ES8101032A1 - Procedimiento para producir acido formico - Google Patents

Procedimiento para producir acido formico

Info

Publication number
ES8101032A1
ES8101032A1 ES490435A ES490435A ES8101032A1 ES 8101032 A1 ES8101032 A1 ES 8101032A1 ES 490435 A ES490435 A ES 490435A ES 490435 A ES490435 A ES 490435A ES 8101032 A1 ES8101032 A1 ES 8101032A1
Authority
ES
Spain
Prior art keywords
formic acid
distillation
anhydrous
extractant
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES490435A
Other languages
English (en)
Other versions
ES490435A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of ES490435A0 publication Critical patent/ES490435A0/es
Publication of ES8101032A1 publication Critical patent/ES8101032A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Cosmetics (AREA)

Abstract

PROCEDIMIENTO DE OBTENCION DE ACIDO FORMICO. CONSTA DE LAS SIGUIENTES ETAPAS: 1) HIDROLISIS DEL METILFORMIATO. 2) DESTILACION DE LA MEZCLA DE HIDROLISIS DEL METANOL Y EL METILFORMIATO EN EXCESO. 3) EXTRACCION DEL PRODUCTO DE FONDO CON UN AGENTE QUE EXTRAE PRINCIPALMENTE EL ACIDO FORMICO. 4) DESTILACION DE LA FASE EXTRAIDA. 5) RECICLADO DEL PRODUCTO DE CABEZA QUE SE OBTIENE DE LA DESTILACION EN FORMA DE VAPOR A LA PARTE INFERIOR DE LA COLUMNA DE DESTILACION, DONDE SE SOMETE DE NUEVO A LA ETAPA 2. 6) SEPARACION POR DESTILACION DEL COMPUESTO DE FONDO DE ETAPA 4 EN ACIDO FORMICO ANDHIDRIDO O ESENCIALMENTE ANHIDRO Y AGENTE DE EXTRACCION. 7) RECICLADO DEL AGENTE DE EXTRACCION QUE SALE DE LA ETAPA 6. EL AGUA QUE SE NECESITA PARA LA HIDROLISIS SE INTRODUCE EN FORMA DE VAPOR EN LA PARTE INFERIOR O MEDIA DE LA COLUMNA CORRESPONDIENTE DE LA ETAPA 2.
ES490435A 1979-04-11 1980-04-10 Procedimiento para producir acido formico Expired ES8101032A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19792914671 DE2914671A1 (de) 1979-04-11 1979-04-11 Verfahren zur gewinnung von wasserfreier oder weitgehend wasserfreier ameisensaeure

Publications (2)

Publication Number Publication Date
ES490435A0 ES490435A0 (es) 1980-12-01
ES8101032A1 true ES8101032A1 (es) 1980-12-01

Family

ID=6068072

Family Applications (1)

Application Number Title Priority Date Filing Date
ES490435A Expired ES8101032A1 (es) 1979-04-11 1980-04-10 Procedimiento para producir acido formico

Country Status (10)

