FI110107B - Termoplastinen olefiinipolymeeri ja menetelmä sen valmistamiseksi - Google Patents

Termoplastinen olefiinipolymeeri ja menetelmä sen valmistamiseksi Download PDF

Info

Publication number: FI110107B
Authority: FI; Finland
Prior art keywords: olefin; component; ethylene; polymer; propylene
Prior art date: 1989-08-23

Application number

FI904109A

Other languages

English (en)

Finnish (fi)

Swedish (sv)

Other versions

FI904109A0 (fi

Inventor

Anteo Pelliconi

Giuliano Cecchin

Giovanni Patroncini

Lewis R Leonard

Original Assignee

Montell North America Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-08-23

Filing date

1990-08-20

Publication date

2002-11-29

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27015928&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=FI110107(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1990-08-20 Application filed by Montell North America Inc filed Critical Montell North America Inc

1990-08-20 Publication of FI904109A0 publication Critical patent/FI904109A0/fi

2002-11-29 Application granted granted Critical

2002-11-29 Publication of FI110107B publication Critical patent/FI110107B/fi

Links

229920000642 polymer Polymers 0.000 title claims abstract description 60
229920002397 thermoplastic olefin Polymers 0.000 title claims abstract description 24
238000002360 preparation method Methods 0.000 title claims description 17
238000000034 method Methods 0.000 title claims description 15
239000004711 α-olefin Substances 0.000 claims abstract description 39
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 33
239000005977 Ethylene Substances 0.000 claims abstract description 33
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 27
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 24
229920001577 copolymer Polymers 0.000 claims abstract description 21
150000001993 dienes Chemical class 0.000 claims abstract description 6
229920001519 homopolymer Polymers 0.000 claims abstract description 6
229920005606 polypropylene copolymer Polymers 0.000 claims abstract description 4
238000006116 polymerization reaction Methods 0.000 claims description 34
239000000178 monomer Substances 0.000 claims description 27
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 18
239000008096 xylene Substances 0.000 claims description 18
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 16
-1 titanium halide Chemical class 0.000 claims description 16
239000003054 catalyst Substances 0.000 claims description 15
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 11
239000011949 solid catalyst Substances 0.000 claims description 11
150000001875 compounds Chemical class 0.000 claims description 9
239000000463 material Substances 0.000 claims description 5
239000010936 titanium Substances 0.000 claims description 5
125000000217 alkyl group Chemical group 0.000 claims description 4
238000004519 manufacturing process Methods 0.000 claims description 4
239000011148 porous material Substances 0.000 claims description 4
229920001384 propylene homopolymer Polymers 0.000 claims description 4
230000035939 shock Effects 0.000 claims description 4
238000002083 X-ray spectrum Methods 0.000 claims description 3
229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
239000012798 spherical particle Substances 0.000 claims description 3
238000009826 distribution Methods 0.000 claims description 2
229910052719 titanium Inorganic materials 0.000 claims description 2
230000001747 exhibiting effect Effects 0.000 claims 1
150000003944 halohydrins Chemical class 0.000 claims 1
229920001083 polybutene Polymers 0.000 claims 1
239000000203 mixture Substances 0.000 abstract description 16
229920000089 Cyclic olefin copolymer Polymers 0.000 abstract description 2
229920005684 linear copolymer Polymers 0.000 abstract description 2
229920001748 polybutylene Polymers 0.000 abstract 1
239000007789 gas Substances 0.000 description 25
239000012071 phase Substances 0.000 description 25
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 10
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 9
229920001971 elastomer Polymers 0.000 description 9
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
239000007788 liquid Substances 0.000 description 8
239000000047 product Substances 0.000 description 8
239000005060 rubber Substances 0.000 description 8
239000007787 solid Substances 0.000 description 8
238000003756 stirring Methods 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 7
239000001257 hydrogen Substances 0.000 description 7
229910052739 hydrogen Inorganic materials 0.000 description 7
229920001897 terpolymer Polymers 0.000 description 7
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 6
239000007791 liquid phase Substances 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
239000012467 final product Substances 0.000 description 5
238000002156 mixing Methods 0.000 description 5
229920001155 polypropylene Polymers 0.000 description 5
239000004743 Polypropylene Substances 0.000 description 4
229920001038 ethylene copolymer Polymers 0.000 description 4
150000002430 hydrocarbons Chemical class 0.000 description 4
239000011777 magnesium Substances 0.000 description 4
235000011147 magnesium chloride Nutrition 0.000 description 4
239000002245 particle Substances 0.000 description 4
239000002904 solvent Substances 0.000 description 4
229920001169 thermoplastic Polymers 0.000 description 4
229920002725 thermoplastic elastomer Polymers 0.000 description 4
239000004416 thermosoftening plastic Substances 0.000 description 4
OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 3
239000004215 Carbon black (E152) Substances 0.000 description 3
229920000181 Ethylene propylene rubber Polymers 0.000 description 3
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
239000012190 activator Substances 0.000 description 3
238000005054 agglomeration Methods 0.000 description 3
230000002776 aggregation Effects 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 3
229930195733 hydrocarbon Natural products 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
