KR970702302A - 연속 중합에 의한 투명 피복 수지(CLEAR COAT RESINS BY CONTINUOUS POLYMERIZATlON) - Google Patents

연속 중합에 의한 투명 피복 수지(CLEAR COAT RESINS BY CONTINUOUS POLYMERIZATlON) Download PDF

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KR970702302A
KR970702302A KR1019960705527A KR19960705527A KR970702302A KR 970702302 A KR970702302 A KR 970702302A KR 1019960705527 A KR1019960705527 A KR 1019960705527A KR 19960705527 A KR19960705527 A KR 19960705527A KR 970702302 A KR970702302 A KR 970702302A
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reaction vessel
reaction
reactor zone
stirring means
acrylic monomer
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KR1019960705527A
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KR100240850B1 (ko
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마이클 씨 그레디
바실 브이 그레고로비치
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메코나헤이 미리암 디
이. 아이. 듀퐁 드 네모아 앤드 캄파니
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1862—Stationary reactors having moving elements inside placed in series
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00083—Coils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00121—Controlling the temperature by direct heating or cooling
    • B01J2219/0013—Controlling the temperature by direct heating or cooling by condensation of reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • B01J2219/00166—Controlling or regulating processes controlling the flow controlling the residence time inside the reactor vessel

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

팁 속도가 500 내지 1200rpm인 교반 수단을 가지는 용기에서 연속 중합에 의해 양호한 크레이터 방지성을 가지는 아크릴 중합체를 제조하는 공정. 단량체 및/또는 개시제를 투여하기 위한 공급 밸브는 교반 본체의 표면 아래에 위치시킨다.

Description

연속 중합에 의한 투명 피복 수지(CLEAR COAT RESINS BY CONTINUOUS POLYMERIZATlON)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 중합 공정을 도시하는 개략도이다.

Claims (9)

  1. (a) (i) 하나 이상의 아크릴 단량체; (ii) 상기 아크릴 단량체에 대한 개시제의 몰비가 약 0.01 내지 0.09가 되도륵 하는 양의 중합 개시제; (iii) 아크릴 단량체의 중량을 기준으로 약 0 내지 60%인 반응 용매를, 팁 속도가 500rpm 이상인 교반 수단을 가지는 제1반응 용기의 제1연속 혼합 반응기 영역내에 투입하고, (b) (i) 상기 반응기 영역에서 상기 투입된 아크릴 단량체의 체류시간을 약 15분 이상 제공하고; (ii) 상기 반응기 영역에서 반응 혼합물의 예정된 농도를 유지하고; (iii) 가공되기 쉬운 균일 농축된 중합체 생성물로의 전환을 가속시키기에 층분한 상승된 온도에서 용융 수지 혼합물을 유지하기에 충분하도륵 상기 제1반응기 영역을 통해 유동 속도를 유지시키고, (c) 상기 반응 혼합물을 팁 속도가 500rpm 이상인 교반 수단을 가지는 제2반응 용기의 제2연속 혼합 반응기 영역내로, 상기 제1반응 용기로부터 상기 제2반응 용기로 이르는 연결 수단을 통해 이동시키는 단계를 포함하는, 양호한 크레이터 방지성을 가지는 아크릴 중합체를 제조하기 위한 중합 공정.
  2. 제l항에 있어서, 상기 제1반응 용기의 직경에 대한 상기 제1반응 용기의 교반 수단의 직경의 비가 0.15 내지 0.95인 공정.
  3. 제1항에 있어서, 상기 제2반응 용기의 직격에 대한 상기 제2반응 용기의 교반 수단의 직경의 비가 0.15 내지 0.95인 공정.
  4. 제1항에 있어서, 온도가 80 내지 180℃의 범위인 공정.
  5. 제1항에 있어서, 체류 시간이 약 15 내지 120분인 공정.
  6. 제1항에 있어서, 중합체로 반응 생성물을 형성할 수 있는 용매가 아크릴 단량체의 혼합물에 사용되는 공정.
  7. 제1항에 있어서, 단량체 공급물이 반응성인 본체의 표면 아래로 반응 용기내에 도입되는 공정.
  8. 제1항에 있어서, 개시제 공급물이 반응성인 본체의 표면 아래로 반응 용기내에 도입되는 공정.
  9. 제5항에 있어서, 개시제 공급물이 반응성인 본체의 표면 아래로 반응 용기내에 도입되는 공정.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960705527A 1994-04-08 1995-04-10 양호한 크레이터 방지성을 가지는 아크릴 중합체를 제조하기 위한 중합공정 KR100240850B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US08/224,418 1994-04-08
US8/224,418 1994-04-08
US08/224,418 US5447998A (en) 1994-04-08 1994-04-08 Clear coat resins by continuous polymerization
PCT/US1995/004390 WO1995027742A1 (en) 1994-04-08 1995-04-10 Clear coat resins by continuous polymerization