Country Link
US (1) US4326073A (es)
EP (1) EP0017866B1 (es)
JP (1) JPS568341A (es)
AT (1) ATE1670T1 (es)
AU (1) AU528657B2 (es)
CA (1) CA1135282A (es)
DE (2) DE2914671A1 (es)
ES (1) ES8101032A1 (es)
NO (1) NO152371C (es)
ZA (1) ZA802156B (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS585895B2 (ja) * 1980-07-17 1983-02-02 日本ソレツクス株式会社 有機酸の分離方法
NL8103517A (nl) * 1981-07-24 1983-02-16 Badger Bv Werkwijze voor het scheiden van carbonzuren van mengsels met niet-zuren door een absorptie-stripbehandeling.
DE3319651A1 (de) * 1983-05-31 1984-12-06 Basf Ag, 6700 Ludwigshafen Verfahren zur destillativen gewinnung von ameisensaeure
DE3411384A1 (de) * 1984-03-28 1985-10-10 Basf Ag, 6700 Ludwigshafen Verfahren zur gewinnung von wasserfreier oder weitgehend wasserfreier ameisensaeure durch hydrolyse von methylformiat
DE3417790A1 (de) * 1984-05-14 1985-11-14 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von ameisensaeure
DE4211141A1 (de) * 1992-04-03 1993-10-07 Basf Ag Verfahren zur Herstellung von Ameisensäure durch thermische Spaltung von quartären Ammoniumformiaten
DE4444979A1 (de) 1994-12-16 1996-06-20 Basf Ag Verfahren und Vorrichtung zur Gewinnung von Ameisensäure
DE19953832A1 (de) * 1999-11-09 2001-05-10 Basf Ag Verfahren zur Herstellung von Ameisensäure
DE10002794A1 (de) * 2000-01-24 2001-07-26 Basf Ag Abwasserreinigung beim Verfahren zur Herstellung von wasserfreier Ameisensäure
DE10002793A1 (de) * 2000-01-24 2001-07-26 Basf Ag Verwendung eines Extraktionsmittels bei der Herstellung von wasserfreier Ameisensäure
DE10002790A1 (de) * 2000-01-24 2001-07-26 Basf Ag Verfahren zur Reinigung von Abgasströmen
DE10002795A1 (de) 2000-01-24 2001-08-02 Basf Ag Werkstoff für eine Anlage zur Herstellung von wasserfreier Ameisensäure
DE10002791A1 (de) * 2000-01-24 2001-07-26 Basf Ag Verfahren zur Gewinnung von wasserfreier Ameisensäure
DE10237379A1 (de) * 2002-08-12 2004-02-19 Basf Ag Verfahren und Vorrichtung zur Herstellung von ameisensauren Formiaten und deren Verwendung
DE10237380A1 (de) * 2002-08-12 2004-02-19 Basf Ag Verfahren und Vorrichtung zur Herstellung von ameisensauren Formlaten und deren Verwendung
US7495232B2 (en) * 2003-10-16 2009-02-24 Alis Corporation Ion sources, systems and methods
CN101544558B (zh) * 2008-03-24 2014-05-07 四川省达科特能源科技有限公司 从含水甲酸中分离精制得到高纯度甲酸的方法
US8138371B2 (en) * 2009-03-11 2012-03-20 Biofine Technologies Llc Production of formic acid
WO2013030162A1 (en) 2011-08-27 2013-03-07 Taminco Process of formic acid production by hydrolysis of methyl formate
US10266466B2 (en) 2017-08-02 2019-04-23 Eastman Chemical Company Iron-catalyzed transfer hydrogenation of esters to alcohols
US10266467B2 (en) 2017-08-02 2019-04-23 Eastman Chemical Company Synthesis of glycols via transfer hydrogenation of alpha-functional esters with alcohols
US10435349B2 (en) 2017-08-02 2019-10-08 Eastman Chemical Company Iron-catalyzed cross-coupling of methanol with secondary or tertiary alcohols to produce formate esters
US10544077B2 (en) * 2017-08-02 2020-01-28 Eastman Chemical Company Process for making formic acid utilizing higher-boiling formate esters
US10570081B2 (en) 2017-08-02 2020-02-25 Eastman Chemical Company Process for making formic acid utilizing lower-boiling formate esters
WO2019037768A1 (en) 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
CN114644549A (zh) * 2022-04-24 2022-06-21 聊城市鲁西化工工程设计有限责任公司 一种甲酸的生产***及生产工艺

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2160064A (en) * 1936-06-17 1939-05-30 Carbide & Carbon Chem Corp Manufacture of formic acid
NL7501253A (nl) * 1974-02-15 1975-08-19 Basf Ag Werkwijze voor het winnen van mierezuur.
US4217460A (en) * 1975-10-11 1980-08-12 Basf Aktiengesellschaft Isolation of formic acid from its aqueous solutions
DE2545658C2 (de) * 1975-10-11 1985-12-19 Basf Ag, 6700 Ludwigshafen Verfahren zur Gewinnung von Carbonsäuren aus ihren wäßrigen Lösungen
DE2545730A1 (de) * 1975-10-11 1977-04-21 Basf Ag Verfahren zur reindarstellung von ameisensaeure
US4143066A (en) * 1976-12-16 1979-03-06 The Dow Chemical Company Separation and recovery of carboxylic acids from water
DE2744313A1 (de) * 1977-10-01 1979-04-12 Basf Ag Verfahren zur herstellung von ameisensaeure
DE2853991A1 (de) * 1978-12-14 1980-07-03 Basf Ag Verfahren zur gewinnung von wasserfreier oder weitgehend wasserfreier ameisensaeure

Also Published As

Publication number Publication date
US4326073A (en) 1982-04-20
DE2914671A1 (de) 1980-10-23
DE3060960D1 (en) 1982-11-25
JPS6236507B2 (es) 1987-08-07
NO152371B (no) 1985-06-10
ES490435A0 (es) 1980-12-01
NO152371C (no) 1985-09-18
ZA802156B (en) 1981-05-27
NO801034L (no) 1980-10-13
ATE1670T1 (de) 1982-11-15
CA1135282A (en) 1982-11-09
EP0017866A1 (de) 1980-10-29
JPS568341A (en) 1981-01-28
EP0017866B1 (de) 1982-10-20
AU528657B2 (en) 1983-05-05
AU5729680A (en) 1980-10-16

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