229920000098 polyolefin Polymers 0.000 description 3
239000000843 powder Substances 0.000 description 3
239000001294 propane Substances 0.000 description 3
229910000077 silane Inorganic materials 0.000 description 3
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
229920002943 EPDM rubber Polymers 0.000 description 2
241000282326 Felis catus Species 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
239000004264 Petrolatum Substances 0.000 description 2
239000012298 atmosphere Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
229920001400 block copolymer Polymers 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
238000010276 construction Methods 0.000 description 2
238000001816 cooling Methods 0.000 description 2
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229920001903 high density polyethylene Polymers 0.000 description 2
239000004700 high-density polyethylene Substances 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
239000000155 melt Substances 0.000 description 2
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
235000019271 petrolatum Nutrition 0.000 description 2
229940066842 petrolatum Drugs 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
239000006069 physical mixture Substances 0.000 description 2
150000004756 silanes Chemical class 0.000 description 2
229920002545 silicone oil Polymers 0.000 description 2
239000000243 solution Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 2
150000003609 titanium compounds Chemical class 0.000 description 2
PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
RJUCIROUEDJQIB-GQCTYLIASA-N (6e)-octa-1,6-diene Chemical compound C\C=C\CCCC=C RJUCIROUEDJQIB-GQCTYLIASA-N 0.000 description 1
PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 1
240000007124 Brassica oleracea Species 0.000 description 1
235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
238000004566 IR spectroscopy Methods 0.000 description 1
239000005662 Paraffin oil Substances 0.000 description 1
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
240000002871 Tectona grandis Species 0.000 description 1
FNYLWPVRPXGIIP-UHFFFAOYSA-N Triamterene Chemical compound NC1=NC2=NC(N)=NC(N)=C2N=C1C1=CC=CC=C1 FNYLWPVRPXGIIP-UHFFFAOYSA-N 0.000 description 1
BEIOEBMXPVYLRY-UHFFFAOYSA-N [4-[4-bis(2,4-ditert-butylphenoxy)phosphanylphenyl]phenyl]-bis(2,4-ditert-butylphenoxy)phosphane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(C=1C=CC(=CC=1)C=1C=CC(=CC=1)P(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C BEIOEBMXPVYLRY-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
239000000956 alloy Substances 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
238000010923 batch production Methods 0.000 description 1
230000002051 biphasic effect Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
210000000988 bone and bone Anatomy 0.000 description 1
CVIGVIRPHDSILR-UHFFFAOYSA-N but-1-ene ethene Chemical group C=C.C=CCC.C=C CVIGVIRPHDSILR-UHFFFAOYSA-N 0.000 description 1
IYYGCUZHHGZXGJ-UHFFFAOYSA-N but-1-ene;ethene;prop-1-ene Chemical compound C=C.CC=C.CCC=C IYYGCUZHHGZXGJ-UHFFFAOYSA-N 0.000 description 1
239000001273 butane Substances 0.000 description 1
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
235000013539 calcium stearate Nutrition 0.000 description 1
239000008116 calcium stearate Substances 0.000 description 1
235000011089 carbon dioxide Nutrition 0.000 description 1
239000012986 chain transfer agent Substances 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
XUCKQPJKYWZURJ-UHFFFAOYSA-N cyclohexyl(dimethoxy)silane Chemical compound CO[SiH](OC)C1CCCCC1 XUCKQPJKYWZURJ-UHFFFAOYSA-N 0.000 description 1
SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
ZVMRWPHIZSSUKP-UHFFFAOYSA-N dicyclohexyl(dimethoxy)silane Chemical compound C1CCCCC1[Si](OC)(OC)C1CCCCC1 ZVMRWPHIZSSUKP-UHFFFAOYSA-N 0.000 description 1
238000000113 differential scanning calorimetry Methods 0.000 description 1
AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 description 1
239000003814 drug Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000000806 elastomer Substances 0.000 description 1
230000001804 emulsifying effect Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
238000012685 gas phase polymerization Methods 0.000 description 1
238000002309 gasification Methods 0.000 description 1
238000005469 granulation Methods 0.000 description 1
230000003179 granulation Effects 0.000 description 1
238000001033 granulometry Methods 0.000 description 1
238000000227 grinding Methods 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
239000008240 homogeneous mixture Substances 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
229920000092 linear low density polyethylene Polymers 0.000 description 1
239000004707 linear low-density polyethylene Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
238000003801 milling Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
150000005673 monoalkenes Chemical class 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
JQCXWCOOWVGKMT-UHFFFAOYSA-N phthalic acid diheptyl ester Natural products CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920005629 polypropylene homopolymer Polymers 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
229920005604 random copolymer Polymers 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
230000000707 stereoselective effect Effects 0.000 description 1
239000000725 suspension Substances 0.000 description 1
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
239000006200 vaporizer Substances 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1
238000004073 vulcanization Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/909—Polymerization characterized by particle size of product
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Graft Or Block Polymers (AREA)
Compositions Of Macromolecular Compounds (AREA)
Processes Of Treating Macromolecular Substances (AREA)
Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Surface Acoustic Wave Elements And Circuit Networks Thereof (AREA)