Publications (2)

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KR970702302A true KR970702302A (ko) 1997-05-13
KR100240850B1 KR100240850B1 (ko) 2000-01-15

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KR1019960705527A KR100240850B1 (ko) 1994-04-08 1995-04-10 양호한 크레이터 방지성을 가지는 아크릴 중합체를 제조하기 위한 중합공정

Country Status (9)

Country Link
US (1) US5447998A (ko)
EP (1) EP0754197B1 (ko)
JP (1) JP3748568B2 (ko)
KR (1) KR100240850B1 (ko)
BR (1) BR9507450A (ko)
CA (1) CA2185220A1 (ko)
DE (1) DE69510542T2 (ko)
MX (1) MX9604496A (ko)
WO (1) WO1995027742A1 (ko)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19850243A1 (de) 1998-10-31 2000-05-11 Basf Coatings Ag Flüssige Stoffgemische und (Co)Polymerisate, Verfahren zu ihrer Herstellung und ihre Verwendung zur Herstellung von reaktiven Mehrstoffmischungen
DE19904330A1 (de) 1999-01-28 2000-08-10 Basf Coatings Ag Wäßriger Beschichtungsstoff und Modulsystem zu seiner Herstellung
DE19903725A1 (de) 1999-01-30 2000-08-10 Basf Coatings Ag Bindemittelgemische und ihre Verwendung in mit aktinischer Strahlung und/oder thermisch härtbaren Beschichtungsstoffen
DE19909894A1 (de) 1999-03-06 2000-09-07 Basf Coatings Ag Sol-Gel-Überzug für einschichtige oder mehrschichtige Lackierungen
DE19921457B4 (de) 1999-05-08 2006-05-04 Basf Coatings Ag Modulsystem zur Herstellung wäßriger Beschichtungsstoffe, Verfahren zu deren Herstellung und Verwendung sowie damit hergestellte Lackierungen
DE19938759A1 (de) 1999-08-16 2001-02-22 Basf Coatings Ag Beschichtungsstoff und seine Verwendung zur Herstellung hochkratzfester mehrschichtiger Klarlackierungen
DE19940855A1 (de) * 1999-08-27 2001-03-01 Basf Coatings Ag Lösemittelhaltiger Beschichtungsstoff und seine Verwendung
DE19940857A1 (de) 1999-08-27 2001-03-01 Basf Coatings Ag Sol-Gel-Überzug für einschichtige oder mehrschichtige Lackierungen
DE19940858A1 (de) 1999-08-27 2001-03-01 Basf Coatings Ag Sol-Gel-Überzug für einschichtige oder mehrschichtige Lackierungen
DE19961402A1 (de) * 1999-12-20 2001-07-05 Basf Coatings Ag Verfahren zur Herstellung von Beschichtungen aus thermisch und mit aktinischer Strahlung härtbaren Beschichtungstoffen
DE10029802A1 (de) 2000-06-16 2002-01-03 Basf Coatings Ag Farb- und/oder effektgebende wäßrige Beschichtungsstoffe und ihre Verwendung zur Herstellung farb- und/oder effektgebender, verformbarer Laminate
DE10043810A1 (de) 2000-09-06 2002-04-04 Basf Coatings Ag Bindemittellösung und ihre Verwendung für die KFZ-Kleinstreparatur im Teil
DE10130972C1 (de) 2001-06-27 2002-11-07 Basf Coatings Ag Verfahren zur Herstellung von Beschichtungen aus thermisch und mit aktinischer Strahlung härtbaren Beschichtungsstoffen und mit dem Verfahren herstellbare Lackierungen
US20110039116A1 (en) * 2009-08-11 2011-02-17 Chuang Peng-Jung Colored plating structure and method thereof
US8901198B2 (en) 2010-11-05 2014-12-02 Ppg Industries Ohio, Inc. UV-curable coating compositions, multi-component composite coatings, and related coated substrates
US8513321B2 (en) 2010-11-05 2013-08-20 Ppg Industries Ohio, Inc. Dual cure coating compositions, methods of coating a substrate, and related coated substrates
WO2012140131A1 (de) 2011-04-12 2012-10-18 Basf Coatings Gmbh Lösemittelhaltige klarlackbeschichtungszusammensetzung, verfahren zu ihrer herstellung und ihre verwendung
WO2013076208A1 (de) 2011-11-25 2013-05-30 Basf Coatings Gmbh Lösemittelhaltige klarlackbeschichtungszusammensetzung, verfahren zu ihrer herstellung und ihre verwendung
US9617448B2 (en) 2012-02-03 2017-04-11 Basf Coatings Gmbh Clearcoat coating composition, method for production and use
US20130213894A1 (en) 2012-02-17 2013-08-22 Jsr Corporation Cleaning method of immersion liquid, immersion liquid cleaning composition, and substrate
JP6504177B2 (ja) * 2014-09-22 2019-04-24 東亞合成株式会社 アクリル酸系共重合体の製造方法
WO2016184853A1 (de) 2015-05-21 2016-11-24 Covestro Deutschland Ag Polyurethan-beschichtungszusammensetzungen
CN109925975B (zh) * 2019-04-03 2020-09-01 中山华明泰科技股份有限公司 一种固体丙烯酸树脂管式自动反应装置
EP4004060B1 (en) 2019-07-29 2023-05-31 BASF Coatings GmbH Coating compositions containing (meth)acrylic resins having silane groups

