FR2370689A1 - Poudre de zeolite cristalline de type a - Google Patents

Poudre de zeolite cristalline de type a

Info

Publication number
FR2370689A1
FR2370689A1 FR7728472A FR7728472A FR2370689A1 FR 2370689 A1 FR2370689 A1 FR 2370689A1 FR 7728472 A FR7728472 A FR 7728472A FR 7728472 A FR7728472 A FR 7728472A FR 2370689 A1 FR2370689 A1 FR 2370689A1
Authority
FR
France
Prior art keywords
zeolite powder
solution
type
crystalline zeolite
sodium aluminate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7728472A
Other languages
English (en)
Other versions
FR2370689B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Deutsche Gold und Silber Scheideanstalt
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa GmbH, Deutsche Gold und Silber Scheideanstalt filed Critical Degussa GmbH
Publication of FR2370689A1 publication Critical patent/FR2370689A1/fr
Application granted granted Critical
Publication of FR2370689B1 publication Critical patent/FR2370689B1/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • C11D3/128Aluminium silicates, e.g. zeolites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/20Silicates
    • C01B33/26Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28Base exchange silicates, e.g. zeolites
    • C01B33/2807Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
    • C01B33/2815Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of type A (UNION CARBIDE trade name; corresponds to GRACE's types Z-12 or Z-12L)
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00Chemistry of inorganic compounds
    • Y10S423/24LTA, e.g. A, alpha, ZK-4, ZK-21, ZK-22

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Detergent Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

a. L'invention concerne une poudre de zéolite de type A, cristalline. b. Cette poudre de zéolite est constituée de 50 % de particules inférieures à 4,9 mu m et le procédé est caractérisé en ce qu'on mélange une solution de silicate alvalin et une lessive de soude caustique avec une solution d'aluminate de sodium, un des composés étant introduit en premier, en empêchant la formation d'un gel insoluble au moyen d'un rapport SiO 2 / Al2 O3 de 2 à 50, puis ajoute une nouvelle quantité de solution d'aluminate de sodium, puis laisse cristalliser. c. Cette poudre de zéolite convient comme substitut des phosphates dans les agents de lavage, lessivage et nettoyage.
FR7728472A 1976-11-11 1977-09-21 Poudre de zeolite cristalline de type a Granted FR2370689A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19762651419 DE2651419A1 (de) 1976-11-11 1976-11-11 Kristallines zeolithpulver des typs a iv

Publications (2)

Publication Number Publication Date
FR2370689A1 true FR2370689A1 (fr) 1978-06-09
FR2370689B1 FR2370689B1 (fr) 1980-06-06

Family

ID=5992883

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7728472A Granted FR2370689A1 (fr) 1976-11-11 1977-09-21 Poudre de zeolite cristalline de type a

Country Status (12)

Country Link
US (2) US4303628A (fr)
JP (3) JPS5361596A (fr)
BE (1) BE860757A (fr)
BR (1) BR7707167A (fr)
CA (1) CA1082163A (fr)
CH (1) CH631947A5 (fr)
DE (1) DE2651419A1 (fr)
ES (1) ES463996A1 (fr)
FR (1) FR2370689A1 (fr)
GB (1) GB1571536A (fr)
IT (1) IT1202414B (fr)
NL (1) NL7709210A (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2447349A1 (fr) * 1979-01-26 1980-08-22 Montedison Spa Procede de fabrication de zeolites 4a convenant particulierement a la formulation de compositions detergentes
EP0016393A2 (fr) * 1979-03-15 1980-10-01 Henkel Kommanditgesellschaft auf Aktien Procédé de préparation de silicates amorphes d'aluminium et de sodium
EP0356625A1 (fr) * 1988-08-12 1990-03-07 Degussa Aktiengesellschaft Zéolite Na A en poudre pour l'utilisation dans les produits détergents liquides
EP0357989A1 (fr) * 1988-08-12 1990-03-14 Degussa Aktiengesellschaft Zéolite Na A en poudre pour l'utilisation dans les produits détergents liquides
WO1994021558A1 (fr) * 1993-03-25 1994-09-29 Henkel Kommanditgesellschaft Auf Aktien Procede de preparation de silicates d'aluminium de metaux alcalins zeolithiques finement pulverises

