FR2414034A1 - Procede de dealkylation, a la vapeur d'eau, d'hydrocarbures aromatiques - Google Patents

Procede de dealkylation, a la vapeur d'eau, d'hydrocarbures aromatiques

Info

Publication number
FR2414034A1
FR2414034A1 FR7800335A FR7800335A FR2414034A1 FR 2414034 A1 FR2414034 A1 FR 2414034A1 FR 7800335 A FR7800335 A FR 7800335A FR 7800335 A FR7800335 A FR 7800335A FR 2414034 A1 FR2414034 A1 FR 2414034A1
Authority
FR
France
Prior art keywords
water vapor
aromatic hydrocarbons
dealkylation
dealkylation process
addition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7800335A
Other languages
English (en)
Other versions
FR2414034B1 (fr
Inventor
Philippe Courty
Germain Martino
Jean-Francois Le Page
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7800335A priority Critical patent/FR2414034A1/fr
Priority to JP16598078A priority patent/JPS5531061A/ja
Priority to BE1009221A priority patent/BE873180A/fr
Priority to DE19782856863 priority patent/DE2856863A1/de
Priority to NL7900049A priority patent/NL7900049A/xx
Priority to IT19092/79A priority patent/IT1109943B/it
Priority to GB79423A priority patent/GB2011945B/en
Priority to SU792705002A priority patent/SU888813A3/ru
Priority to US06/001,653 priority patent/US4207169A/en
Publication of FR2414034A1 publication Critical patent/FR2414034A1/fr
Application granted granted Critical
Publication of FR2414034B1 publication Critical patent/FR2414034B1/fr
Granted legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G59/00—Treatment of naphtha by two or more reforming processes only or by at least one reforming process and at least one process which does not substantially change the boiling range of the naphtha
    • C10G59/02—Treatment of naphtha by two or more reforming processes only or by at least one reforming process and at least one process which does not substantially change the boiling range of the naphtha plural serial stages only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
    • C07C4/12—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
    • C07C4/14—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene splitting taking place at an aromatic-aliphatic bond
    • C07C4/20—Hydrogen being formed in situ, e.g. from steam
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    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
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    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
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    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of actinides
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
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    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
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    • C07C2523/22—Vanadium
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    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
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    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
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    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
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    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
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    • C07C2523/44—Palladium
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    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
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    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

L'INVENTION CONCERNE UN PROCEDE DE DEALKYLATION D'HYDROCARBURES AROMATIQUES, EN PRESENCE DE VAPEUR D'EAU ET D'UN CATALYSEUR. L'INVENTION EST CARACTERISEE EN CE QUE LES CATALYSEURS RENFERMENT, OUTRE AU MOINS UN METAL CHOISI PARMI LES METAUX NOBLES DE LA FAMILLE DU PLATINE, OUTRE D'EVENTUELS METAUX ALCALINS OU METAUX ADDITIONNELS DIVERS, DE L'OXYDE DE TITANE. L'INVENTION S'APPLIQUE NOTAMMENT A LA DEALKYLATION A LA VAPEUR D'EAU D'UN EFFLUENT D'UN REFORMING CATALYTIQUE.
FR7800335A 1978-01-06 1978-01-06 Procede de dealkylation, a la vapeur d'eau, d'hydrocarbures aromatiques Granted FR2414034A1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR7800335A FR2414034A1 (fr) 1978-01-06 1978-01-06 Procede de dealkylation, a la vapeur d'eau, d'hydrocarbures aromatiques
JP16598078A JPS5531061A (en) 1978-01-06 1978-12-29 Dealkylation of aromatic hydrocarbon by steam
BE1009221A BE873180A (fr) 1978-01-06 1978-12-29 Procede de dealkylation a la vapeur d'eau
DE19782856863 DE2856863A1 (de) 1978-01-06 1978-12-30 Verfahren zur entalkylierung von aromatischen kohlenwasserstoffen mit wasserdampf
NL7900049A NL7900049A (nl) 1978-01-06 1979-01-04 Werkwijze voor het met stroom dealkyleren van aroma- tische koolwaterstoffen.
IT19092/79A IT1109943B (it) 1978-01-06 1979-01-05 Procedimento di dealchilazione,al vapor d'acqua,di idrocarburi aromatici
GB79423A GB2011945B (en) 1978-01-06 1979-01-05 Process for the steam dealkylation of aromatic hydrocarbons
SU792705002A SU888813A3 (ru) 1978-01-06 1979-01-05 Способ получени бензола
US06/001,653 US4207169A (en) 1978-01-06 1979-01-08 Process for the steam dealkylation of aromatic hydrocarbons

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7800335A FR2414034A1 (fr) 1978-01-06 1978-01-06 Procede de dealkylation, a la vapeur d'eau, d'hydrocarbures aromatiques

Publications (2)

Publication Number Publication Date
FR2414034A1 true FR2414034A1 (fr) 1979-08-03
FR2414034B1 FR2414034B1 (fr) 1981-07-10

Family

ID=9203188

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7800335A Granted FR2414034A1 (fr) 1978-01-06 1978-01-06 Procede de dealkylation, a la vapeur d'eau, d'hydrocarbures aromatiques

Country Status (9)

Country Link
US (1) US4207169A (fr)
JP (1) JPS5531061A (fr)
BE (1) BE873180A (fr)
DE (1) DE2856863A1 (fr)
FR (1) FR2414034A1 (fr)
GB (1) GB2011945B (fr)
IT (1) IT1109943B (fr)
NL (1) NL7900049A (fr)
SU (1) SU888813A3 (fr)