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2839563A1 (de) * 1978-09-12 1980-03-27 Hoechst Ag Verfahren zur kontinuierlichen massepolymerisation von alkenylaromaten
DE2951045C2 (de) * 1979-12-19 1983-12-22 Röhm GmbH, 6100 Darmstadt Herstellung von schlagzähen Harzen
US4414370A (en) * 1981-01-09 1983-11-08 S. C. Johnson & Son, Inc. Process for continuous bulk copolymerization of vinyl monomers
US4529787A (en) * 1982-06-15 1985-07-16 S. C. Johnson & Son, Inc. Bulk polymerization process for preparing high solids and uniform copolymers
US4546160A (en) * 1984-02-29 1985-10-08 S. C. Johnson & Son, Inc. Bulk polymerization process for preparing high solids and uniform copolymers
DE68903655T2 (de) * 1988-03-17 1993-04-08 Dainippon Ink & Chemicals Verfahren zur herstellung eines styrol/methacrylsaeurecopolymers.

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Publication number Publication date
DE69510542T2 (de) 1999-11-11
DE69510542D1 (de) 1999-08-05
KR100240850B1 (ko) 2000-01-15
US5447998A (en) 1995-09-05
WO1995027742A1 (en) 1995-10-19
JP3748568B2 (ja) 2006-02-22
MX9604496A (es) 1997-11-29
EP0754197B1 (en) 1999-06-30
EP0754197A1 (en) 1997-01-22
JPH09511777A (ja) 1997-11-25
EP0754197A4 (en) 1997-08-13
BR9507450A (pt) 1997-08-05
CA2185220A1 (en) 1995-10-19

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