FR2954312B1 - Procede de preparation d'acroleine par deshydratation catalytique de glycerol ou glycerine - Google Patents
Procede de preparation d'acroleine par deshydratation catalytique de glycerol ou glycerineInfo
- Publication number
- FR2954312B1 FR2954312B1 FR0959276A FR0959276A FR2954312B1 FR 2954312 B1 FR2954312 B1 FR 2954312B1 FR 0959276 A FR0959276 A FR 0959276A FR 0959276 A FR0959276 A FR 0959276A FR 2954312 B1 FR2954312 B1 FR 2954312B1
- Authority
- FR
- France
- Prior art keywords
- acrolein
- glycerin
- glycerol
- preparation
- catalytic dehydration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 title 5
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 title 2
- 235000011187 glycerol Nutrition 0.000 title 2
- 230000003197 catalytic effect Effects 0.000 title 1
- 230000018044 dehydration Effects 0.000 title 1
- 238000006297 dehydration reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
- C07C319/18—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by addition of thiols to unsaturated compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/28—Regeneration or reactivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
- B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
- B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
- B01J29/0341—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/90—Regeneration or reactivation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
- C07C319/20—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by reactions not involving the formation of sulfide groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/22—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and doubly-bound oxygen atoms bound to the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
- C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C47/22—Acryaldehyde; Methacryaldehyde
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/34—Reaction with organic or organometallic compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0959276A FR2954312B1 (fr) | 2009-12-21 | 2009-12-21 | Procede de preparation d'acroleine par deshydratation catalytique de glycerol ou glycerine |
JP2012545389A JP2013515044A (ja) | 2009-12-21 | 2010-12-21 | グリセロールまたはグリセリンからアクロレインを調製する方法 |
KR1020127019053A KR20120097540A (ko) | 2009-12-21 | 2010-12-21 | 글리세롤 또는 글리세린으로부터 아크롤레인을 제조하는 방법 |
CN2010800588812A CN102695694A (zh) | 2009-12-21 | 2010-12-21 | 由甘油或丙三醇制备丙烯醛的方法 |
TW099145403A TW201130791A (en) | 2009-12-21 | 2010-12-21 | Method for preparing acrolein from glycerol or glycerin |
PCT/FR2010/052855 WO2011083254A1 (fr) | 2009-12-21 | 2010-12-21 | Procede de preparation d'acroleine a partir de glycerol ou de glycerine |
US13/516,113 US8604234B2 (en) | 2009-12-21 | 2010-12-21 | Method for preparing acrolein from glycerol by catalytic dehydration of glycerol using a heteropolyacid catalyst |
EP10808909A EP2516375A1 (fr) | 2009-12-21 | 2010-12-21 | Procede de preparation d'acroleine a partir de glycerol ou de glycerine |
BR112012014883-4A BR112012014883A2 (pt) | 2009-12-21 | 2010-12-21 | metodo para preparar acroleina a partir de glicerol ou glicerina |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0959276A FR2954312B1 (fr) | 2009-12-21 | 2009-12-21 | Procede de preparation d'acroleine par deshydratation catalytique de glycerol ou glycerine |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2954312A1 FR2954312A1 (fr) | 2011-06-24 |
FR2954312B1 true FR2954312B1 (fr) | 2012-02-10 |
Family
