ES442881A1 - Pyrimidinyl -thiono- phosphoric -phosphonic- acid esters and ester-amides and their use as insecticides acaricides and nemati cides - Google Patents
Pyrimidinyl -thiono- phosphoric -phosphonic- acid esters and ester-amides and their use as insecticides acaricides and nemati cidesInfo
- Publication number
- ES442881A1 ES442881A1 ES442881A ES442881A ES442881A1 ES 442881 A1 ES442881 A1 ES 442881A1 ES 442881 A ES442881 A ES 442881A ES 442881 A ES442881 A ES 442881A ES 442881 A1 ES442881 A1 ES 442881A1
- Authority
- ES
- Spain
- Prior art keywords
- formula
- thiono
- phosphonic
- phosphoric
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000000895 acaricidal effect Effects 0.000 title 1
- 239000000642 acaricide Substances 0.000 title 1
- 239000002917 insecticide Substances 0.000 title 1
- 239000005645 nematicide Substances 0.000 title 1
- 125000000714 pyrimidinyl group Chemical group 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- -1 pyrimidinyl (thiono) Chemical class 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- WHEQVHAIRSPYDK-UHFFFAOYSA-N 4,6-dimethyl-1h-pyrimidin-2-one Chemical class CC1=CC(C)=NC(O)=N1 WHEQVHAIRSPYDK-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000012458 free base Substances 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052717 sulfur Chemical group 0.000 abstract 1
- 239000011593 sulfur Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
- C07F9/6509—Six-membered rings
- C07F9/6512—Six-membered rings having the nitrogen atoms in positions 1 and 3
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Procedure for preparing esters and amides of substituted pyrimidinyl (thiono) phosphoric (phosphonic) esters, of formula: ** (See formula) ** in that R is alkyl with 1 to 4 carbon atoms, R1 is alkyl, alkoxy or alkylanino with 1 to 6 carbon or phenyl atoms, R2 is alkyl with 1 to 4 carbon atoms or phenyl optionally substituted by halogen, and X is oxygen or sulfur; characterized by comprising reacting ester halides, respectively ester esters, phosphoric (thiono) acids (phosphonic), of the formula: ** (See formula) ** with the free base, with the alkaline, alkaline earth or ammonium salts or the hydrochloride of 2-hydroxy-4,6-dimethylpyrimidine derivatives of formula ** (See formula) ** in whose formulas R, R1, R2 and X have the meanings defined above and Hal represents halogen, optionally in the presence of an acid acceptor and optionally in the presence of an organic solvent, at temperatures between 0 and 120ºC, preferably between 40 and 65ºC. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19742455586 DE2455586A1 (en) | 1974-11-23 | 1974-11-23 | SUBSTITUTED PYRIMIDINYL (THIONO) PHOSPHORUS (PHOSPHONE) -AEUREESTER OR. -ESTERAMIDE, METHOD OF MANUFACTURING AND USING THEY AS INSECTICIDES, ACARICIDES AND NEMATICIDES |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES442881A1 true ES442881A1 (en) | 1977-04-16 |
Family
ID=5931604
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES442881A Expired ES442881A1 (en) | 1974-11-23 | 1975-11-21 | Pyrimidinyl -thiono- phosphoric -phosphonic- acid esters and ester-amides and their use as insecticides acaricides and nemati cides |
Country Status (18)
| Country | Link |
|---|---|
| JP (2) | JPS5173134A (en) |
| AT (1) | AT334399B (en) |
| AU (1) | AU8671175A (en) |
| BE (1) | BE835769A (en) |
| BR (1) | BR7507716A (en) |
| DD (1) | DD125569A5 (en) |
| DE (1) | DE2455586A1 (en) |
| DK (1) | DK525175A (en) |
| ES (1) | ES442881A1 (en) |
| GB (1) | GB1476072A (en) |
| IE (1) | IE42181B1 (en) |
| IL (1) | IL48503A0 (en) |
| LU (1) | LU73851A1 (en) |
| NL (1) | NL7513585A (en) |
| PL (1) | PL95712B1 (en) |
| SU (1) | SU592331A3 (en) |
| TR (1) | TR18550A (en) |
| ZA (1) | ZA757313B (en) |
-
1974
- 1974-11-23 DE DE19742455586 patent/DE2455586A1/en active Pending
-
1975
- 1975-10-17 GB GB4262175A patent/GB1476072A/en not_active Expired
- 1975-11-18 AU AU86711/75A patent/AU8671175A/en not_active Expired
- 1975-11-20 NL NL7513585A patent/NL7513585A/en unknown
- 1975-11-20 SU SU752189812A patent/SU592331A3/en active
- 1975-11-20 IL IL48503A patent/IL48503A0/en unknown
- 1975-11-20 BE BE162036A patent/BE835769A/en unknown
- 1975-11-20 TR TR18550A patent/TR18550A/en unknown
- 1975-11-21 JP JP50139380A patent/JPS5173134A/en active Pending
- 1975-11-21 JP JP50139379A patent/JPS5175080A/ja active Pending
- 1975-11-21 DD DD189617A patent/DD125569A5/xx unknown
- 1975-11-21 LU LU73851A patent/LU73851A1/xx unknown
- 1975-11-21 ZA ZA00757313A patent/ZA757313B/en unknown
- 1975-11-21 DK DK525175A patent/DK525175A/en unknown
- 1975-11-21 BR BR7507716*A patent/BR7507716A/en unknown
- 1975-11-21 PL PL1975184907A patent/PL95712B1/en unknown
- 1975-11-21 AT AT887975A patent/AT334399B/en not_active IP Right Cessation
- 1975-11-21 IE IE2537/75A patent/IE42181B1/en unknown
- 1975-11-21 ES ES442881A patent/ES442881A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL7513585A (en) | 1976-05-25 |
| ZA757313B (en) | 1976-10-27 |
| PL95712B1 (en) | 1977-11-30 |
| AT334399B (en) | 1976-01-10 |
| LU73851A1 (en) | 1976-09-06 |
| ATA887975A (en) | 1976-05-15 |
| AU8671175A (en) | 1977-05-26 |
| DK525175A (en) | 1976-05-24 |
| JPS5175080A (en) | 1976-06-29 |
| IL48503A0 (en) | 1976-01-30 |
| BE835769A (en) | 1976-05-20 |
| DD125569A5 (en) | 1977-05-04 |
| GB1476072A (en) | 1977-06-10 |
| TR18550A (en) | 1977-03-24 |
| SU592331A3 (en) | 1978-02-05 |
| JPS5173134A (en) | 1976-06-24 |
| BR7507716A (en) | 1976-08-10 |
| IE42181B1 (en) | 1980-06-18 |
| DE2455586A1 (en) | 1976-05-26 |
| IE42181L (en) | 1976-05-23 |
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