008-10-23 2014-10-15 サントル ナスィオナル ド ラ ルシェルシュ スィアンティフィク 電極材料として有用なフルオロ硫酸塩
GB201201717D0 (en) * 2012-02-01 2012-03-14 Faradion Ltd Sulfate electrodes

Also Published As

Publication number Publication date
EP2820705A1 (fr) 2015-01-07
WO2013128115A1 (fr) 2013-09-06
FR2987498A1 (fr) 2013-08-30
JP6228142B2 (ja) 2017-11-08
US20150017322A1 (en) 2015-01-15
JP2015515084A (ja) 2015-05-21

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