FR2398120A2 - Production de carbonates de metaux alcalins dans une cellule electrolytique a membrane - Google Patents
Production de carbonates de metaux alcalins dans une cellule electrolytique a membraneInfo
- Publication number
- FR2398120A2 FR2398120A2 FR7821269A FR7821269A FR2398120A2 FR 2398120 A2 FR2398120 A2 FR 2398120A2 FR 7821269 A FR7821269 A FR 7821269A FR 7821269 A FR7821269 A FR 7821269A FR 2398120 A2 FR2398120 A2 FR 2398120A2
- Authority
- FR
- France
- Prior art keywords
- alkali metal
- production
- carbonates
- electrolytic
- alkaline metals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
- C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/14—Alkali metal compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Le secteur technique de l'invention est celui de la production électrolytique de carbonates de métaux alcalins. L'invention se rapporte à l'obtention d'un carbonate de métal alcalin par électrolyse d'un chlorure de métal alcalin dans une cellule électrolytique à séparateur formé d'une pelliclule de polymère fluoré ayant des groupes carboxyliques ou carboxylates de métal alcalin, avec introduction d'anhydride carbonique dans le catholyte, en transformant l'hydroxyde de métal alcalin en un carbonate de métal alcalin, et utilisation d'une intensité de courant d'électrolyse qui réduit la concentration de chlorure de métal alcalin, dans les solides du catholyte, à moins de 400 ppm. Application à la production de carbonate de métaux alcalins de grande pureté.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/817,007 US4147599A (en) | 1977-07-19 | 1977-07-19 | Production of alkali metal carbonates in a cell having a carboxyl membrane |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2398120A2 true FR2398120A2 (fr) | 1979-02-16 |
FR2398120B2 FR2398120B2 (fr) | 1985-10-18 |
Family
ID=25222156
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7821269A Expired FR2398120B2 (fr) | 1977-07-19 | 1978-07-18 | Production de carbonates de metaux alcalins dans une cellule electrolytique a membrane |
Country Status (20)
Country | Link |
---|---|
US (1) | US4147599A (fr) |
JP (1) | JPS5421997A (fr) |
AT (1) | AT357571B (fr) |
AU (1) | AU524401B2 (fr) |
BE (1) | BE869064R (fr) |
BR (1) | BR7804634A (fr) |
CA (1) | CA1123780A (fr) |
DD (1) | DD140261A6 (fr) |
DE (1) | DE2831331A1 (fr) |
ES (1) | ES471711A2 (fr) |
FI (1) | FI782273A (fr) |
FR (1) | FR2398120B2 (fr) |
GB (1) | GB1580010A (fr) |
IN (1) | IN150311B (fr) |
IT (1) | IT1156869B (fr) |
MX (1) | MX149917A (fr) |
NL (1) | NL7807684A (fr) |
PL (1) | PL110147B1 (fr) |
SE (1) | SE7807916L (fr) |
ZA (1) | ZA784070B (fr) |
Families Citing this family (62)
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---|---|---|---|---|
JPS53144481A (en) * | 1977-05-24 | 1978-12-15 | Asahi Glass Co Ltd | Method of joining fluorine contained cation exchange resin membrane |
FR2441667A1 (fr) * | 1978-11-14 | 1980-06-13 | Ugine Kuhlmann | Procede de preparation electrolytique des chlorates alcalins |
US4278526A (en) * | 1978-12-28 | 1981-07-14 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Apparatus for electrolysis of an aqueous alkali metal chloride solution |
JPS5672190A (en) * | 1979-11-20 | 1981-06-16 | Toyo Soda Mfg Co Ltd | Cation exchange membrane for electrolysis of alkali metal halogenide |
JPS5742564A (en) * | 1980-08-26 | 1982-03-10 | Asahi Glass Co Ltd | Treatment of resin-containing formed body |
CA1214433A (fr) * | 1980-11-05 | 1986-11-25 | Toyo Soda Manufacturing Co., Ltd. | Fabrication d'une membrane echangeuse de cations |
JPS5792028A (en) * | 1980-11-29 | 1982-06-08 | Asahi Chem Ind Co Ltd | Fluorocarbon cation exchange membrane |
US4465568A (en) * | 1981-11-16 | 1984-08-14 | Olin Corporation | Electrochemical production of KNO3 /NaNO3 salt mixture |