ID=42340662
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR0959276A Expired - Fee Related FR2954312B1 (fr) | 2009-12-21 | 2009-12-21 | Procede de preparation d'acroleine par deshydratation catalytique de glycerol ou glycerine |
Country Status (9)
Country | Link |
---|---|
US (1) | US8604234B2 (fr) |
EP (1) | EP2516375A1 (fr) |
JP (1) | JP2013515044A (fr) |
KR (1) | KR20120097540A (fr) |
CN (1) | CN102695694A (fr) |
BR (1) | BR112012014883A2 (fr) |
FR (1) | FR2954312B1 (fr) |
TW (1) | TW201130791A (fr) |
WO (1) | WO2011083254A1 (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2939791B1 (fr) | 2008-12-16 | 2011-01-14 | Adisseo France Sas | Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute |
FR2961507B1 (fr) * | 2010-06-17 | 2016-03-04 | Adisseo France Sas | Procede de preparation d'acroleine a partir de glycerol ou de glycerine |
US9796648B2 (en) | 2014-05-02 | 2017-10-24 | University Of Tennessee Research Foundation | Glycerol dehydration methods and products thereof |
CN106008188B (zh) * | 2016-05-30 | 2018-05-29 | 浙江工业大学 | 一种甘油催化脱水制备丙烯醛的新方法 |
CN115197769A (zh) * | 2022-08-23 | 2022-10-18 | 广州诺拜因化工有限公司 | 一种耐高温不结焦人造板连续压机聚酯型高温链条油 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2882052B1 (fr) * | 2005-02-15 | 2007-03-23 | Arkema Sa | Procede de deshydratation du glycerol en acroleine |
WO2007058221A1 (fr) | 2005-11-15 | 2007-05-24 | Nippon Shokubai Co., Ltd. | Procede de deshydratation des polyols |
WO2008006977A1 (fr) * | 2006-07-11 | 2008-01-17 | Adisseo France S.A.S. | Procédé de préparation du 2-hydroxy-4-(méthylthio)butyronitrile et de la méthionine |
EP2103591A4 (fr) * | 2006-12-01 | 2013-10-16 | Nippon Catalytic Chem Ind | Procédé de production d'un acide acrylique |
DE102007004351A1 (de) * | 2007-01-29 | 2008-07-31 | Evonik Degussa Gmbh | Neue Katalysatoren und Verfahren zur Dehydratisierung von Glycerin |
DE102007004350A1 (de) * | 2007-01-29 | 2008-07-31 | Evonik Degussa Gmbh | Verfahren zur Regenerierung eines Katalysators |
JP2008266165A (ja) * | 2007-04-17 | 2008-11-06 | Nippon Shokubai Co Ltd | アクロレインの製造方法 |
FR2920767B1 (fr) * | 2007-09-06 | 2009-12-18 | Arkema France | Procede de vaporisation reactive de glycerol |
WO2009127889A1 (fr) | 2008-04-16 | 2009-10-22 | Arkema France | Procédé de fabrication d'acroléine à partir de glycérol |
-
2009
- 2009-12-21 FR FR0959276A patent/FR2954312B1/fr not_active Expired - Fee Related
-
2010
- 2010-12-21 WO PCT/FR2010/052855 patent/WO2011083254A1/fr active Application Filing
- 2010-12-21 BR BR112012014883-4A patent/BR112012014883A2/pt not_active IP Right Cessation
- 2010-12-21 US US13/516,113 patent/US8604234B2/en not_active Expired - Fee Related
- 2010-12-21 KR KR1020127019053A patent/KR20120097540A/ko not_active Application Discontinuation
- 2010-12-21 TW TW099145403A patent/TW201130791A/zh unknown
- 2010-12-21 EP EP10808909A patent/EP2516375A1/fr not_active Withdrawn
- 2010-12-21 JP JP2012545389A patent/JP2013515044A/ja active Pending
- 2010-12-21 CN CN2010800588812A patent/CN102695694A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
EP2516375A1 (fr) | 2012-10-31 |
US20120330049A1 (en) | 2012-12-27 |
US8604234B2 (en) | 2013-12-10 |
CN102695694A (zh) | 2012-09-26 |
TW201130791A (en) | 2011-09-16 |
BR112012014883A2 (pt) | 2018-03-27 |
WO2011083254A1 (fr) | 2011-07-14 |
KR20120097540A (ko) | 2012-09-04 |
JP2013515044A (ja) | 2013-05-02 |
FR2954312A1 (fr) | 2011-06-24 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |
Effective date: 20150831 |