ES332250A1 - Procedure for preparing polyoxyliocohylene eter dolls. (Machine-translation by Google Translate, not legally binding) - Google Patents
Procedure for preparing polyoxyliocohylene eter dolls. (Machine-translation by Google Translate, not legally binding)Info
- Publication number
- ES332250A1 ES332250A1 ES0332250A ES332250A ES332250A1 ES 332250 A1 ES332250 A1 ES 332250A1 ES 0332250 A ES0332250 A ES 0332250A ES 332250 A ES332250 A ES 332250A ES 332250 A1 ES332250 A1 ES 332250A1
- Authority
- ES
- Spain
- Prior art keywords
- iii
- group
- integer
- carbon atoms
- oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Abstract
Process for preparing polyoxyalkylene ether diols, wherein the hydroxyl groups are substantially terminal hydroxyl groups, comprising mixing at least one polymerizable organic cyclic monomer, having a ring of 2 to 3 carbon atoms and an oxygen atom, and up to total of 18 carbon atoms, said oxide being chosen from the group consisting of epoxides, oxetanes, 3-substituted oxetanes and 3,3-disubstituted oxetanes, with water being present in an amount of about 0.0001 to 5% by weight, based on in the polymerizable oxide, in the presence of a catalyst in an amount of about 0.0001 to 15% by weight on said monomer, said catalyst comprising a double metal cyanide complex compound having the general formula Ma (Z) c. (H2O) ) d. (R) e, where Z is chosen from the group consisting of M '(CN) by M' [(CN) r (X) t] b where M is at least one metal selected from the group consisting of Zn (II), Fe (II), Fe (III), Co (II), Ni (II), Mo (IV), M or (VI), Al (III), V (IV), V (V), Sr (II), W (IV), W (VI), Mn (II) and Cr (III) M 'is a selected metal of the group consisting of Fe (II), Fe (II) Co (II), Co (III) Cr (ll), Cr (III), Mn (II), Mn (III), V (IV) and V ( V), X is an elected member of the group consisting of (see formula), R is an organic compound of low molecular weight that has up to 18 carbon atoms and is selected from the group consisting of alcohols, aldehydes, ketones, ethers, esters and amides, nitriles and sulfides, being a, b and c numbers whose values are a function of the valences and coordination indices of M and M ', with the total positive net charge of M, multiplied by a, essentially equal to the total negative net charge of Z multiplied by c, R is an integer, T is an integer, where R is greater than T, d is equal to 0 or an integer, and e is an integer; maintaining said mixture at a temperature at which said water and cyclic oxide will react to produce said polyoxyalkylene ether diols. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US496721A US3404109A (en) | 1963-02-14 | 1965-10-15 | Production of polyether diols using water as a telogen |
Publications (1)
Publication Number | Publication Date |
---|---|
ES332250A1 true ES332250A1 (en) | 1967-07-16 |
Family
ID=41533525
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES0332250A Expired ES332250A1 (en) | 1965-10-15 | 1966-10-14 | Procedure for preparing polyoxyliocohylene eter dolls. (Machine-translation by Google Translate, not legally binding) |
Country Status (2)
Country | Link |
---|---|
JP (1) | JPS4627250B1 (en) |
ES (1) | ES332250A1 (en) |
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-
1966
- 1966-10-14 ES ES0332250A patent/ES332250A1/en not_active Expired
- 1966-10-15 JP JP6743366A patent/JPS4627250B1/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
JPS4627250B1 (en) | 1971-08-07 |
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