JPS6068994U (ja) * | 1983-10-19 | 1985-05-16 | 石橋ハマプラス株式会社 | 葉たばこ選別台 |
RU2420345C2 (ru) * | 2004-09-23 | 2011-06-10 | Джо Дэвид Джоунс | Удаление диоксида углерода из потоков отходов путем совместного получения карбонатных и/или бикарбонатных минералов |
US7727374B2 (en) * | 2004-09-23 | 2010-06-01 | Skyonic Corporation | Removing carbon dioxide from waste streams through co-generation of carbonate and/or bicarbonate minerals |
EP1900688A1 (fr) * | 2006-09-14 | 2008-03-19 | SOLVAY (Société Anonyme) | Procédé pour obtenir des cristaux de carbonate de sodium |
US7887694B2 (en) | 2007-12-28 | 2011-02-15 | Calera Corporation | Methods of sequestering CO2 |
US7753618B2 (en) * | 2007-06-28 | 2010-07-13 | Calera Corporation | Rocks and aggregate, and methods of making and using the same |
CN101743046A (zh) | 2007-06-28 | 2010-06-16 | 卡勒拉公司 | 包括碳酸盐化合物沉淀的脱盐方法和*** |
CA2930096A1 (fr) | 2007-09-20 | 2009-03-26 | Skyonic Corporation | Elimination du dioxyde de carbone de circuits de dechets par cogeneration de composes carbonatee et/ou bicarbonates |
US20100239467A1 (en) | 2008-06-17 | 2010-09-23 | Brent Constantz | Methods and systems for utilizing waste sources of metal oxides |
US7749476B2 (en) | 2007-12-28 | 2010-07-06 | Calera Corporation | Production of carbonate-containing compositions from material comprising metal silicates |
US7754169B2 (en) * | 2007-12-28 | 2010-07-13 | Calera Corporation | Methods and systems for utilizing waste sources of metal oxides |
CN101984749B (zh) | 2008-07-16 | 2015-02-18 | 卡勒拉公司 | 使用二氧化碳气体的低能量4-电池电化学*** |
JP5373079B2 (ja) | 2008-07-16 | 2013-12-18 | カレラ コーポレイション | 電気化学システム中でのco2の利用 |
US7993500B2 (en) | 2008-07-16 | 2011-08-09 | Calera Corporation | Gas diffusion anode and CO2 cathode electrolyte system |
US7966250B2 (en) * | 2008-09-11 | 2011-06-21 | Calera Corporation | CO2 commodity trading system and method |
TW201026597A (en) | 2008-09-30 | 2010-07-16 | Calera Corp | CO2-sequestering formed building materials |
US7815880B2 (en) | 2008-09-30 | 2010-10-19 | Calera Corporation | Reduced-carbon footprint concrete compositions |
US8869477B2 (en) | 2008-09-30 | 2014-10-28 | Calera Corporation | Formed building materials |
US7939336B2 (en) * | 2008-09-30 | 2011-05-10 | Calera Corporation | Compositions and methods using substances containing carbon |
CA2694980C (fr) * | 2008-10-31 | 2011-09-20 | Calera Corporation | Compositions non cimentaires comprenant des additifs sequestrants du co2 |
US9133581B2 (en) | 2008-10-31 | 2015-09-15 | Calera Corporation | Non-cementitious compositions comprising vaterite and methods thereof |
EP2384520A1 (fr) * | 2008-12-23 | 2011-11-09 | Calera Corporation | Système et procédé de transfert de protons électrochimique à faible énergie |
US7790012B2 (en) * | 2008-12-23 | 2010-09-07 | Calera Corporation | Low energy electrochemical hydroxide system and method |
US20110091366A1 (en) * | 2008-12-24 | 2011-04-21 | Treavor Kendall | Neutralization of acid and production of carbonate-containing compositions |
CN102317244A (zh) | 2009-01-29 | 2012-01-11 | 普林斯顿大学 | 二氧化碳转化至有机产物 |
US20100200419A1 (en) * | 2009-02-10 | 2010-08-12 | Gilliam Ryan J | Low-voltage alkaline production from brines |
EP2245215A4 (fr) | 2009-02-10 | 2011-04-27 | Calera Corp | Production à basse tension d'agents alcalins au moyen d'hydrogène et d'électrodes électrocatalytiques |
US8883104B2 (en) | 2009-03-02 | 2014-11-11 | Calera Corporation | Gas stream multi-pollutants control systems and methods |
US8137444B2 (en) | 2009-03-10 | 2012-03-20 | Calera Corporation | Systems and methods for processing CO2 |
US7993511B2 (en) * | 2009-07-15 | 2011-08-09 | Calera Corporation | Electrochemical production of an alkaline solution using CO2 |