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2651419A1 (de) * 1976-11-11 1978-05-18 Degussa Kristallines zeolithpulver des typs a iv
DE3007080A1 (de) * 1980-02-26 1981-09-10 Degussa Ag, 6000 Frankfurt Verfahren zur herstellung von kristallinem zeolithpulver des typs a
DE3007044A1 (de) * 1980-02-26 1981-09-10 Degussa Ag, 6000 Frankfurt Verfahren zur herstellung von kristallinem zeolith a
DE3007123A1 (de) * 1980-02-26 1981-09-10 Degussa Ag, 6000 Frankfurt Verfahren zur herstellung von zeolith a
DE3007087A1 (de) * 1980-02-26 1981-09-10 Degussa Ag, 6000 Frankfurt Verfahren zur herstellung von zeolith a
DE3132379A1 (de) * 1981-08-17 1983-02-24 Degussa Ag, 6000 Frankfurt Zeolithgranulat, verfahren zu seiner herstellung und verwendung
DE3132928C1 (de) 1981-08-20 1983-01-13 Degussa Ag, 6000 Frankfurt Verfahren zur Erstarrungsbeschleunigung von hydraulischen Zementmischungen
DE3208598A1 (de) * 1982-03-10 1983-09-22 Degussa Ag, 6000 Frankfurt Verfahren zur herstellung von mit organosilanen oberflaechenmodifizierten zeolithen
DE3444311A1 (de) * 1984-12-05 1986-06-05 Degussa Ag, 6000 Frankfurt Waessrige stabile suspension wasserunloeslicher, zum binden von calciumionen befaehigter silikate und deren verwendung zur herstellung von wasch- und reinigungsmitteln
DE3516660A1 (de) 1985-05-09 1986-11-13 Degussa Ag, 6000 Frankfurt Pulverfoermiges bindemittelkonzentrat
US5474753A (en) * 1990-11-09 1995-12-12 Laviosa Rhone-Poulenc Preparation of crystalline 4A zeolites
US7052541B2 (en) * 2002-06-19 2006-05-30 Board Of Regents, The University Of Texas System Color compositions
US7425235B2 (en) * 2005-02-11 2008-09-16 The Board Of Regents Of The University Of Texas System Color compositions and methods of manufacture
CN101243142A (zh) * 2005-06-17 2008-08-13 得克萨斯大学体系董事会 有机/无机路易斯酸复合材料

