FR2356677A1 - Procede de production sous pression elevee de polyethylene - Google Patents
Procede de production sous pression elevee de polyethyleneInfo
- Publication number
- FR2356677A1 FR2356677A1 FR7719762A FR7719762A FR2356677A1 FR 2356677 A1 FR2356677 A1 FR 2356677A1 FR 7719762 A FR7719762 A FR 7719762A FR 7719762 A FR7719762 A FR 7719762A FR 2356677 A1 FR2356677 A1 FR 2356677A1
- Authority
- FR
- France
- Prior art keywords
- reaction zone
- zone
- high pressure
- ethylene
- degrees
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
- B01J3/04—Pressure vessels, e.g. autoclaves
- B01J3/042—Pressure vessels, e.g. autoclaves in the form of a tube
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
L'invention concerne un procédé de production sous pression élevée de polyéthylène. Dans la zone de réaction supérieure 3 d'un réacteur autoclave 1, on polymérise de l'éthylène à une température de 130 degrés -200 degrés C et une pression de 1 000 à 1 800 kg/cm**2 en utilisant un agent d'amorçage, puis on poursuit la polymérisation à 220-280 degrés C en utilisant un agent d'amorçage dans la zone de réaction inférieure 4 du réacteur autoclave, avec les caractéristiques suivantes : 75 % ou plus de l'éthylène est introduit dans la zone de réaction supérieure par les conduites 7 et 8, et le rapport volumique de la zone de réaction supérieure à la zone de réaction inférieure est de 1,5 à 6, et le réacteur comprend au moins deux entrées d'alimentation pour l'éthylène 7, 8 et pour l'agent d'amorçage 9, 10 de façon à réguler la température de réaction dans cette zone supérieure (Figure '1). Obtention de polyéthylène basse densité ayant d'excellentes propriétés optiques et d'excellentes propriétés de mise en oeuvre.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7730076A JPS532585A (en) | 1976-06-29 | 1976-06-29 | Preparation of polyethylene |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2356677A1 true FR2356677A1 (fr) | 1978-01-27 |
FR2356677B1 FR2356677B1 (fr) | 1981-03-06 |
Family
ID=13630037
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7719762A Granted FR2356677A1 (fr) | 1976-06-29 | 1977-06-28 | Procede de production sous pression elevee de polyethylene |
Country Status (11)
Country | Link |
---|---|
US (1) | US4085266A (fr) |
JP (1) | JPS532585A (fr) |
BR (1) | BR7704172A (fr) |
CA (1) | CA1065544A (fr) |
DE (1) | DE2729103A1 (fr) |
FR (1) | FR2356677A1 (fr) |
GB (1) | GB1538633A (fr) |
HU (1) | HU179321B (fr) |
MX (1) | MX4569E (fr) |
NL (1) | NL7707167A (fr) |
SU (1) | SU1075978A3 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0017230A1 (fr) * | 1979-04-05 | 1980-10-15 | E.I. Du Pont De Nemours And Company | Procédé continu de préparation de coplymères ordonnés d'éthylène et d'un acide carboxylique alpha, béta-insaturé ainsi que les ionomères préparés à partir de ces copolymères. |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5322582A (en) * | 1976-08-13 | 1978-03-02 | Sumitomo Chem Co Ltd | Production of polyethylene |
US4282339A (en) * | 1978-10-02 | 1981-08-04 | National Distillers And Chemical Corp. | Dual reactor process and apparatus for polymerizing ethylene |
US4607086A (en) * | 1979-04-05 | 1986-08-19 | E. I. Du Pont De Nemours And Company | Continuous process for the manufacture of low-density polyethylene in stirred autoclaves |
JPS5819284U (ja) * | 1981-07-30 | 1983-02-05 | リコーエレメックス株式会社 | 時計のカレンダ−機構 |
US4979987A (en) * | 1988-07-19 | 1990-12-25 | First Miss Gold, Inc. | Precious metals recovery from refractory carbonate ores |
NO178790C (no) * | 1993-12-13 | 1996-06-05 | Borealis Holding As | Fremgangsmåte ved fremstilling av olefinpolymerer i en autoklavrektor |
US5648438A (en) * | 1994-04-01 | 1997-07-15 | Exxon Chemical Patents, Inc. | Process for producing polymers with multimodal molecular weight distributions |
US6407191B1 (en) | 1998-01-12 | 2002-06-18 | The Dow Chemical Company | Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process |
DE69826103T3 (de) | 1998-01-12 | 2012-07-12 | Dow Global Technologies Inc. | Äthylenpolymere mittlerer Dichte, Verfahren zur Herstellung dieser Polymere und Verwendung von Carbonyl-haltigen Kettenübertragungsmitteln in diesem Verfahren |
JP2005097483A (ja) * | 2003-09-26 | 2005-04-14 | Sumitomo Chemical Co Ltd | 高圧ラジカル重合法ポリエチレン |
US7604783B2 (en) * | 2004-12-22 | 2009-10-20 | Placer Dome Technical Services Limited | Reduction of lime consumption when treating refractor gold ores or concentrates |
