FR2000575A1 - Chlorination of pvc obtained by bulk of suspension - Google Patents

Chlorination of pvc obtained by bulk of suspension

Info

Publication number
FR2000575A1
FR2000575A1 FR6900855A FR6900855A FR2000575A1 FR 2000575 A1 FR2000575 A1 FR 2000575A1 FR 6900855 A FR6900855 A FR 6900855A FR 6900855 A FR6900855 A FR 6900855A FR 2000575 A1 FR2000575 A1 FR 2000575A1
Authority
FR
France
Prior art keywords
polymers
suspension
polymer
chlorine
chlorination
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR6900855A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay SA
Original Assignee
Solvay SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay SA filed Critical Solvay SA
Publication of FR2000575A1 publication Critical patent/FR2000575A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/18Introducing halogen atoms or halogen-containing groups
    • C08F8/20Halogenation

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Chlorinated polyvinyl chlorides having a chlorine content of 60-70% are prepared by (1) carrying out a suspension or mass polymerisation of vinyl chloride using an acyl peroxide catalyst to give a polymer having a K value of 50 - 80 in dichloroethane, a relative viscosity of 1.3 - 1.8, a specific weight of 0.40 - 0.80 kg/dm3, and a particle size of 0.50-0.5 mm.,and (2) chlorinating an aqueous suspension of the polymer at 35 deg. - 80 deg.C. using a chlorine pressure of 2 -10 kg/cm2 and a water : polymer phase ratio between 1.5:1 and 5:1. The chlorination step is simple, rapid and cheap, and large amounts of chlorine are incorporated quickly. The polymers have an excellent stability under load at high temperatures and are also easy to blend with plasticisers or other polymers. The polymers are remarkably transparent.
FR6900855A 1968-01-23 1969-01-17 Chlorination of pvc obtained by bulk of suspension Withdrawn FR2000575A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL6800992A NL6800992A (en) 1968-01-23 1968-01-23

Publications (1)

Publication Number Publication Date
FR2000575A1 true FR2000575A1 (en) 1969-09-12

Family

ID=19802568

Family Applications (1)

Application Number Title Priority Date Filing Date
FR6900855A Withdrawn FR2000575A1 (en) 1968-01-23 1969-01-17 Chlorination of pvc obtained by bulk of suspension

Country Status (11)

Country Link
AT (1) AT290127B (en)
BE (1) BE726839A (en)
BR (1) BR6905829D0 (en)
CH (1) CH490430A (en)
DE (1) DE1817523A1 (en)
DK (1) DK121473B (en)
ES (1) ES362482A1 (en)
FR (1) FR2000575A1 (en)
GB (1) GB1186847A (en)
NL (1) NL6800992A (en)
SE (1) SE345278B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3136362A1 (en) 2022-06-14 2023-12-15 Institut Mines Telecom Instrumented scleral lens and associated device, embedded in the lens or not, for measuring the pupil diameter of an eye.

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4412898A (en) 1980-08-26 1983-11-01 The B.F. Goodrich Company Process for chlorination of PVC in water without use of swelling agents
AU543448B2 (en) * 1980-08-26 1985-04-18 B.F. Goodrich Company, The Process for chlorination of pvc in water without use of swelling agents
JP2017521535A (en) * 2014-07-22 2017-08-03 リライアンス インダストリーズ リミテッドReliance Industries Ltd. Production process of chlorinated polyvinyl chloride

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3136362A1 (en) 2022-06-14 2023-12-15 Institut Mines Telecom Instrumented scleral lens and associated device, embedded in the lens or not, for measuring the pupil diameter of an eye.
WO2023242067A1 (en) 2022-06-14 2023-12-21 Institut Mines Telecom Instrumented scleral lens and associated device, optionally fitted in the lens, for measuring the pupil diameter of an eye

Also Published As

Publication number Publication date
ES362482A1 (en) 1970-12-01
BE726839A (en) 1969-07-14
GB1186847A (en) 1970-04-08
SE345278B (en) 1972-05-23
DK121473B (en) 1971-10-18
BR6905829D0 (en) 1973-01-04
DE1817523A1 (en) 1969-07-31
CH490430A (en) 1970-05-15
NL6800992A (en) 1969-07-25
AT290127B (en) 1971-05-25

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Legal Events

Date Code Title Description
TP Transmission of property
ST Notification of lapse