FI904109A 1989-08-23 1990-08-20 Termoplastinen olefiinipolymeeri ja menetelmä sen valmistamiseksi FI110107B (fi)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date
US39761689A	1989-08-23	1989-08-23
US39761689		1989-08-23
US54246890A	1990-06-22	1990-06-22
US54246890		1990-06-22

Publications (2)

Publication Number	Publication Date
FI904109A0 FI904109A0 (fi)	1990-08-20
FI110107B true FI110107B (fi)	2002-11-29

Family

ID=27015928

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FI904109A FI110107B (fi)	1989-08-23	1990-08-20	Termoplastinen olefiinipolymeeri ja menetelmä sen valmistamiseksi

Country Status (15)

Country	Link
US (1)	US5326639A (de)
EP (1)	EP0416379B1 (de)
JP (1)	JP2977250B2 (de)
KR (1)	KR0178977B1 (de)
CN (1)	CN1057777C (de)
AT (1)	ATE136911T1 (de)
AU (1)	AU630731B2 (de)
BR (1)	BR9004156A (de)
DE (1)	DE69026558T2 (de)
DK (1)	DK0416379T3 (de)
FI (1)	FI110107B (de)
HU (1)	HU210337B (de)
IL (1)	IL95097A0 (de)
NO (1)	NO177789C (de)
PT (1)	PT95063A (de)

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1990
- 1990-07-16 IL IL95097A patent/IL95097A0/xx unknown
- 1990-08-07 NO NO903465A patent/NO177789C/no unknown
- 1990-08-16 HU HU905040A patent/HU210337B/hu not_active IP Right Cessation
- 1990-08-18 CN CN90107146A patent/CN1057777C/zh not_active Expired - Fee Related
- 1990-08-20 FI FI904109A patent/FI110107B/fi active IP Right Grant
- 1990-08-21 AU AU61208/90A patent/AU630731B2/en not_active Ceased
- 1990-08-22 PT PT95063A patent/PT95063A/pt not_active Application Discontinuation
- 1990-08-22 JP JP2220943A patent/JP2977250B2/ja not_active Expired - Fee Related
- 1990-08-22 BR BR909004156A patent/BR9004156A/pt not_active IP Right Cessation
- 1990-08-23 KR KR1019900013007A patent/KR0178977B1/ko not_active IP Right Cessation
- 1990-08-23 AT AT90116161T patent/ATE136911T1/de not_active IP Right Cessation
- 1990-08-23 DE DE69026558T patent/DE69026558T2/de not_active Expired - Fee Related
- 1990-08-23 DK DK90116161.2T patent/DK0416379T3/da active
- 1990-08-23 EP EP90116161A patent/EP0416379B1/de not_active Expired - Lifetime
1993
- 1993-06-08 US US08/073,631 patent/US5326639A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
EP0416379B1 (de)	1996-04-17
ATE136911T1 (de)	1996-05-15
BR9004156A (pt)	1991-09-03
JP2977250B2 (ja)	1999-11-15
HU210337B (en)	1995-03-28
NO903465L (no)	1991-02-25
DE69026558T2 (de)	1996-10-02
DK0416379T3 (da)	1996-05-13
HUT59707A (en)	1992-06-29
EP0416379A2 (de)	1991-03-13
NO177789C (no)	1995-11-22
CN1051183A (zh)	1991-05-08
FI904109A0 (fi)	1990-08-20
CN1057777C (zh)	2000-10-25
KR0178977B1 (ko)	1999-05-15
AU6120890A (en)	1991-02-28
JPH0397747A (ja)	1991-04-23
NO177789B (no)	1995-08-14
PT95063A (pt)	1991-04-18
NO903465D0 (no)	1990-08-07
EP0416379A3 (en)	1991-09-25
AU630731B2 (en)	1992-11-05
HU905040D0 (en)	1991-01-28
IL95097A0 (en)	1991-06-10
KR910004684A (ko)	1991-03-29
DE69026558D1 (de)	1996-05-23
US5326639A (en)	1994-07-05

Legal Events

Date	Code	Title	Description
1996-02-26	HC	Name/ company changed in application	Owner name: MONTELL NORTH AMERICA INC.
2004-08-31	FG	Patent granted	Owner name: MONTELL NORTH AMERICA INC.

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KR20080075117A (ko)	2008-08-14	프로필렌-에틸렌 공중합체 및 이의 제조 방법