CN102762277A (zh) | 2009-12-18 | 2012-10-31 | 斯凯约尼克公司 | 通过形成ii族碳酸盐和二氧化硅的二氧化碳固定 |
US20110114502A1 (en) * | 2009-12-21 | 2011-05-19 | Emily Barton Cole | Reducing carbon dioxide to products |
US8721866B2 (en) | 2010-03-19 | 2014-05-13 | Liquid Light, Inc. | Electrochemical production of synthesis gas from carbon dioxide |
US8500987B2 (en) | 2010-03-19 | 2013-08-06 | Liquid Light, Inc. | Purification of carbon dioxide from a mixture of gases |
US8845877B2 (en) | 2010-03-19 | 2014-09-30 | Liquid Light, Inc. | Heterocycle catalyzed electrochemical process |
JP5730385B2 (ja) * | 2010-04-23 | 2015-06-10 | シンボル インコーポレイテッド | 塩化リチウムから炭酸リチウムを製造する方法 |
MY161228A (en) | 2010-07-08 | 2017-04-14 | Skyonic Corp | Carbon dioxide sequestration involving two-salt-based thermolytic processes |
US8845878B2 (en) | 2010-07-29 | 2014-09-30 | Liquid Light, Inc. | Reducing carbon dioxide to products |
US8961774B2 (en) | 2010-11-30 | 2015-02-24 | Liquid Light, Inc. | Electrochemical production of butanol from carbon dioxide and water |
US8568581B2 (en) | 2010-11-30 | 2013-10-29 | Liquid Light, Inc. | Heterocycle catalyzed carbonylation and hydroformylation with carbon dioxide |
US9090976B2 (en) | 2010-12-30 | 2015-07-28 | The Trustees Of Princeton University | Advanced aromatic amine heterocyclic catalysts for carbon dioxide reduction |
AU2012384397B2 (en) * | 2012-07-06 | 2016-08-18 | Hitachi, Ltd. | Method and device for treating saline wastewater |
JP2014014743A (ja) * | 2012-07-06 | 2014-01-30 | Hitachi Ltd | 塩排水の処理方法及びその処理装置 |
US9175407B2 (en) | 2012-07-26 | 2015-11-03 | Liquid Light, Inc. | Integrated process for producing carboxylic acids from carbon dioxide |
US8845876B2 (en) | 2012-07-26 | 2014-09-30 | Liquid Light, Inc. | Electrochemical co-production of products with carbon-based reactant feed to anode |
US8858777B2 (en) | 2012-07-26 | 2014-10-14 | Liquid Light, Inc. | Process and high surface area electrodes for the electrochemical reduction of carbon dioxide |
US8641885B2 (en) | 2012-07-26 | 2014-02-04 | Liquid Light, Inc. | Multiphase electrochemical reduction of CO2 |
US10329676B2 (en) | 2012-07-26 | 2019-06-25 | Avantium Knowledge Centre B.V. | Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode |
US9267212B2 (en) | 2012-07-26 | 2016-02-23 | Liquid Light, Inc. | Method and system for production of oxalic acid and oxalic acid reduction products |
US9873951B2 (en) | 2012-09-14 | 2018-01-23 | Avantium Knowledge Centre B.V. | High pressure electrochemical cell and process for the electrochemical reduction of carbon dioxide |
AU2013318506A1 (en) * | 2012-09-19 | 2015-03-26 | Liquid Light, Inc. | Electrochemical co-production of chemicals utilizing a halide salt |
CN106061583A (zh) | 2014-01-17 | 2016-10-26 | 斯凯约尼克公司 | 从气体流去除酸性气体 |
EP3261991B9 (fr) | 2015-02-23 | 2023-11-15 | Carbonfree Chemicals Holdings, LLC | Séquestration de dioxyde de carbone par de l'hydroxyde de magnésium et régénération d'hydroxyde de magnésium |
WO2023074426A1 (fr) * | 2021-10-26 | 2023-05-04 | 株式会社カネカ | Dispositif d'électrolyse |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1941847A1 (de) * | 1968-12-31 | 1970-07-23 | Bitterfeld Chemie | Verfahren zur Elektrolyse von Salzloesungen in Zellen mit Diaphragma |
JPS5177452A (ja) * | 1974-12-26 | 1976-07-05 | Toshiba Machine Co Ltd | Sakushonbureedoosonaetadaatsushiima |
FR2333824A1 (fr) * | 1975-08-29 | 1977-07-01 | Asahi Glass Co Ltd | Membrane fluoree echangeuse de cations et son application pour l'electrolyse d'un halogenure de metal alcalin |
US4065366A (en) * | 1975-10-17 | 1977-12-27 | Asahi Glass Co., Ltd. | Process for producing alkali metal hydroxide |
FR2359220A2 (fr) * | 1976-07-21 | 1978-02-17 | Diamond Shamrock Corp | Production de carbonates de metaux alcalins dans une cellule electrolytique a membrane |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2967807A (en) * | 1952-01-23 | 1961-01-10 | Hooker Chemical Corp | Electrolytic decomposition of sodium chloride |
DE1233366B (de) * | 1963-06-28 | 1967-02-02 | Ceskoslovenska Akademie Ved | Elektrolyseur fuer die gleichzeitige Herstellung von Chlor und Alkalicarbonaten |
US3976549A (en) * | 1973-02-26 | 1976-08-24 | Hooker Chemicals & Plastics Corporation | Electrolysis method |
US3899403A (en) * | 1973-11-01 | 1975-08-12 | Hooker Chemicals Plastics Corp | Electrolytic method of making concentrated hydroxide solutions by sequential use of 3-compartment and 2-compartment electrolytic cells having separating compartment walls of particular cation-active permselective membranes |
-
1977
- 1977-07-19 US US05/817,007 patent/US4147599A/en not_active Expired - Lifetime
-
1978
- 1978-05-31 GB GB25759/78A patent/GB1580010A/en not_active Expired
- 1978-07-13 ES ES471711A patent/ES471711A2/es not_active Expired
- 1978-07-15 PL PL1978208432A patent/PL110147B1/pl unknown
- 1978-07-17 AU AU38095/78A patent/AU524401B2/en not_active Expired
- 1978-07-17 IN IN787/CAL/78A patent/IN150311B/en unknown
- 1978-07-17 DE DE19782831331 patent/DE2831331A1/de active Pending
- 1978-07-17 AT AT515778A patent/AT357571B/de not_active IP Right Cessation
- 1978-07-18 BE BE189330A patent/BE869064R/fr not_active IP Right Cessation
- 1978-07-18 ZA ZA00784070A patent/ZA784070B/xx unknown
- 1978-07-18 CA CA307,627A patent/CA1123780A/fr not_active Expired
- 1978-07-18 IT IT50351/78A patent/IT1156869B/it active
- 1978-07-18 FI FI782273A patent/FI782273A/fi not_active Application Discontinuation
- 1978-07-18 FR FR7821269A patent/FR2398120B2/fr not_active Expired
- 1978-07-18 DD DD78206785A patent/DD140261A6/de unknown
- 1978-07-18 MX MX174220A patent/MX149917A/es unknown
- 1978-07-18 JP JP8764278A patent/JPS5421997A/ja active Granted
- 1978-07-18 SE SE787807916A patent/SE7807916L/xx unknown
- 1978-07-18 NL NL7807684A patent/NL7807684A/xx not_active Application Discontinuation
- 1978-07-18 BR BR7804634A patent/BR7804634A/pt unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1941847A1 (de) * | 1968-12-31 | 1970-07-23 | Bitterfeld Chemie | Verfahren zur Elektrolyse von Salzloesungen in Zellen mit Diaphragma |
JPS5177452A (ja) * | 1974-12-26 | 1976-07-05 | Toshiba Machine Co Ltd | Sakushonbureedoosonaetadaatsushiima |
FR2333824A1 (fr) * | 1975-08-29 | 1977-07-01 | Asahi Glass Co Ltd | Membrane fluoree echangeuse de cations et son application pour l'electrolyse d'un halogenure de metal alcalin |
US4065366A (en) * | 1975-10-17 | 1977-12-27 | Asahi Glass Co., Ltd. | Process for producing alkali metal hydroxide |
US4065366B1 (fr) * | 1975-10-17 | 1984-05-22 | ||
FR2359220A2 (fr) * | 1976-07-21 | 1978-02-17 | Diamond Shamrock Corp | Production de carbonates de metaux alcalins dans une cellule electrolytique a membrane |
Also Published As
Publication number | Publication date |
---|---|
CA1123780A (fr) | 1982-05-18 |
ZA784070B (en) | 1979-09-26 |
DE2831331A1 (de) | 1979-02-08 |
IN150311B (fr) | 1982-09-11 |
IT7850351A0 (it) | 1978-07-18 |
AU3809578A (en) | 1980-01-17 |
ES471711A2 (es) | 1979-10-16 |
ATA515778A (de) | 1979-12-15 |
FR2398120B2 (fr) | 1985-10-18 |
DD140261A6 (de) | 1980-02-20 |
AU524401B2 (en) | 1982-09-16 |
BE869064R (fr) | 1979-01-18 |
PL208432A1 (pl) | 1979-03-12 |
AT357571B (de) | 1980-07-25 |
SE7807916L (sv) | 1979-01-20 |
MX149917A (es) | 1984-02-09 |
US4147599A (en) | 1979-04-03 |
BR7804634A (pt) | 1979-03-20 |
GB1580010A (en) | 1980-11-26 |
FI782273A (fi) | 1979-01-20 |
NL7807684A (nl) | 1979-01-23 |
JPS5421997A (en) | 1979-02-19 |
PL110147B1 (en) | 1980-07-31 |
JPS6131190B2 (fr) | 1986-07-18 |
IT1156869B (it) | 1987-02-04 |
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