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2882243A (en) * 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
DE1038017B (de) 1953-12-24 1958-09-04 Union Carbide Corp Verfahren zur Herstellung kristalliner zeolithischer Molekularsiebe
US3058805A (en) * 1958-10-03 1962-10-16 Bayer Ag Process for the production of sodium zeolite a
US3310373A (en) 1963-04-03 1967-03-21 Mobil Oil Corp Method for producing crystalline aluminosilicates
DK151231C (da) * 1973-04-13 1988-07-04 Henkel Kgaa Fremgangsmaade til rensning, herunder vask, forvask og blegende vask, affaste materialer, isaer tekstiler, samt middel til udoevelse af fremgangsmaaden og fremgamgsmaade til fremstiling af midlet
AT330930B (de) * 1973-04-13 1976-07-26 Henkel & Cie Gmbh Verfahren zur herstellung von festen, schuttfahigen wasch- oder reinigungsmitteln mit einem gehalt an calcium bindenden substanzen
AR208392A1 (es) * 1973-05-07 1976-12-27 Henkel & Cie Gmbh Composicion para lavar blanquear o limpiar materiales resistentes especialmente textiles adicional a la patente no 201687 adicional a la no 253286
US4605509A (en) * 1973-05-11 1986-08-12 The Procter & Gamble Company Detergent compositions containing sodium aluminosilicate builders
CA1037815A (fr) * 1973-06-20 1978-09-05 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Fabrication d'agents solides de lavage ou de nettoyage versables, contenant une certaine quantite de silicate fixateur de calcium
DE2433485A1 (de) * 1973-07-16 1975-02-06 Procter & Gamble Zur verwendung in waschmitteln geeignete aluminosilikat-ionenaustauscher
US4274975A (en) * 1974-03-11 1981-06-23 The Procter & Gamble Company Detergent composition
US3985669A (en) * 1974-06-17 1976-10-12 The Procter & Gamble Company Detergent compositions
DE2447021C3 (de) 1974-10-02 1984-03-22 Degussa Ag, 6000 Frankfurt Kristallines Zeolithpulver des Typs A und das Verfahren zu seiner Herstellung
US4066394A (en) * 1974-12-30 1978-01-03 Colgate-Palmolive Reusable zeolite water softener for clothes washing
DE2514399A1 (de) * 1975-04-02 1976-10-14 Degussa Verfahren zur herstellung von aluminiumsilikaten
DE2517218B2 (de) * 1975-04-18 1977-05-05 Henkel & Cie GmbH, 4000 Düsseldorf; Deutsche Gold- und Silber-Scheideanstalt vormals Roessler, 6000 Frankfurt Kristallines zeolithpulver des typs a
US4041135A (en) * 1975-07-25 1977-08-09 J. M. Huber Corporation Production of high capacity inorganic crystalline base exchange materials
DE2651420A1 (de) * 1976-11-11 1978-05-18 Degussa Kristallines zeolithpulver des typs a v
DE2651436A1 (de) * 1976-11-11 1978-05-18 Degussa Kristallines zeolithpulver des typs a iii
DE2651419A1 (de) * 1976-11-11 1978-05-18 Degussa Kristallines zeolithpulver des typs a iv
DE2651485A1 (de) * 1976-11-11 1978-05-24 Degussa Kristallines zeolithpulver des typs a i
DE2651437A1 (de) * 1976-11-11 1978-05-18 Degussa Kristallines zeolithpulver des typs a vi

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2447349A1 (fr) * 1979-01-26 1980-08-22 Montedison Spa Procede de fabrication de zeolites 4a convenant particulierement a la formulation de compositions detergentes
EP0016393A2 (fr) * 1979-03-15 1980-10-01 Henkel Kommanditgesellschaft auf Aktien Procédé de préparation de silicates amorphes d'aluminium et de sodium
EP0016393A3 (en) * 1979-03-15 1981-04-15 Henkel Kommanditgesellschaft Auf Aktien Process for the preparation of amorphous sodium-aluminium silicates
EP0356625A1 (fr) * 1988-08-12 1990-03-07 Degussa Aktiengesellschaft Zéolite Na A en poudre pour l'utilisation dans les produits détergents liquides
EP0357989A1 (fr) * 1988-08-12 1990-03-14 Degussa Aktiengesellschaft Zéolite Na A en poudre pour l'utilisation dans les produits détergents liquides
WO1994021558A1 (fr) * 1993-03-25 1994-09-29 Henkel Kommanditgesellschaft Auf Aktien Procede de preparation de silicates d'aluminium de metaux alcalins zeolithiques finement pulverises
US5645811A (en) * 1993-03-25 1997-07-08 Henkel Kommanditgesellschaft Auf Aktien Process for the production of very fine-particle zeolitic alkali metal aluminum silicates

Also Published As

Publication number Publication date
JPS5723697A (en) 1982-02-06
BE860757A (fr) 1978-05-10
CH631947A5 (de) 1982-09-15
CA1082163A (fr) 1980-07-22
US4303628A (en) 1981-12-01
JPS6324928B2 (fr) 1988-05-23
GB1571536A (en) 1980-07-16
IT1202414B (it) 1989-02-09
US4551322A (en) 1985-11-05
ES463996A1 (es) 1978-07-16
DE2651419A1 (de) 1978-05-18
JPS5727918A (en) 1982-02-15
FR2370689B1 (fr) 1980-06-06
JPS5361596A (en) 1978-06-02
BR7707167A (pt) 1978-08-01
NL7709210A (nl) 1978-05-16

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Legal Events

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