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FR2434131A1 (fr) * 1978-02-24 1980-03-21 Inst Francais Du Petrole Procede de desalkylation a la vapeur d'eau d'hydrocarbures aromatiques
US4977129A (en) * 1989-03-13 1990-12-11 W. R Grace & Co.-Conn. Auto exhaust catalyst composition having low H2 S emissions and method of making the catalyst
US5102853A (en) * 1989-11-22 1992-04-07 Ford Motor Company Three-way catalyst for automotive emission control
US5492880A (en) * 1991-06-24 1996-02-20 University Of Pittsburgh Of The Commonwealth System Of Higher Education Process for the inorganic chemical modification of rhodium alumina catalysts and automotive catalyst made by the process
US5714660A (en) * 1996-08-29 1998-02-03 Phillips Petroleum Company Catalyst composition and processes therefor and therewith
US5714659A (en) * 1996-08-29 1998-02-03 Phillips Petroleum Company Catalyst composition and processes therefor and therewith
CA2352171C (fr) * 1998-11-26 2009-12-15 Idemitsu Kosan Co., Ltd. Catalyseur d'oxydation de monoxyde de carbone, procede de preparation d'un catalyseur d'oxydation de monoxyde de carbone, et procede de production d'un gaz contenant de l'hydrogene
JP2001232195A (ja) * 1999-12-17 2001-08-28 Ngk Insulators Ltd 触媒体
SE517251C2 (sv) * 2000-08-30 2002-05-14 Gustav Berggren Komponent för reglering av avgasåterflöde
AU2001284443A1 (en) * 2000-09-08 2002-03-22 Ngk Insulators, Ltd. Method for producing catalyst body and carrier having alumina carried thereon
US6589908B1 (en) * 2000-11-28 2003-07-08 Shell Oil Company Method of making alumina having bimodal pore structure, and catalysts made therefrom
KR100632591B1 (ko) * 2000-12-16 2006-10-09 에스케이 주식회사 다이옥신 제거용 촉매 조성물 및 이의 제조 방법
US6756340B2 (en) * 2002-04-08 2004-06-29 Uop Llc Dehydrogenation catalyst composition
US6713032B2 (en) * 2002-04-12 2004-03-30 Matsushita Electric Works, Ltd. Catalyst for removing carbon monoxide in hydrogen rich gas and production method therefor
US7569508B2 (en) * 2004-11-17 2009-08-04 Headwaters Technology Innovation, Llc Reforming nanocatalysts and method of making and using such catalysts
US7199273B2 (en) * 2003-11-24 2007-04-03 Exxonmobil Chemical Patents, Inc. Selective hydrogenation of alkynes and/or diolefins
US20050113614A1 (en) * 2003-11-24 2005-05-26 Lowe David M. Catalyst and process for selective hydrogenation
US7220701B2 (en) * 2003-11-24 2007-05-22 Exxonmobil Chemical Patents Inc. Catalyst and process for selective hydrogenation
US7220700B2 (en) * 2003-11-24 2007-05-22 Exxonmobil Chemical Patents Inc. Catalyst and process for selective hydrogenation
DE102005053230A1 (de) * 2005-11-06 2007-05-10 Basf Ag Verfahren zur Aromatisierung von Nichtaromaten und anschließende Dealkylierung von Alkyl-substituierten aromatischen Kohlenwasserstoffen mit Wasserdampf
TW200800387A (en) * 2006-06-01 2008-01-01 Ritek Corp Catalyst for catalyzing carbon nanotubes growth
JP5314910B2 (ja) * 2008-03-26 2013-10-16 株式会社東芝 メタノール酸化触媒およびその製造方法

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US3436433A (en) * 1967-04-21 1969-04-01 Universal Oil Prod Co Dealkylation of alkyl substituted aromatic hydrocarbons
US3595932A (en) * 1968-08-20 1971-07-27 Gdal Nossonovich Maslyansky Method of producing benzene and its low-molecular weight homologs
US3649707A (en) * 1969-06-27 1972-03-14 Universal Oil Prod Co Dual catalyst in steam dealkylation process
US3649706A (en) * 1969-06-27 1972-03-14 Universal Oil Prod Co Steam dealkylation process
GB1355344A (en) * 1970-08-06 1974-06-05 Ici Ltd Dealkylation of aromatic hydrocarbons
US4013734A (en) * 1973-12-14 1977-03-22 Exxon Research And Engineering Company Novel catalyst and its use for steam hydroconversion and dealkylation processes
US3992468A (en) * 1974-03-01 1976-11-16 Institut Francais Du Petrole, Des Carburants Et Lubrifiants Et Entreprise De Recherches Et D'activities Petrolieres Elf Process for the catalytic hydrodealkylation of alkylaromatic hydrocarbons
JPS5139588A (en) * 1974-10-01 1976-04-02 Mitsubishi Oil Co Suijokino sonzaika niokeru arukiruhokozokutankasuisono datsuarukirukayoshokubai
FR2317962A1 (fr) * 1975-07-15 1977-02-11 Raffinage Cie Francaise Nouveaux catalyseurs pour la dealkylation des hydrocarbures alkylaromatiques en presence de vapeur d'eau
FR2355791A1 (fr) * 1976-06-22 1978-01-20 Rhone Poulenc Ind Procede d'hydrodealkylation d'hydrocarbures alkyl aromatiques en presence d'un catalyseur plurimetallique

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BE873180A (fr) 1979-06-29
NL7900049A (nl) 1979-07-10
GB2011945B (en) 1982-03-24
DE2856863A1 (de) 1979-07-12
JPS5531061A (en) 1980-03-05
IT1109943B (it) 1985-12-23
US4207169A (en) 1980-06-10
FR2414034B1 (fr) 1981-07-10
SU888813A3 (ru) 1981-12-07
IT7919092A0 (it) 1979-01-05
GB2011945A (en) 1979-07-18

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