US8061888B2 (en) * | 2006-03-17 | 2011-11-22 | Barrick Gold Corporation | Autoclave with underflow dividers |
US8252254B2 (en) * | 2006-06-15 | 2012-08-28 | Barrick Gold Corporation | Process for reduced alkali consumption in the recovery of silver |
BRPI0915561B1 (pt) * | 2008-07-10 | 2019-04-24 | Borealis Ag | Processo para a produção de um polímero e polímero para aplicações em cabos e arames |
KR101707696B1 (ko) * | 2009-03-31 | 2017-02-16 | 다우 글로벌 테크놀로지스 엘엘씨 | 불균질 에틸렌/알파-올레핀 혼성중합체로부터 제조된 필름 |
ES2380568T3 (es) * | 2009-11-10 | 2012-05-16 | Basell Polyolefine Gmbh | LDPE de alta presión, para aplicaciones médicas |
US20110172354A1 (en) * | 2010-01-04 | 2011-07-14 | Dow Global Technologies Inc. | Ethylene-based polymer compositions for use in fiber applications |
US8653207B1 (en) * | 2012-11-30 | 2014-02-18 | Westlake Longview Corporation | Process and apparatus for polymerizing ethylene under ultra-high pressure |
EP3168237A1 (fr) * | 2015-11-10 | 2017-05-17 | Dow Global Technologies LLC | Polymérisations à radicaux libres et pression élevée pour produire des polymères à base d'éthylène |
EP3168238A1 (fr) * | 2015-11-10 | 2017-05-17 | Dow Global Technologies LLC | Polymères à base d'éthylène formés par polymérisations à radical libre |
EP3168239A1 (fr) * | 2015-11-10 | 2017-05-17 | Dow Global Technologies LLC | Polymérisations de radicaux libres à haute pression |
EP3260472A1 (fr) * | 2016-06-24 | 2017-12-27 | Dow Global Technologies LLC | Polymères à base d'éthylène formés par polymérisations à radical libre |
JP2022156612A (ja) * | 2021-03-31 | 2022-10-14 | 住友化学株式会社 | ポリエチレンの製造方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA676159A (en) * | 1963-12-17 | C. Hull David | Ethylene resins | |
US2964515A (en) * | 1957-07-01 | 1960-12-13 | Nat Distillers Chem Corp | Ethylene polymerization process |
US3178404A (en) * | 1959-12-23 | 1965-04-13 | Eastman Kodak Co | Preparation of polyethylene in a two zone reactor employing caprylyl peroxide in the first zone as the catalyst |
US3756996A (en) * | 1964-10-02 | 1973-09-04 | Nat Distillers Chem Corp | Process for the production of ethylene polymers |
US3536693A (en) * | 1968-01-31 | 1970-10-27 | Eastman Kodak Co | Process for preparing polyethylene having improved properties |
GB1208120A (en) * | 1968-02-01 | 1970-10-07 | Ici Ltd | Ethylene polymerisation |
NL160292C (nl) * | 1969-09-19 | 1979-10-15 | Stamicarbon | Werkwijze en reactor voor het continu polymeriseren van etheen. |
US3875128A (en) * | 1973-05-04 | 1975-04-01 | Sumitomo Chemical Co | Process and apparatus for producing ethylene polymer |
US3923767A (en) * | 1974-08-22 | 1975-12-02 | Gulf Research Development Co | Ethylene polymerization process in the presence of quinone alkides |
US3963690A (en) * | 1974-10-07 | 1976-06-15 | The Dow Chemical Company | Polymerization of ethylene in stirred autoclave with cooled inner wall |
IN145649B (fr) * | 1974-12-16 | 1985-01-05 | Standard Oil Co |
-
1976
- 1976-06-29 JP JP7730076A patent/JPS532585A/ja active Granted
-
1977
- 1977-06-13 US US05/805,908 patent/US4085266A/en not_active Expired - Lifetime
- 1977-06-27 SU SU772498149A patent/SU1075978A3/ru active
- 1977-06-27 BR BR7704172A patent/BR7704172A/pt unknown
- 1977-06-28 HU HU77SU948A patent/HU179321B/hu not_active IP Right Cessation
- 1977-06-28 CA CA281,526A patent/CA1065544A/fr not_active Expired
- 1977-06-28 DE DE19772729103 patent/DE2729103A1/de not_active Ceased
- 1977-06-28 FR FR7719762A patent/FR2356677A1/fr active Granted
- 1977-06-28 MX MX775849U patent/MX4569E/es unknown
- 1977-06-28 NL NL7707167A patent/NL7707167A/xx not_active Application Discontinuation
- 1977-06-29 GB GB27291/77A patent/GB1538633A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0017230A1 (fr) * | 1979-04-05 | 1980-10-15 | E.I. Du Pont De Nemours And Company | Procédé continu de préparation de coplymères ordonnés d'éthylène et d'un acide carboxylique alpha, béta-insaturé ainsi que les ionomères préparés à partir de ces copolymères. |
Also Published As
Publication number | Publication date |
---|---|
HU179321B (en) | 1982-09-28 |
GB1538633A (en) | 1979-01-24 |
DE2729103A1 (de) | 1978-01-12 |
FR2356677B1 (fr) | 1981-03-06 |
JPS5415904B2 (fr) | 1979-06-18 |
CA1065544A (fr) | 1979-10-30 |
US4085266A (en) | 1978-04-18 |
MX4569E (es) | 1982-06-17 |
NL7707167A (nl) | 1978-01-02 |
JPS532585A (en) | 1978-01-11 |
BR7704172A (pt) | 1978-03-28 |
SU1075978A3 (ru) | 1984-02-23 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |